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Solid-state perspectives of the photoelectrochemistry of semiconductor–electrolyte junctions

Abstract

More than one mechanism is required to account for the photoinduced movement of charge across semiconductor–electrolyte junctions. Distinguishing the various mechanisms, which is here accomplished using a synthesis of theoretical ideas from both solid-state physics and electrochemistry, may have important consequences in research related to potential applications of liquid junction devices in solar energy conversion.

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References

  1. Eden, R. C., Moll, J. L. & Spicer, W. E. Phys. Rev. Lett. 18, 597–599 (1967).

    Article  ADS  CAS  Google Scholar 

  2. Williams, B. F. & Simon, R. E. Phys. Rev. Lett. 18, 485–487 (1967).

    Article  ADS  CAS  Google Scholar 

  3. Williams, F., Varma, S. P. & Hillenius, S. J. chem. Phys. 64, 1549–1554 (1976).

    Article  ADS  CAS  Google Scholar 

  4. Redfield, D. Phys. Rev. 140, A2056–2058 (1965).

    Article  ADS  CAS  Google Scholar 

  5. Inglis, G. B. & Williams, F. Phys. Rev. lett. 25, 1275–1278 (1970); J. non-cryst. Solids. 5, 313–327 (1971); Phys. Rev. B 11, 2200–2204 (1975).

    Article  ADS  CAS  Google Scholar 

  6. Krohn, C. E. & Thompson, J. C. Phys. Rev. B 20, 4365–4367 (1979).

    Article  ADS  CAS  Google Scholar 

  7. Bard, A. J. Science 207, 139–144 (1980).

    Article  ADS  CAS  Google Scholar 

  8. Nozik, A. J. A. Rev. Phys. Chem. 29, 189–222 (1978).

    Article  ADS  CAS  Google Scholar 

  9. Wrighton, M. S. Acc. chem. Res. 12, 303–310 (1979).

    Article  CAS  Google Scholar 

  10. Heller, A. Acc. chem. Res. 14, 154–162 (1981).

    Article  CAS  Google Scholar 

  11. Boudreaux, D. S., Williams, F. & Nozik, A. J. J. appl. Phys. 51, 2158–2163 (1980).

    Article  ADS  CAS  Google Scholar 

  12. Nozik, A. J., Chance, R. R., Boudreaux, D. S. & Williams, F. Adv. Chem. Ser. 184, 155–171 (1980).

    Article  CAS  Google Scholar 

  13. Buhks, E. & Williams, F. in Photoelectrochemistry: Fundamental Properties and Measurement Techniques, Electrochem. Soc. Symp. Proc. (eds Wallace, W., Nozik, A. J., Deb, S. K. & Wilson, R.) 1–13 (Electrochemical Society, 1981).

    Google Scholar 

  14. Williams, F. & Nozik, A. J. Nature 271, 137–139 (1978).

    Article  ADS  CAS  Google Scholar 

  15. Parkinson, B. A., Heller, A. & Miller, B. Appl. Phys. Lett. 33, 521–523 (1978).

    Article  ADS  CAS  Google Scholar 

  16. Bard, A. J., Bocarsly, A. B., Fan, F. R. F., Walton, E. G. & Wrighton, M. S. J. Am. chem. Soc. 102, 3671–3677 (1980).

    Article  CAS  Google Scholar 

  17. Kelly, J. J. & Memming, R. J. electrochem. Soc. 129, 730–738 (1982).

    Article  CAS  Google Scholar 

  18. Cooper, G., Turner, J. A., Parkinson, B. A. & Nozik, A. J. J. appl. Phys. 54, 6463–6473 (1983).

    Article  ADS  CAS  Google Scholar 

  19. Kautek, W. & Gerischer, H. Ber. Bunsenges phys. Chem. 84, 645–653 (1980).

    Article  CAS  Google Scholar 

  20. Chazalviel, J. N. J. electrochem. Soc. 129, 963–969 (1982).

    Article  CAS  Google Scholar 

  21. Kittel, X. Introduction to Solid State Physics, 5th edn. 231–237 (Wiley, New York, 1976).

    Google Scholar 

  22. Thomas, D. G., Hopfield, J. J. & Frosch, C. J. Phys. Rev. Lett. 15, 857–860 (1965).

    Article  ADS  Google Scholar 

  23. Williams, F., Berry, D. E. & Bernard, J. E. Radiationless Processes (ed. DiBartolo, B.) 1–38 & 409–430 (Plenum, New York, 1980).

    Book  Google Scholar 

  24. Albery, W. J. A. Rev. phys. Chem. 31, 227–263 (1980).

    Article  ADS  CAS  Google Scholar 

  25. Marcus, R. A. Faraday Disc. Chem. Soc. 74, 7–15 (1982).

    Article  Google Scholar 

  26. Gerischer, H. Z. phys. Chem. 26, 223–247 (1960).

    Article  CAS  Google Scholar 

  27. Fröhlich, H. & Paranjape, B. V. Proc. phys. Soc. B69, 21–32 (1956).

    Article  ADS  Google Scholar 

  28. Eastman, L. F. Festkörperprobleme 22, 173–187 (1982).

    CAS  Google Scholar 

  29. Turner, J. A. & Nozik, A. J. Appl. Phys. Lett. 41, 101–103 (1982).

    Article  ADS  CAS  Google Scholar 

  30. Cooper, G., Turner, J. A., Parkinson, B. A. & Nozik, A. J. J. appl. Phys. 54, 6463–6473 (1983).

    Article  ADS  CAS  Google Scholar 

  31. Dingle, R. Festkörperprobleme 15, 21–48 (1975).

    Article  CAS  Google Scholar 

  32. Dingle, R., Wiegmann, W. & Henry, C. H. Phys. Rev. Lett. 33, 827–830 (1974).

    Article  ADS  CAS  Google Scholar 

  33. Rossetti, R., Nakahara, S. & Brus, L. E. J. chem. Phys. 79, 1086–1088 (1983).

    Article  ADS  CAS  Google Scholar 

  34. Brus, L. E. J. chem. Phys. 79, 5566–5571 (1983).

    Article  ADS  CAS  Google Scholar 

  35. Rossetti, R., Ellison, J. L., Gibson, J. M. & Brus, L. E. J. chem. Phys. (in the press).

  36. Brus, L. E. J. chem. Phys. (in the press).

  37. Micic, O. I., Nenadovic, M. T., Nozik, A. J., Rajh, T. & Williams, F. J. phys. chem. (submitted).

  38. Williams, F. & Nozik, A. J. (in preparation).

  39. Bastard, G., Mendex, E. E., Chang, L. I. & Esaki, L. Phys. Rev. B26, 1974–1979 (1982).

    Article  ADS  CAS  Google Scholar 

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Williams, F., Nozik, A. Solid-state perspectives of the photoelectrochemistry of semiconductor–electrolyte junctions. Nature 312, 21–27 (1984). https://doi.org/10.1038/312021a0

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