Abstract
XENON trioxide is a strong oxidizing agent, with a potential of −1.8 V (ref. 1) and the kinetics of several of its oxidation reactions, all of them thermal, have been studied2–4. We have now obtained evidence of a photochemical reaction in the course of a study of the oxidation of neptunium(V) by xenon trioxide
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References
Appelman, E. H., and Malm, J. G., J. Amer. Chem. Soc., 86, 2141 (1964).
Koch, C. W., and Williams, S. M., in Noble Gas Compounds (edit. by Hyman H. H.), 181 (University of Chicago Press, Chicago, 1963).
Cleveland, J. M., J. Amer. Chem. Soc., 87, 1816 (1965).
Cleveland, J. M., Inorg. Chem. (in the press).
Hagan, P. G., and Cleveland, J. M., J. Inorg. Nucl. Chem., 28, 2905 (1966).
Werkema, G. J., Fortran II Progam for Reduction of Spectrophotometric Reaction Kinetics Data; US AEC Rep. RFP–629 (Nov. 17, 1965).
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An erratum to this article is available at https://doi.org/10.1038/215906c0
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CLEVELAND, J., WERKEMA, G. Photochemical Oxidation of Neptunium(V) by Xenon Trioxide. Nature 215, 732–733 (1967). https://doi.org/10.1038/215732a0
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DOI: https://doi.org/10.1038/215732a0
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