Abstract
THE rates of racemization of the complexes MI3Cr(oxalate)3 have been found to depend on the nature of the alkali metal ion MI as shown in Table 1.
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Beese, N. W. D., and Johnson, C. H., Trans. Faraday Soc., 31, 1632 (1935).
Kernohan, J. A., Odell, A. L., and Olliff, R. W., (unpublished results).
Hay, R. W., and Harvie, S. J., Austral. J. Chem., 18, 1197 (1965).
Ashley, K. R., and Hamm, R. E., Inorg. Chem., 4, 1120 (1960).
Bunton, C. A., Carter, J. H., Llewellyn, D. R., O'Connor, C. J., Odell, A. L., and Yih, S. Y., J. Chem. Soc., 4615 (1964). Bunton, C. A., Carter, J. H., Llewellyn, D. R., Odell, A. L., and Yih, S. Y., J. Chem. Soc., 4622 (1964). Llewellyn, D. R., O'Connor, C. J., Odell, A. L., and Olliff, R. W., J. Chem. Soc., 4627 (1964).
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KERNOHAN, J., ODELL, A., OLLIFF, R. et al. Catalysis by Alkali Metal Ions of the Racemization of the Tris-oxalato Chromium-III Anion. Nature 209, 906 (1966). https://doi.org/10.1038/209906b0
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DOI: https://doi.org/10.1038/209906b0
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