Abstract
HYDROQUINONE pyridinium salts of organic acids, for example, formate and acetate, were prepared by the action of pyridine on p-quinone in presence of formic or acetic acid1. These salts are found by analysis not to contain active hydrogen. They are not methylated by diazomethane or dimethylsulphate, nor acetylated by acetic anhydride ; and in all these experiments the materials were recovered almost unchanged. So far as could be ascertained from the literature, the preparation of such derivatives has not hitherto been attempted.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
Buchta, Ber., 70 (B), 2339 (1937).
Barnett, Cook and Peck, J. Chem. Soc., 125, 1035 (1924).
Diels and Kassebart, Ann., 530, 51 (1937).
Schönberg and Ismail, J. Chem. Soc., 1374 (1940).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
ALY ISMAIL, A. A Quinonoid Structure for Hydroquinone Pyridinium Salts of Organic Acids. Nature 163, 565–566 (1949). https://doi.org/10.1038/163565b0
Issue Date:
DOI: https://doi.org/10.1038/163565b0
This article is cited by
-
A compound of 2:6-dimethoxy quinone and acetone
Proceedings of the Indian Academy of Sciences - Section A (1953)
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.