Abstract
The vitrification of pure liquid water by projecting a thin jet of liquid water at high speed into a liquid cryomedium is reported. The influence of the experimental parameters on the cooling rate and the devitrification of the jet-frozen vitrified material have been investigated. A structural difference between vitrified liquid water and amorphous solid water prepared from the vapour phase is inferred from a comparison of the X-ray diffraction patterns.
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References
Olander, D. S. & Rice, S. A. Proc. natn. Acad. Sci. U.S.A. 69, 98–100 (1972).
Rice, S. A. & Sceats, M. G. J. phys. Chem. 85, 1108–1119 (1981).
Narten, A. H., Venkatesh, C. G. & Rice, S. A. J. chem. Phys. 64, 1106–1121 (1976).
Rice, S. A. Topics curr. Chem. 60, 109–200 (1975).
Angell, C. A. in Treatise on Water Vol. 7 (ed. Franks F.) (in the press).
Angell, C. A., Shuppert, J. & Tucker, J. C. J. phys. Chem. 77, 3092–3099 (1973).
Speedy, R. J. & Angell, C. A. J. chem. Phys. 65, 851–858 (1976).
Angell, C. A. & Tucker, J. C. J. phys. Chem. 84, 268–272 (1980).
Mazur, P. Science 168, 939–949 (1970).
Wolstenholme, G. E. W. & O'Connor, M. The Frozen Cell (Churchill, London, 1970).
Becker, E. D. & Pimentel, G. C. J. chem. Phys. 25, 224–228 (1956).
Fletcher, N. H. Rep. Prog. Phys. 34, 913–994 (1971).
Pryde, J. A. & Jones, G. O. Nature 170, 685–688 (1952).
Brüggeller, P. & Mayer, E. Nature 288, 569–571 (1980).
Bachmann, L. & Schmitt, W. W. Proc. natn. Acad. Sci. U.S.A. 68, 2149–2152 (1971); in Freeze Etching (eds Benedetti, E. L. & Favard, P.) 73–79 (Soc. Frac. Microsc. Electron, Paris 1973).
Stewart, G. W. & Mannheimer, M. Z. anorg. allg. Chem. 171, 61–72 (1928).
Sahores, J. J. Adv. X-ray Analysis 16, 186–197 (1973).
Berry, P. F., Furuta, T. & Rhodes, J. R. Adv. X-ray Analysis 12, 612–632 (1969).
Berglund, R. N. & Lui, B. Y. H. Envir. Sci. Technol. 7, 147–153 (1973).
Dowell, L. G. & Rinfret, A. P. Nature 188, 1144–1148 (1960).
Uhlmann, D. R. J. Non-Cryst. Solids 7, 337–348 (1972).
Hobbs, P. Ice Physics (Clarendon, Oxford, 1974).
Kauzmann, W. Chem. Rev. 43, 219–256 (1948).
Rasmussen, D. H., MacKenzie, A. P., Tucker, J. C. & Angell, C. A. Science 181, 342–344 (1973).
Kanno, H. & Angell, C. A. J. chem. Phys. 73, 1940–1947 (1980).
Bruckner, R. J. Non-Cryst. Solids 5, 281 (1971).
Rice, S. A., Bergren, M. S. & Swingle, L. Chem. Phys. Lett. 59, 14–16 (1978).
Rice, S. A. & Sceats, M. G. J. phys. Chem. 85, 1108–1119 (1981).
Johari, G. P. Phil. Mag. 35, 1077–1090 (1977).
Narten, A. H. & Levy, H. A. J. chem. Phys. 55, 2263–2269 (1971).
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Mayer, E., Brüggeller, P. Vitrification of pure liquid water by high pressure jet freezing. Nature 298, 715–718 (1982). https://doi.org/10.1038/298715a0
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DOI: https://doi.org/10.1038/298715a0
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