Abstract
Metastable N2(A3Σu+) molecules are produced copiously in auroral substorms by the impact of low-energy secondary electrons on N2 and by the absorption of cosmic rays and solar X-rays at E-region altitudes and below. The major loss process for N2(A3Σu+) molecules below 100 km is collisional deactivation by O2. We present here the results of a detailed study of the reaction N2(A3Σu+); v′ = 0, 1, 2) + O2 → N2O + O, and we show that N2O is formed with an effective yield of 0.6 with a probable absolute error of ±30%.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
Harteck, P. & Dondes, S. J. chem. Phys. 24, 619 (1956).
Zipf, E. C. & Dubin, M. EOS 57, 156 (1976).
Malcombe-Lawes, D. J. Nature 247, 540 (1974).
Cartwright, D. C. J. geophys. Res. 83, 517 (1978).
Zipf, E. C. Geophys. Res. Lett. 6, 881 (1979).
Swider, W. Geophys. Res. Lett. 3, 335 (1976).
Sharp, W. E. J. geophys. Res. 76, 987 (1971).
Sharp, W. E. & Torr, D. G. J. geophys. Res. 84, 5345 (1979).
Gerard, J. C. & Rusch, D. W. J. geophys. Res. 84, 4335 (1979).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Zipf, E. A laboratory study on the formation of nitrous oxide by the reaction N2(A3Σu+) + O2 → N2O + O. Nature 287, 523–524 (1980). https://doi.org/10.1038/287523a0
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1038/287523a0
This article is cited by
-
The Chemistry of Gaseous Dodecane Degradation in a BaTiO3 Packed-Bed Plasma Reactor
Plasma Chemistry and Plasma Processing (2015)
-
Energetic Particle Precipitation and the Chemistry of the Mesosphere/Lower Thermosphere
Surveys in Geophysics (2012)
-
In situ aircraft measurements of enhanced levels of N2O associated with thunderstorm lightning
Nature (1983)
-
A mesospheric source of nitrous oxide
Nature (1982)
-
Atmospheric nitrous oxide produced by solar protons and relativistic electrons
Nature (1981)
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.