Abstract
THE monolayers of long-chain compounds such as cetyl and stearyl alcohols are being used extensively to minimize the loss of water by evaporation in reserviors1. Permeability of water vapour through a monolayer depends on, among others, the magnitude of the van der Waals type of cohesive forces of the film molecule with its neighbours, and on the adhesive force between the monolayer and the water subphase. Further extension of the n-alkyl chain and/or suitable modification of the terminal polar group would, therefore, make a monolayer more effective in reducing evaporation.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
a, Mansfield, W. W., Nature, 175, 247 (1955). b, Mansfield, W. W., 172, 1101 (1953). c, Mansfield, W. W., Austral. J. App. Sci., 9 (3), 245 (1958).
a, Deo, A. V., et al., Nature, 187, 870 (1960). b, Kulkarni, S. B., et al., (i) Ind. Pat. No. 70670 (1960); (ii) Australian Pat. No. 63866 (1960) and also U.S. Patent No. 62522 (1960).
Cary, A., and Rideal, E. K., Proc. Roy. Soc., A, 109, 318 (1925).
Nutting, G. C., and Harkins, W. D., J. Amer. Chem. Soc., 61, 1180 (1939).
a, Langmuir, I., and Schaefer, V. J., J. Franklin Inst., 235, 119 (1943). b, Archer, R. J., and La Mer, V. K., J. Phys. Chem., 59, 200 (1955).
La Mer, V. K., and Barnes, G. T., Proc. U.S. Nat. Acad. Sci., 45 (8), 1274 (1959).
Rosano, H. L., and La Mer, V. K., J. Phys. Chem., 60, 348 (1956).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
DEO, A., KULKARNI, S., GHARPUREY, M. et al. Compressibility and Specific Evaporation Resistance of the Monolayers of Long-Chain Alcohols and Glycol Monoalkyl Ethers. Nature 191, 378–379 (1961). https://doi.org/10.1038/191378a0
Issue Date:
DOI: https://doi.org/10.1038/191378a0
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.