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Carbon and sulphur isotopic composition of Kilauea parental magma

Abstract

All the available data for the isotopic composition of carbon in gases emitted from summit fumaroles at Kilauea volcano, Hawaii, indicate that the carbon is enriched in 13C compared with oceanic tholeiite and in contrast to most estimates for the isotopic composition of mantle carbon1–6. Several mechanisms proposed to explain this enrichment of 13C have proved unsatisfactory2. We show here that recent models7,8 for the volatile contents and degassing of Kilauea magma permit a satisfactory reinterpretation of carbon and sulphur isotope data1–3,9,10 for Kilauea. The results indicate that Kilauea parental magma is significantly enriched in 13C compared with mid-oceanic basalts and with inferred isotopic compositions for mantle carbon3–6. Hence, mantle sources of hot-spot and mid-oceanic basalts may differ in δ13C. In contrast, the isotopic composition of sulphur in Kilauea parental magma is similar to that of mid-oceanic basalts11.

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References

  1. Craig, H. in Nuclear Geology on Geothermal Areas (ed. Tongiorgi, E.) 17–53 (Consiglio Nazionale Della Ricerche, Laboratorio Di Geologia Nucleare, Pisa, 1963).

    Google Scholar 

  2. Thomas, D. M. thesis, Univ. Hawaii (1977).

  3. Des Marais, D. J. & Moore, J. G. Earth planet. Sci. Lett. 69, 43–57 (1984).

    Article  ADS  CAS  Google Scholar 

  4. Pineau, F., Javoy, M. & Bottinga, Y. Earth planet. Sci. Lett. 29, 413–421 (1976).

    Article  ADS  CAS  Google Scholar 

  5. Deines, P. Geochim. cosmochim. Acta 44, 943–961 (1980).

    Article  ADS  CAS  Google Scholar 

  6. Pineau, F. & Javoy, M. Earth planet. Sci. Lett. 62, 239–257 (1983).

    Article  ADS  CAS  Google Scholar 

  7. Gerlach, T. M. & Graeber, E. J. Nature 313, 273–277 (1985).

    Article  ADS  CAS  Google Scholar 

  8. Greenland, L. P., Rose, W. I. & Stokes, J. B. Geochim. cosmochim. Acta 49, 125–129 (1985).

    Article  ADS  CAS  Google Scholar 

  9. Sakai, H., Casadevall, T. J. & Moore, J. G. Geochim. cosmochim. Acta 46, 729–738 (1982).

    Article  ADS  CAS  Google Scholar 

  10. Sakai, H., Des Marais, D. J., Ueda, A. & Moore, J. G. Geochim. cosmochim. Acta 48, 2433–2441 (1984).

    Article  ADS  CAS  Google Scholar 

  11. Puchelt, H. & Hubberten, H.-W. Init. Rep. DSDP 51, 52, 53, 54, Pt 2, 1145–1148 (1980).

    Google Scholar 

  12. Swanson, D. A., Duffield, W. J. & Fiske, R. S. U.S. geol. Surv. prof. Pap. 963, 1–39 (1976).

    Google Scholar 

  13. Ryan, M. P., Blevins, J. Y. K., Okamura, A. T. & Koyanagi, R. Y. J. geophys. Res. 88, 4147–4181 (1983).

    Article  ADS  Google Scholar 

  14. Eaton, J. P. in The Crust of the Pacific Basin (ed. Endo, E. T.) 13–29 (American Geophysical Union, 1962).

    Google Scholar 

  15. Ellsworth, W. L. & Koyanagi, R. Y. J. geophys. Res. 82, 5379–5394 (1977).

    Article  ADS  Google Scholar 

  16. Wright, T. L. J. geophys. Res. 89, 3233–3252 (1984).

    Article  ADS  CAS  Google Scholar 

  17. Ryan, M. P., Koyanagi, R. Y. & Fiske, R. S. J. geophys. Res. 86, 7111–7129 (1981).

    Article  ADS  Google Scholar 

  18. Wright, T. L. & Fiske, R. S. J. Petrol. 12, 1–65 (1971).

    Article  ADS  CAS  Google Scholar 

  19. Duffield, W. A., Christiansen, R. L., Koyanagi, R. Y. & Peterson, D. W. J. Volcanol. geotherm. Res. 13, 273–307 (1982).

    Article  ADS  CAS  Google Scholar 

  20. Dzurison, D., Koyanagi, R. Y. & English, T. T. J. Volcanol. geotherm. Res. 21, 177–206 (1984).

    Article  ADS  Google Scholar 

  21. Macdonald, G. A. & Abbott, A. T. Volcanos in the Sea (University Press of Hawaii, 1974).

    Google Scholar 

  22. Javoy, M., Pineau, F. & Iiyama, L. Contr. Miner. Petrol. 67, 35–39 (1978).

    Article  ADS  CAS  Google Scholar 

  23. Keller, G. V., Grose, L. T., Murray, J. C. & Skokan, C. K. J. Volcanol geotherm. Res. 5, 345–385 (1979).

    Article  ADS  CAS  Google Scholar 

  24. Swanson, D. A. & Fabbi, B. P. J. Res. U.S. Geol. Surv. 1, 649–658 (1973).

    CAS  Google Scholar 

  25. Moore, J. G. & Fabii, B. P. Contr. Miner. Petrol. 33, 118–127 (1971).

    Article  ADS  CAS  Google Scholar 

  26. Kanehira, K., Yui, S., Sakai, H. & Sasaki, A. Geochemistry 7, 89–96 (1973).

    CAS  Google Scholar 

  27. Grinenko, V. A., Dmitriev, L. V., Migdisov, A. A. & Sharaskin, A. Ya., Geochem. Int. 1975, 132–137 (1975).

    Google Scholar 

  28. Sakai, H., Ueda, A. & Field, C. W. in Short Pap. 4th int. Conf. Geochronology, Cosmochronology and Isotope Geology (ed. Zartman, R. E.) 372–374 (US Geological Survey Open-File Report 78–701, 1978).

    Google Scholar 

  29. Ohmoto, H. & Rye, R. O. in Geochemistry of Hydrothermal Ore Deposits (ed. Barnes, H. L.) 509–567 (Wiley, New York, 1979).

    Google Scholar 

  30. Stoiber, R. E. & Malone, G. B. EOS 56, 461 (1975).

    Google Scholar 

  31. Casadevall, T. J. & Hazlett, R. W. J. Volcanol. geotherm. Res. 16, 173–188 (1983).

    Article  ADS  Google Scholar 

  32. Sen, G. Earth planet. Sci. Lett. 62, 215–228 (1983).

    Article  ADS  CAS  Google Scholar 

Download references

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Gerlach, T., Thomas, D. Carbon and sulphur isotopic composition of Kilauea parental magma. Nature 319, 480–483 (1986). https://doi.org/10.1038/319480a0

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