Abstract
NUMEROUS oxidants, the standard potentials of which are high enough to oxidize anthracene, form hole injecting contacts with it1,2. Carrier injection occurs by a wholly electrochemical process, the transfer of an electron from solid to dissolved oxidant. Anthracene oxidizes in homogeneous solution at 1.09 V with respect to a saturated calomel electrode (SCE)3.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
Mehl, W., Ber. Buns. Ges., 69, 583 (1965).
Mehl, W., Hale, J. M., and Lohmann, F., J. Electrochem. Soc., 113, 1166 (1966).
Pysh, E. S., and Yang, N. C., J. Amer. Chem. Soc., 85, 2124 (1963).
Kallman, A., and Pope, M., J. Chem. Phys., 32, 300 (1960).
Aparicio, F. J. L., and Waters, W. A., J. Chem. Soc., 4666 (1952).
Gränaeher, I., Solid State Commun., 2, 365 (1964).
Briegleb, G., Elektronen-Donator-Acceptor-Komplexe (Springer Verlag, Berlin, 1961).
Euler, H., and Willstaedt, H., Arkiv Kemi, Mineral Geol., 10B, 1 (1929).
Cullinane, N. M., Chard, S. J., and Leyshon, D. M., J. Chem. Soc., 4106 (1952).
Olah, G., ed., Friedel Crafts and Related Reactions, I, 385 (Interscience, NY, 1963).
Gerischer, H., J. Electrochem. Soc., 113, 1172 (1966).
Beyerle, M., and Gerischer, H., Ber. Bunsenges. Physik. Chem., 71, 380 (1967).
Conant, J. B., and Fieser, L. F., J. Amer. Chem. Soc., 46, 1858 (1924).
Aalbersberg, W., Hoijtink, G. J., Mackor, E. L., and Weijland, W. P., J. Chem. Soc., 3049 (1959).
Walker, D., and Hiebert, J. D., Chem. Rev., 67, 153 (1967).
Buck, H. M., Oosterhoff, L. J. v. d., Sluys, M. J., Vlugt, v. d., and Verhoeven, K. G., Rec. Trav. Chim., 86, 923 (1967).
Elving, P. J., and Markowitz, J. M., J. Phys. Chem., 65, 686 (1961).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
HOFFMANN, A. Chemical Mechanisms for Injection of Positive Carriers into Single Crystals. Nature 218, 1157–1158 (1968). https://doi.org/10.1038/2181157a0
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1038/2181157a0
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.