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Oxidation of Ferrous Ions in Aqueous Solution by X- and Î-Radiation

Abstract

THE oxidation of ferrous ions in dilute sulphuric acid solution by X- and γ-radiation has attracted attention since the work of Fricke1,2 as a possible method of integral dosimetry for aqueous media3. A study has now been made which confirms that the rate of oxidation with dose is essentially independent of the concentration of ferrous ions in the region 103 to 10-4 M, and which also shows that this rate is maintained independently of the wave-length of the radiation over a much wider range of wave-length than has hitherto been used in studies of this type.

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References

  1. Fricke, Amer. J. Roent. Rod. Ther., 18, 430 (1927); Phys. Rev., 31, 1117 (1928). Fricke and Morse, Phil. Mag., 7, 129 (1929).

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  2. Fricke and Hart, J. Chem. Phys., 3, 60 (1935).

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  3. For example, Stenström and Löhmann, Radiology, 18, 322 (1931).

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  4. Shishacow, Phil. Mag., 14, 198 (1932).

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  5. Gray and Weigert (unpublished data).

  6. Lea, "Actions of Radiations on Living Cells", 34 (Camb. Univ. Press, 1946).

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MILLER, N. Oxidation of Ferrous Ions in Aqueous Solution by X- and Î-Radiation. Nature 162, 448–449 (1948). https://doi.org/10.1038/162448b0

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