Abstract
HETEROGENEOUS chemical reactions on the surfaces of solid or liquid particles present in the lower stratosphere may be an important influence on the levels of ozone depletion resulting from increased concentrations of anthropogenic chlorine compounds in the atmosphere1. Such processes, occurring on ice particles in polar stratospheric clouds, have been invoked to explain the formation of the springtime ozone hole over Antarctica2,3. Sulphuric acid aerosols injected into the atmosphere following a volcanic eruption may also provide sites for heterogeneous chemistry leading to ozone depletion4. Here we present model calculations that assess the importance of heterogeneous processes in future ozone depletion, assuming that trace-gas concentrations follow the protocol agreed at the recent international convention in London. We find that, even if this protocol is adhered to, reactions on the surface of sulphuric acid aerosol particles could produce significant ozone depletion into the beginning of the next century, especially if a major volcanic eruption (similar to the El Chichón eruption of 19824) takes place.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
Scientific Assessment of Stratospheric Ozone: 1989, Global Ozone Research and Monitoring Project, Rep. No. 20 (UN Environment Program/World Meteorological Organisation Geneva, 1990).
Solomon, S., Garcia, R. R., Rowland, F. R. & Wuebbles, D. J. Nature 321, 755 (1986).
McElroy, M. B., Salawitch, R. J., Wofsy, S. C. & Logan, J. A. Nature 321, 759–762 (1986).
Hofmann, D. J. & Solomon, S. J. geophys. Res. 94, 5029–5061 (1989).
Junge, C. E., Chagnon, C. W. & Marson, J. E. J. Met. 18, 81–108 (1961).
Tolbert, M. A., Rossi, M. J. & Golden, D. M. Geophys. Res. Lett 15, 867–850 (1988).
Worsnop, D. M. et al. Polar Ozone Workshop NASA Conf. Publ. 10014, 98–101 (1988).
Brasseur, G. et al. J. geophys Res. 95, 5639–5655 (1990).
Solomon, S., Garcia, R. R. & Stordal, F. J. geophys. Res. 90, 12981–12989 (1985).
Brasseur, G. & Hitchman, M. H. Science 240, 634–637 (1988).
Chipperfield, M. P. & Pyle, J. A. J. geophys. Res 95, 11865–11874 (1990).
Granier, C. & Brasseur, G. J. geophys. Res. (in the press).
Rosen, J. M. J. atmos. Met 10, 1044–1045 (1971).
Hofmann, D. J. & Rosen, J. M. J. geophys. Res. 89, 4883–4890 (1986).
McCormick, M. P. & Swissler, T. J. Geophys. Res. Lett. 10, 877–880 (1983).
Mozurkewich, M. & Calvert, J. G. J. geophys. Res. 93, 15889–15896 (1988).
De More, W. B. et al. Evaluation Number 9, JPL Publ. 90–1 (Jet Propulsion Laboratory, Pasadena, 1990).
Jager, H. & Wege, K. J. atmos. Chem. 10, 273–287 (1990).
Bais, A. F. et al. in Atmospheric Ozone (eds Zerefos, C. S. & Ghazi, A.) 353–356 (Reidel, Dordrecht, 1985).
Dütsch, H. U. in Atmospheric Ozone (eds Zerefos, C. S. & Ghazi, A.) 263–268 (Reidel, Dordrecht, 1985).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Brasseur, G., Granier, C. & Walters, S. Future changes in stratospheric ozone and the role of heterogeneous chemistry. Nature 348, 626–628 (1990). https://doi.org/10.1038/348626a0
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1038/348626a0
This article is cited by
-
Middle stratospheric polar vortex ozone budget during the warming Arctic winter, 2002–2003
Advances in Atmospheric Sciences (2011)
-
The impact of high altitude aircraft on the ozone layer in the stratosphere
Journal of Atmospheric Chemistry (1994)
-
Stratospheric CIO and ozone from the Microwave Limb Sounder on the Upper Atmosphere Research Satellite
Nature (1993)
-
Increased chlorine dioxide over Antarctica caused by volcanic aerosols from Mount Pinatubo
Nature (1993)
-
Ground-based monitoring of pinatubo aerosols and ozone at L'Aquila, Italy
Il Nuovo Cimento C (1993)
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.