Abstract
SHIFTS to lower frequencies of the C=O stretching vibration on complex formation between metals and ligands containing the carbonyl group have been the subject of several investigations, following the work of Bellamy and Branch1. A similar examination of the C=O bending vibration, to the best of our knowledge, has not been previously reported: so we investigated this vibration in complexes of amides.
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References
Bellamy, L. J., and Branch, R. F., J. Chem. Soc., 4491 (1964).
Vilkov, L. V., Akishin, P. A., and Presnyakova, V. M., J. Structural Chem., 3, 3 (1962).
Miyazawa, T., Shimanouchi, T., and Mizushima, S., J. Chem. Phys., 24, 408 (1956).
Miyazawa, T., Shimanouchi, T., and Mizushima, S., J. Chem. Phys., 29, 611 (1958).
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JUNGBAURER, M., CURRAN, C. N—C=O Bending Vibration in Complexes of Dimethylformamide with Metal Halides. Nature 202, 290 (1964). https://doi.org/10.1038/202290a0
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DOI: https://doi.org/10.1038/202290a0
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