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Heat of Atomization of Carbon

Abstract

IT is known that spectroscopic data are in agreement only with a series of discrete values for the dissociation energy of carbon monoxide (Dco) and therefore also for the heat of sublimation of carbon (Lc)

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References

  1. Gaydon, A. G., and Penney, W. G., Proc. Roy. Soc., A, 183, 374 (1945). Herzberg, G., Chem. Rev., 20, 145 (1937). Schmid, R., and Gerö, L., Z. Phys., 105, 36 (1937). These papers discuss the arguments in favour of each of the values quoted as well as those against the intermediate possible values of 8.4 and 9.6 eV.

    ADS  CAS  Google Scholar 

  2. Goldfinger, P., and Jeunehomme, W., Trans. Farad. Soc., 32, 1591 (1936).

    Article  CAS  Google Scholar 

  3. Ribaud, G., and Bégue, J., C.R. Acad. Sci. Paris, 221, 73 (1945). Their values for the vapour pressure of carbon are too high for Lc = 170 but too low for Lc = 124 kcal.

    CAS  Google Scholar 

  4. Goldfinger, P., Lasareff, W., and Rosen, B., C.R. Acad. Sci. Paris, 201, 958 (1935).

    CAS  Google Scholar 

  5. Mulliken, R. S., and Rieke, C. A., Rev. Mod. Phys., 14, 259 (1942).

    Article  ADS  Google Scholar 

  6. Basset, J., C.R. Acad. Sci. Paris, 208, 267 (1939); J. Phys. Rad., 10, 217 (1939).

    Google Scholar 

  7. Van Vleck, J. H., J. Chem. Phys., 2, 20, 297 (1934).

    Article  ADS  CAS  Google Scholar 

  8. Long, L. H., and Norrish, R. G. W., Nature, 157, 486 (1946); 158, 237 (1946). Sidgwick, N. V., and Springall, H. D., Nature, 156, 600 (1945). Baughan, E. G., Nature, 147, 542 (1941). Baughan E. G., and Polanyi, M., Nature, 146, 685 (1940).

    Article  ADS  CAS  Google Scholar 

  9. Penney, W. G., Trans. Farad. Soc., 31, 734 (1935).

    Article  CAS  Google Scholar 

  10. Andersen, H. C., and Kistiakowsky, G. B., J. Chem. Phys. 11, 6 (1943). Kistiakowsky, G. B., and Van Artsdalen, E. R., J. Chem. Phys., 12, 479 (1944).

    Article  ADS  CAS  Google Scholar 

  11. Goldfinger, P., Lasareff, W., and Letort, M., C.R. Acad. Sci. Paris, 200, 1593 (1935).

    CAS  Google Scholar 

  12. Kynch, G. J., and Penney, W. G., Proc. Roy. Soc., A, 179, 214 (1941).

    ADS  CAS  Google Scholar 

  13. Duchesne, J., Physica, 10, 817 (1943).

    Article  ADS  CAS  Google Scholar 

  14. Faltings, K., Groth, W., and Harteck, P., Z. Phys. Chem:, B, 41, 15 (1938).

    Google Scholar 

  15. Hagstrum, H. D., and Tate, J. T., Phys. Rev., 59, 354 (1941).

    Article  ADS  CAS  Google Scholar 

  16. Voge, J. Chem. Phys., 4, 581 (1936).

    Article  ADS  CAS  Google Scholar 

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DUCHESNE, J., GOLDFINGER, P. & ROSEN, B. Heat of Atomization of Carbon. Nature 159, 130–131 (1947). https://doi.org/10.1038/159130a0

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