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Argon isotopic evolution of upper mantle

Abstract

BROWN et al.1 have treated the problem of the history of the argon degassing of the Earth, and claim to demonstrate that the 40Ar/36Ar ratio in the mantle has increased from 133, 770 Myr ago, to a value that “is at present not greater than the atmospheric ratio (295.5) and is probably a little lower”. Their Table 1 and Fig. 1 show the results of K–Ar isochron analyses of several suites of “mantle-derived igneous” samples. We have been unable to reproduce in detail their results from the references they cite, and conclude that the apparent trend in their Fig. 1 is an artefact of data selection and that the source of the observed argon has been misidentified. We think the 40Ar/36Ar ratios in the solid earth and the atmosphere have probably increased with time. Theoretical considerations and the available literature both indicate, however, that the 40Ar/36Ar ratio in the solid earth is much higher than the 40Ar/36Ar ratio in the atmosphere.

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ALEXANDER, E., SCHWARTZMAN, D. Argon isotopic evolution of upper mantle. Nature 259, 104–106 (1976). https://doi.org/10.1038/259104a0

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