Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • Letter
  • Published:

Structure of Anomalous Water and Its Mechanism

Abstract

SINCE the discovery of “anomalous water”1, several models2–12 have been proposed for its structure. I derive here a model based on present experimental knowledge, and then explain its mechanism.

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Similar content being viewed by others

References

  1. Derjaguin, B. V., Churaev, N. V., Fedyakin, N. N., Talaev, M. V., and Ershova, I. G., Izv. Akad. Nauk SSSR, 10, 2178 (1967), and Bull. Acad. Sci. USSR, Div. Chem. Sci., 2095 (1967).

    Google Scholar 

  2. Bolander, R. W., Kassner, jun., J. L., and Zung, J. T., Nature, 221 1233 (1969).

    Article  ADS  CAS  Google Scholar 

  3. Bellamy, L. J., Osborn, A. R., Lippincott, E. R., and Bandy, A. R., Chem. Ind., 686 (1969).

  4. Lippincott, E. R., Stromberg, R. R., Grant, W. H., and Cessac, G. L., Science, 164, 1482 (1969).

    Article  ADS  CAS  Google Scholar 

  5. Donohue, J., Science, 166, 1000 (1969).

    Article  ADS  CAS  Google Scholar 

  6. Morokuma, K., Chem. Phys. Lett., 4, 358 (1969).

    Article  ADS  CAS  Google Scholar 

  7. Hertl, W., and Hair, M. L., Nature, 223, 1150 (1969).

    Article  ADS  CAS  Google Scholar 

  8. Petsko, G. A., Science, 167, 171 (1970).

    Article  ADS  CAS  Google Scholar 

  9. Allen, L. C., and Kollman, P. A., Science, 167, 1443 (1970).

    Article  ADS  CAS  Google Scholar 

  10. Erlander, S. R., Phys. Rev. Lett., 22, 177 (1969).

    Article  ADS  CAS  Google Scholar 

  11. Erlander, S. R., Phys. Rev. A., 1, 868 (1970).

    Article  ADS  CAS  Google Scholar 

  12. Linnett, J. W., Science, 167, 1720 (1970).

    Article  ADS  Google Scholar 

  13. Anway, A. R., J. Chem. Phys., 50, 2012 (1969).

    Article  ADS  CAS  Google Scholar 

  14. Robinson, R. A., and Harned, H. S., Chem. Rev., 28, 419 (1941).

    Article  CAS  Google Scholar 

  15. Perrin, D. D., J. Chem. Soc., 3189 (1960).

  16. Grunwald, E., and Fong, D.-W., J. Phys. Chem., 73, 650 (1969).

    Article  CAS  Google Scholar 

  17. Wall, T. T., and Hornig, D. F., J. Chem. Phys., 47, 784 (1967).

    Article  ADS  CAS  Google Scholar 

  18. Del Bene, J., and Pople, J. A., Chem. Phys. Lett., 4, 426 (1969).

    Article  ADS  CAS  Google Scholar 

  19. Nakamoto, K., Margoshes, M., and Rundle, R. E., J. Amer. Chem. Soc., 77, 6480 (1955).

    Article  CAS  Google Scholar 

  20. Derjaguin, B. V., and Churaev, N. V., Priroda, 16 (1968).

  21. Lamberts, L., and Huyskens, P., First Intern. Conf. Calorimetry and Thermodynamics, Warsaw, paper M8 (1969).

  22. Lamberts, L., J. Chim. Phys., 62, 1404 (1965).

    Article  CAS  Google Scholar 

  23. Neerinck, D., van Audenhaege, A., and Lamberts, L., Ann. Chim. (France), 4, 51 (1969).

    Google Scholar 

  24. Drost-Hansen, W., Ind. Eng. Chem., 61, 10 (1969).

    Article  CAS  Google Scholar 

  25. Frank, F. C., Nature, 157, 267 (1946).

    Article  ADS  CAS  Google Scholar 

  26. Baugham, D. H., Nature, 157, 733 (1946).

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

CHUA, K. Structure of Anomalous Water and Its Mechanism. Nature 227, 834–836 (1970). https://doi.org/10.1038/227834b0

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1038/227834b0

This article is cited by

Comments

By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing