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Determination of Radial Distribution Functions by Elastic Electron Diffraction

Abstract

THE ordering of matter in amorphous materials can be characterized by a radial distribution function of density 4πr2ρ(r), and a difference radial distribution function 4πr2(ρ(r) − ρ0). The latter is obtained1 from experimental scattering data I(s) by the Fourier inversion: where s = 2sin½β/λ, β is the scattering angle, and f is the atomic scattering factor. f is a smoothly decreasing function of s and the quantity to be inverted is the ratio of the ripple of I(s) about f2(s), to the smooth curve f2(s).

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References

  1. For example, Guinier, A., X-Ray Diffraction in Crystals, Imperfect Crystals and Amorphous Bodies (Freeman, London, 1963).

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  2. Grigson, C. W. B., J. Electronics and Control, 12, 209 (1962).

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  3. Denbigh, P. N., and Grigson, C. W. B., J. Sci. Inst., 42, 305 (1965).

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  4. Tompsett, M. F., and Grigson, C. W. B., Nature, 206, 923 (1965).

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GRIGSON, C., TOMPSETT, M. Determination of Radial Distribution Functions by Elastic Electron Diffraction. Nature 210, 86–87 (1966). https://doi.org/10.1038/210086a0

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