Abstract
THE early X-ray experiments of James, Firth and Waller1 on the modification of the diffracting power of crystals of sodium chloride due to thermal vibrations of the atoms dealt only with the reduction in intensity of the Bragg reflexions at different temperatures, and could therefore only give average root mean square amplitudes, but the more recent diffuse spot methods promise to give information concerning the whole frequency spectrum. By observation of the position, shape and intensity of the diffuse spots when the crystal is turned into a succession of reflecting positions, the effect of vibrations travelling in different directions, polarized in definite ways and with frequencies within known limits, can be traced2,3,4.
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References
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LONSDALE, K. Crystal Dynamics of Rocksalt. Nature 149, 698–699 (1942). https://doi.org/10.1038/149698b0
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DOI: https://doi.org/10.1038/149698b0
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