Abstract
WE have examined the chloride exchange reaction of triphenylchlorosilane with [36Cl]-labelled tetrabutyl-ammonium chloride in benzene at 30° C. The reaction is very rapid (half-life about 0.05 s) and requires the use of flow techniques1.
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References
Grant, M. W., and Prince, R. H., J. Chem. Soc., A (in the press).
Grant, M. W., and Prince, R. H., Chem. Commun. (in the press).
Copenhafer, D. T., and Krause, C. A., J. Amer. Chem. Soc., 73, 4557 (1951).
Pettit, L. D., and Bruckenstein, S., J. Amer. Chem. Soc., 88, 4783 (1966).
Fainberg, A. H., and Winstein, S., J. Amer. Chem. Soc., 78, 2767 (1956); Fainberg, A. H., Robinson, C. G., and Winstein, S., ibid., 78, 2777 (1956); Winstein, S., and Robinson, C. G., ibid., 80, 169 (1958).
Sommer, L. H., Stereochemistry, Mechanism and Silicon (McGraw-Hill, New York, 1964).
Hughes, E. D., Ingold, C. K., Mok, S. F., Patai, S., and Pocker, Y., J. Chem. Soc., 1222 (1957).
Swain, C. G., and Kreevoy, M. M., J. Amer. Chem. Soc., 77, 1122 (1955).
Schaleger, L. L., and Long, F. A., in Advances in Physical Organic Chemistry, 1 (Academic Press, London, 1963).
Frost, A. A., and Pearson, R. G., Kinetics and Mechanism (Wiley and Sons, New York, 1961).
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GRANT, M., PRINCE, R. Stereochemical and Kinetic Significance of Ion Association in Fast Radiochloride Exchange Reactions at Silicon. Nature 222, 1163–1164 (1969). https://doi.org/10.1038/2221163a0
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DOI: https://doi.org/10.1038/2221163a0
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