Abstract
Dicyano - bis - dimethylglyoximato - cobaltate(III) complex, trans-K[CoIII dg 2(CN)2].3/2 H2O (a new compound)1 (dg = H3C.C(NOH).C(NO).CH3), was found to be reduced at the dropping mercury electrode in one step to a univalent cobalt complex polarographically in 1 M potassium chloride supporting electrolyte. The following electrode process was ascertained.
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Maki, N., Fujita, J., and Tsuchida, R., Bull. Chem. Soc. Japan (in the press).
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MAKI, N. New Univalent Cobalt Complexes of the [CoI dg 2 X 2] Type. Nature 188, 227 (1960). https://doi.org/10.1038/188227a0
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DOI: https://doi.org/10.1038/188227a0
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