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Ionic conductivity in some bivalent metal sulphides

Abstract

INVESTIGATIONS of the ionic conductivity of solids have been concentrated mainly on materials characterised by a purely ionic conductivity, such as AgI, RbAg4I5, and β-alumina, which have practical applications in the production of solid-state high energy–density batteries and other electrochemical devices1. In such cases a non-zero electronic contribution prevents the material from acting as a solid electrolyte: materials with mixed ionic–electronic conductivity can be used as electrode materials in electrochemical cells.

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GALLI, R., GARBASSI, F. Ionic conductivity in some bivalent metal sulphides. Nature 253, 720–722 (1975). https://doi.org/10.1038/253720a0

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