Letter | Published:

Stereochemical and Kinetic Significance of Ion Association in Fast Radiochloride Exchange Reactions at Silicon

Nature volume 222, pages 11631164 (21 June 1969) | Download Citation

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Abstract

WE have examined the chloride exchange reaction of triphenylchlorosilane with [36Cl]-labelled tetrabutyl-ammonium chloride in benzene at 30° C. The reaction is very rapid (half-life about 0.05 s) and requires the use of flow techniques1.

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Author information

Affiliations

  1. University Chemical Laboratory, Cambridge.

    • M. W. GRANT
    •  & R. H. PRINCE

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DOI

https://doi.org/10.1038/2221163a0

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