Abstract
HÆMOCHROMOGENS catalyse the oxidation of ascorbic acid at a pH. below 7 at which there is no autoxidation of ascorbic acid. We can confirm this result of Barron and co-workers1, but the authors have overlooked that the hæmochromogens also undergo oxidation under these conditions, as first observed by Karrer and co-workers2. The product of this oxidation is verdohæmochromogen, a bile pigment iron compound3.
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References
Barron, E. S. G., De Meio, R. H., Klemperer, F., J. Biol. Chem., 112, 625 (1936).
Karrer, P., v. Euler H., Hellström H., Ark. f. Kern. Miner. Geol., B, 11, No. 6 (1933).
Lemberg, R., Biochem. J., 29, 1322 (1935).
Weiss, J. NATURE, 133, 648 (1934).
Keilin, D., and Hartree, E. F., Proc. Roy. Soc., B, 117, 1 (1934).
Keilin, D., and Hartree, E. F., Proc. Roy. Soc., B, 121, 173 (1936).
Warburg, O., Negelein, E., Haas, E., Biochem. Z., 266, 1 (1933).
Lemberg, R., and Wyndham, R. A., Proc. Roy. Soc. New South Wales, 70, 343 (1936).
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LEMBERG, R., CORTIS-JONES, B. & NORRIE, M. Coupled Oxidation of Ascorbic Acid and Hæmo-chromogens. Nature 139, 1016–1017 (1937). https://doi.org/10.1038/1391016a0
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DOI: https://doi.org/10.1038/1391016a0
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