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Phosphine and Arsine Derivatives of the Group 1(b) Metals: Volatile Derivatives of Gold

Nature volume 140, page 502 (18 September 1937) | Download Citation

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Abstract

WE have shown that the trialkyl phosphine and arsine derivatives of cuprous iodide, previously considered to be R3P(As).CuI, have a fourfold macro-molecule1, [R3P(As)CuI]4, and are therefore tetrakis—[iodo-trialkylphosphine (or arsine)-copper]. A complete X-ray examination of the triethyl-arsine member, [Et3AsCuI]4, showed that the four copper atoms occupy the apices of a regular tetrahedron ; the iodine atoms are situated each above the central point of one face of this tetrahedron, so that they also form a tetrahedron external to that of the copper atoms. Beyond each copper atom is an arsenic atom lying on the elongation of the axis joining the centre of the inner tetrahedron to the copper atom. The iodine atoms are thus 3-covalent, each being joined to the three neighbouring copper atoms apparently by one covalent and two co-ordinate links: if this is so, the stereochemistry of the 3-covalent iodine atom must be similar to that of 3-covalent sulphur, and the iodine atom can be regarded as occupying one apex of a tetrahedron with its valencies directed towards the other three apices.

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References

  1. 1.

    , and , J. Chem. Soc., 1503 (1936).

  2. 2.

    , and , J. Chem. Soc., 775 (1936).

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    and , J. Chem. Soc., 1549 (1935) ; Z. Krist. 96, 435 (1937).

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Affiliations

  1. University Chemical and Crystallographic Laboratories, Cambridge. August 19.

    • F. G. MANN
    •  & A. F. WELLS

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DOI

https://doi.org/10.1038/140502a0

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