Abstract
FRACTIONATION1 commercial gelatins has shown that the rigidity of gelatin gels is not solely dependent on the distribution of molecular weights but also depends on another factor—the ‘rigidity factor’. Scatchard's results2 show that the mean molecular weight of gelatin, and also its viscosity in aqueous solution, are decreased by thermal degradation. Ferry3 measured the reduction in the rigidity of gels of these degraded gelatins, and related the changes to the molecular weights. The present investigation shows that while in certain conditions (for example, low pH) Ferry's assumption is correct, in other conditions (for example, neutral or high pH) the rigidity factor is also reduced as degradation proceeds.
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References
Stainsby, G., Saunders, P. R., and Ward, A. G., Proc. 13th Int. Cong. Pure App. Chem. (Uppsala). Ward, A. G., Nature, 171, 1099 (1953).
Scatchard, G., Oncley, J. L., Williams, J. W., and Brown, A., J. Amer. Chem. Soc., 66, 1980 (1944).
Ferry, J. D., J. Amer. Chem. Soc., 70, 2244 (1948). Ferry, J. D., and Eldridge, J. E., J. Phys. Col. Chem., 53, 184 (1949).
Saunders, P. R., and Ward, A. G., Proc. 2nd Int. Cong. Rheology (Butterworths Scientific Publications, ltd., london, 1954).
Stainsby, G. Discussions of the Faraday Society, 18, 288 (1954).
Stainsby, G., Nature, 169, 662 (1952).
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SAUNDERS, P., WARD, A. Mechanical Properties of Degraded Gelatins. Nature 176, 26–27 (1955). https://doi.org/10.1038/176026a0
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DOI: https://doi.org/10.1038/176026a0
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