Abstract
RATES of reaction in solution have not usually been measured over a range of temperature greater than about 50° C. Measurements over a bigger range would give more accurate values of the energy and entropy of activation, and interesting deviations from the linear Arrhenius relation between log k and 1/T might be expected, especially in proton-transfer reactions1. We have measured the rate between −80° C. and + 20° C. of the reaction between ethoxide ion and trinitrotoluene in ethanol, which appears to proceed by a proton transfer:
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on SpringerLink
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
Bell, R. P., “Acid–Base Catalysis”, chapter 8 (Oxford, 1941).
Cf. Chance, J. Franklin Inst., 229, 455, 613, 737 (1940).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
CALDIN, E., LONG, G. & TROWSE, F. Kinetics of Reaction in Ethanol Solution from −80° C. to +20° C.. Nature 171, 1124–1125 (1953). https://doi.org/10.1038/1711124a0
Issue Date:
DOI: https://doi.org/10.1038/1711124a0
This article is cited by
-
Dipole moments of derivatives of 1, 3, 5,-trinitrobenzen
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science (1956)
-
Equilibrium between Ethoxide and Hydroxide Ions in Ethanol
Nature (1953)
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.