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Interaction of small and extended defects in nonstoichiometric oxides

Abstract

Analyses of the extrinsic and/or intrinsic nature of extended defects in nonstoichiometric titanium and tungsten oxides are made by drawing Burgers' circuits directly onto high-resolution electron micrographs. The essentially interstitial and/or vacancy nature of the small defects responsible for the phases TiO2−x and WO3−X , which exist above the extended defect precipitation temperature, may then be implied. Images suggesting a partial wall of anion vacancy defects have also been obtained.

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Bursill, L., Smith, D. Interaction of small and extended defects in nonstoichiometric oxides. Nature 309, 319–321 (1984). https://doi.org/10.1038/309319a0

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