Abstract
RELATIVELY few binary liquid mixtures obey Raoult's law in their vapour pressure relationships. Most of those which do so are mixtures of either isomers or close homologues. The components of the remainder are not, in general, highly polar substances1.
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References
Hildebrand and Scott, “The Solubility of Non-Electrolytes”, 210 (3rd edit., New York, 1950).
Hatem and Valladas-Dubois, Bull. Soc. chim. Fran., 16, 604 (1949).
Nelson and Markham, J. Amer. Chem. Soc., 72, 2417 (1950).
Kipling and Tester, J. Chem. Soc., [4123 (1952)].
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BLACKBURN, A., KIPLING, J. Raoult's Law: a Pseudo-Ideal System. Nature 171, 174–175 (1953). https://doi.org/10.1038/171174a0
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DOI: https://doi.org/10.1038/171174a0
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