Abstract
Anisotropic planar polaritons - hybrid electromagnetic modes mediated by phonons, plasmons, or excitons - in biaxial two-dimensional (2D) van der Waals crystals have attracted significant attention due to their fundamental physics and potential nanophotonic applications. In this Perspective, we review the properties of planar hyperbolic polaritons and the variety of methods that can be used to experimentally tune them. We argue that such natural, planar hyperbolic media should be fairly common in biaxial and uniaxial 2D and 1D van der Waals crystals, and identify the untapped opportunities they could enable for functional (i.e. ferromagnetic, ferroelectric, and piezoelectric) polaritons. Lastly, we provide our perspectives on the technological applications of such planar hyperbolic polaritons.
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Introduction
Polaritons are a hybrid of electromagnetic (EM) modes and dipolar excitations, possessing dispersion characteristics that are intermediate between those of the collective excitations of the material and photons1. These polaritons are essential in the fundamental physics and practical applications of light–matter interactions2. Examples of these modes include plasmon, exciton, and phonon polaritons, which have become critical elements of both the standard theoretical description as well as practical applications in photonics and optoelectronics3,4. Of particular importance, there are the surface polaritonic modes. In general, most existing materials support two-dimensional polaritons that have a two-dimensional (2D) isotropic isofrequency contour, thus energy flows in all directions in the plane. However, many applications would greatly benefit from EM modes that possess highly directional and broadband subdiffractional confinement. The resulting search for novel polaritonic modes in new materials lead to the discovery and development of a new class of anisotropic 2D materials that naturally possess such EM modes, in the form of plasmon, exciton and phonon polaritons. Figure 1 illustrates the change of the polaritonic character from the isotropic circular plasmon polariton in graphene5, to the out-of-plane hyperbolic phonon polariton in h-BN6, the elliptical plasmon and exciton polariton in black phosphorus7,8, and even with a change in topology to the planar hyperbolic phonon polariton in α-MoO39, and its canalized and shear variant in its twisted structures and beyond10,11. Particularly important in this class are the hyperbolic polaritons, due to their inherent singularity in the density of states12 and resulting enhancement of light–matter interactions.
Here we discuss the origin of these planar hyperbolic polariton modes, their experimental observations as well as the variety of ways by which their polaritonic properties can be tuned through fabricating heterostructures, applying strain, or utilizing electrostatic gates, intercalation, nanostructuring, hypercrystals and image polaritons. We also review the plethora of novel properties of planar hyperbolic polaritons, such as the unique ray-like propagation, and magic angles corresponding to topological transitions, shear polaritons, longitudinal plasmon spins, and chiral plasmons. Lastly, we provide our perspectives on possible opportunities that new hyperbolic materials with properties, such as ferromagnetic, ferroelectric, and piezoelectric, may offer to fields such as quantum and spin photonics, thermal management, sensing, subwavelength focusing, transformation optics, and polarization engineering.
Hyperbolic polaritons in flatland
Directionally confined EM waves
We shall begin with a brief historical account of directionally confined EM waves. Due to symmetry, directional EM waves can only exist in anisotropic media. The interest in anisotropic dielectrics as a means to confine and collimate light was boosted after Dyakonov found in 198813 that the interface between a non-magnetic isotropic dielectric and a non-magnetic uniaxial crystal supports, under specific conditions, a bound EM mode, known now as a Dyakonov wave (DW). The existence of DW requires stringent conditions on the orientation of the optic axis with respect to the interface, propagation angle of the wave and of the relative values of all of the dielectric constants involved. This combination of demanding dielectric requirements and reduced cone directions made the experimental confirmation of the existence of DWs14 elusive for some time.
An interesting variation occurs when the dielectric semi-infinite region is replaced by a metal, with the other semi-infinite medium still being a non-magnetic uniaxial crystal. Bound EM fields exist in this case and are denoted as Dyakonov plasmons15. Dyakonov plasmons occur within a finite frequency range and only over a narrow range of propagation angles, leading to an open isofrequency curve shaped like a hyperbola. Using these properties, the hyperbolic-like isofrequency curve was used to demonstrate hyperlensing in a system where the uniaxial crystal was a metamaterial16.
The idea of creating a planar hyperbolic metasurface using a thin metallic grating was explored in ref. 17, where it was shown how these structures could be used to control and manipulate surface plasmons in the visible regime. An interesting possibility is to substitute the metal with a 2D semimetal (e.g. graphene) and thus create a hyperbolic metasurface that could operate in other frequency regimes18. It would of course be highly desirable if such hyperbolic plasmons can also exist naturally in 2D materials. A number of uniaxial natural 3D hyperbolic materials have been studied to date, including α-quartz19, hexagonal boron nitride6,20, and others3. However, the possibility of planar hyperbolicity was speculated to be theoretically possible through the interplay between intraband and interband processes21. Since then, a plethora of experiments have uncovered planar hyperbolic polaritons in various 2D materials, with the first report on planar hyperbolic phonon polaritons9,22 in α-MoO3 as illustrated in Fig. 2a–c, followed by similar observations of planar hyperbolic plasmon polariton in WTe223 (see Fig. 2d).
Super-singularity and extreme confinement
Nanoscale light–matter interactions can be tailored through the engineering of the photonic density-of-states or mode volume. The most widely studied among these modes is the plasmon polariton24, which possesses dispersion characteristics that are intermediate between those of electrons and photons. While electrons enable highly miniaturized electronic components for computing and memories, photons offer functionalities such as long-range communication links based on silicon photonics. An EM mode that possesses both of these characteristics would be an ideal bridge between electronics and photonics25. Other well-known approaches include utilizing Mie resonances and photonic crystals, but these approaches are inherently spectrally narrow. A hyperbolic metamaterial, which is known to possess unusual dispersion relations with open iso-frequency surfaces, as shown in Fig. 2b, allows for access to large wavenumbers across broad spectral windows. Hence, their photonic density-of-states is often dubbed a super-singularity26, making possible applications where high optical resolution and sensitivity are desired27. The super-singularity is only curtailed by absorption losses in the material and spatial dispersion i.e. non-local response28.
However, conventional nanostructured hyperbolic metamaterials and metasurfaces have several important limitations29; cutoff in the accessible momenta limited by its physical feature sizes, metallic losses, and the inability for active tuning (for metal-based systems) and difficulty in accessing volume modes for the case of 3D hyperbolic media. Thus, the discovery of natural 2D van der Waals (vdW) materials with natural planar hyperbolic properties provides a significant advance in the effort to create a toolbox for the control of EM fields at the nanoscale.
Biaxial planar hyperbolic media
vdW materials are generally biaxial media where their principal components of the dielectric tensor ϵ are dissimilar. For plane waves eı(k⋅r−ωt) traveling inside an anisotropic medium, the wave equation can be expressed in the form:
where E is the electric field, k and k0 are the wavevectors in the medium and free space respectively and ϵ is the permittivity tensor.
The governing equation for an isofrequency surface, that is, the allowed k vectors for a fixed frequency for plane waves propagating inside a medium, is determined by applying the condition for the nontrivial plane wave solution in Eq. (1). For a diagonal permittivity tensor, this equation is given by
We consider the exemplary anisotropic vdW material α-MoO3 as illustrated in Fig. 2a. Here, due to translational symmetry in the xy plane, one can fix the planar wave-vector and look for allowed kz solutions. Eq. (2) is, in general, a quartic equation in kz and is expected to yield four solutions. For a given wavevector, the group velocity of propagation is given by the normal to the isofrequency surface at that point. As a reminder, the isofrequency surface for usual elliptical materials (i.e. 0 < ϵx ≠ ϵy ≠ ϵz) consists of two closed surfaces, which in general, intersect at four points along the two optic axes. For biaxial hyperbolic media, however, the isofrequency surface becomes highly nontrivial as shown in Fig. 2b. For example, an isofrequency surface with Re[ϵx] < 0 < Re[ϵy], Re[ϵz] consists of a hyperboloid opening along the kx direction.
In the extreme limit of 2D planar hyperbolic surfaces, the optical response is dictated by the surface conductivity tensor21. In this case, the hyperbolicity arises from the difference in the sign of the imaginary part of the diagonal surface conductivity components21. In a slab of planar hyperbolic material, the polariton dispersion is given by30
where n is an integer, t is the slab thickness, ϵ1 and ϵ2 are the permittivities of the surrounding media, k is the polariton wave-vector and \(\psi=\imath \sqrt{{\epsilon }_{z}/({\epsilon }_{x}{\cos }^{2}\alpha+{\epsilon }_{y}{\sin }^{2}\alpha )}\), α being the angle between the x-axis and the polariton wave-vector. For propagating modes, one can impose the condition ℜ{k} > ℑ{k}. This produces the isofrequency surfaces shown in Fig. 2b. The isofrequency surfaces for 2D polaritons are not merely the projection of the 3D isofrequency surfaces. This is because the refractive index of the surrounding media also influences the 2D polariton dispersion.
Physical origin of plasmonic hyperbolicty
The basic mechanism for hyperbolic plasmon was first theorized as due to the interplay between intraband and interband processes21. In metallic systems, the collective motions of free electrons can generate extremely strong optical absorption below the plasma frequency. The ϵimag due to the intraband transition results in a negative ϵreal as shown in Fig. 3a. Although anisotropic materials would in general impose anisotropy on ϵreal, this would not produce hyperbolicity. On the other hand, interband transitions can contribute positive ϵreal, and its dielectric response is in general anisotropic as dictated by the dipole transition matrix. As a result, hyperbolic dielectric tensors can in principle be induced through the interplay of both intraband and interband transitions, as illustrated in Fig. 3a for the prototypical example of WTe223,31.
Since the real (ϵreal) and imaginary (ϵimag) parts of the dielectric function are connected through the Kramers–Kronig relation32,33, ϵimag exhibiting a strong peak absorption at ω0 can result in a negative (or positive) ϵreal for frequencies larger (or smaller). Hence, one essential condition to attain a hyperbolic plasmonic surface in a medium with ϵreal,i × ϵreal,j≠i < 0 is that ϵimag should exhibit strong resonant-like features along at least one of the crystal directions, where subscripts i and j denote the diagonal elements of the dielectric tensor. The spectral weight of ϵimag is characterized by its electric dipole transition matrix elements31.
Planar hyperbolicity via phonons
Optical phonons are quanta of vibrations associated with out-of-phase oscillations of atoms within a unit cell. In polar crystals, such an oscillation can give rise to a net charge dipole that can couple to radiation. It is well-known that the dipole polarizability changes signs as one sweeps the frequency across the dipole resonance frequency34. It is this phenomenon that is ultimately responsible for the change in the sign of the dielectric function near the optical phonon resonant frequency, as illustrated in Fig. 3b for the prototypical example of α-MoO335.
In the context of phonon-based natural planar hyperbolic systems, the crystal anisotropy in the planar direction leads to different optical phonon frequencies in the x and y directions. The optical dielectric permittivity tensor is then given by a Lorentz model of the form35:
where k = x, y and \({\omega }_{{{{{{{{\rm{LO}}}}}}}}}^{k}\), \({\omega }_{{{{{{{{\rm{TO}}}}}}}}}^{k}\) are the longitudinal and transverse optical phonon frequencies in the respective directions and γk is the damping associated with the phonon modes. By definition, a longitudinal (transverse) optical phonon corresponds to the case where the phonon wavevector is parallel (perpendicular) to the direction of oscillation. For frequencies between the LO and TO phonon resonances (called the Reststrahlen band) for say the x direction, Eq. (4) shows that the dielectric tensor component ϵx becomes negative. If these optical phonon frequencies for the x direction are located far away from the ones in the other planar direction y, then ϵy > 0 and planar hyperbolicity results in this system.
Hyperbolicity induced by excitons
Unlike plasmon and phonon–polaritons, finite exciton population requires photo-excitation with a pump beam detuned to the red from the optical gap. When the exciton densities are below the Mott threshold for the condensation into electron-hold liquid, the excitons are well described by the Wannier Mott model of Coulomb-bound electron–hole pairs. The dielectric response of the materials will be influenced by the presence of these excitons. Due to the lower dimensionality of vdW materials, dielectric screening is also reduced, allowing a substantial portion of the electric fields within the bound electron–hole pair to permeate outside of the vdW materials, leading to strong exciton binding energies on the order of 100 meV36.
The excitons produce resonant absorption peaks in the optical spectra, whose spectral weight is given by the exciton oscillator strength. Since the oscillator strength goes inversely with the effective Bohr radius of the exciton, the strongly bounded excitons in 2D lead to very prominent absorption peaks (or ϵimag) compared to their 3D counterparts. Similar hyperbolic dielectric response can might arise in anisotropic 2D semiconducting materials. Figure 3c depicts the calculated optical spectra for monolayer black phosphorus (BP) by means of density function theory in conjunction with solving the Bethe–Salpeter equation for the two-particle Green’s function, which reveals the existence of a hyperbolic window. We shall survey the experiment progress in the observations of these hyperbolic polaritons in the next section.
Experimental observations of planar hyperbolic polaritons in vdW materials
Experiments on planar hyperbolic phonon polaritons
Natural planar hyperbolic polaritons were first observed in α-MoO3 with scattering-type scanning near-field optical microscopy (s-SNOM)9,22,37 and photo-induced force microscopy (PiFM)35. In these techniques, the polariton is launched by a metallized atomic-force microscope tip, allowing the s-SNOM to detect the scattered light intensity, whereas the PiFM measures the optomechanical force at the tip. The measured interference pattern resulting from the tip-scattered outgoing and field reflected from the flake edge or a highly reflective boundary (e.g. metal structure or defect) reveals the wavevector at the excitation laser frequency by taking a Fourier transform of the lines along the polariton propagation direction38, as shown in Fig. 2c. Repeating the process as a function of frequency enables the user to extract the dispersion relationship for the polaritonic modes.
In a follow-up work on α-MoO335, real space images of the concave wavefront of the planar hyperbolic phonon polaritons, as well as the full dispersion, were experimentally extracted. In this experiment, a silver nanowire was used as an antenna to launch the polariton, thereby replacing the role of the s-SNOM tip in polariton excitation. In practice, both types of excitations still occur, however, typically the scattering of the metal antenna dominates. Furthermore, the polariton lifetime in α-MoO3 and α-V2O5 were both measured to be on the order of a few ps35,37 at room temperature, which is of the same order as high-quality graphene plasmon39 and hBN phonon polariton40.
Plasmonic planar hyperbolicity observed
Experimental observation of plasmonic surfaces with planar hyperbolic polaritons was reported in WTe2 thin films23. As shown in Fig. 2d, the WTe2 thin film is in the Td-type phase. Here, the a-axis is defined along the direction parallel to the tungsten chain. The planar anisotropic optical properties of WTe2 thin films were originally probed using polarization-resolved far-field optical absorption (or extinction) measurements23. A rectangle array along the two optical axes of WTe2 films on polycrystalline diamond substrates was fabricated. The ribbon structure provides the required momentum that allows light to couple with the plasmons41, revealed as a resonant absorption peak in its extinction spectra. The resonance along the a direction is much stronger than that along b, and both occur at different resonant frequencies, indicating an anisotropic plasmonic dispersion.
The fitted plasmon dispersion considering only the intraband contributions, follows \(\omega \propto \sqrt{q}\), with good corroboration to the measured plasmon peaks at low energy. As the wave vector increases, the dispersions along both planar axes soften and deviate from the \(\sqrt{q}\) scaling due to the onset of interband transition. The plasmon polariton is only allowed to propagate along the a direction in the frequency range of 429−632 cm−1, indicative of a hyperbolic regime governed by the interband transition21. The isofrequency contours of the plasmon at different energies reveal the topological transition from the elliptic to hyperbolic regimes, as shown in Fig. 2d. Besides the observed mid-infrared hyperbolicity, monolayer WTe2 also exhibits strong anisotropic dielectric tensors at ~1.0 eV, producing a new near-infrared hyperbolicity31, which can be ascribed to the band nesting effect.
Experiments on hyperbolic exciton-polaritons
Due to the contrasting spectral resonance along the crystal axes, planar hyperbolicity is likely to occur around the exciton–polariton frequencies, as suggested by theoretical calculations in Fig. 3c. On the other hand, 3D hyperbolic excitons have been experimentally observed in uniaxial vdW materials. For instance, 2D hybrid perovskites composed of alternating Pb-I octahedral sheets expanding in two dimensions and organic cations have been reported to support hyperbolic exciton polariton in the visible range42, and optically induced excitonic hyperbolicity was also discovered in the layered transition metal dichalcogenide WSe243. Unlike hyperbolic phonon–polaritons, exciton–polaritons, which originate from electronic processes, can be tuned by varying the optical excitation density. This provides a platform for designing on-demand hyperbolicity at infrared frequencies.
Recent far-field light scattering experiments have extracted the optical constants of monolayer BP, revealing that the dielectric response might be due to hyperbolic planar excitons8. From the measured extinction spectra, the dielectric constants along the armchair and zigzag directions can be extracted. In particular, the oscillator strength for the armchair polarization is significantly larger than that in the zigzag, due to the polarization-sensitive nature of the optical transition matrix elements. As a result, a hyperbolic dielectric window was observed across the spectral range from 1.70 to 1.84 eV8. This is consistent with first principle calculations shown in Fig. 3c.
The first experimental observation of in-plane hyperbolic exciton-polaritons (HEPs) was reported in the vdW semiconductor chromium sulfide bromide (CrSBr)44. In CrSBr, in-plane HEPs exhibit wavefronts that develop with oscillatory out-of-plane electric fields propagating through the bulk-like waveguide modes. The existence of HEPs was confirmed through a combination of energy, temperature, and thickness-dependent measurements. Furthermore, CrSBr is an A-type antiferromagnet material below the Néel temperature TN = 132 K, where excitons have been found to couple to magnetic order, providing an additional way to manipulate hyperbolicity by applying magnetic fields.
Engineering planar hyperbolic materials
Lower symmetry shear and ghost polaritons
New opportunities are afforded by pushing to even lower symmetry crystals. While orthorhombic crystals such as α-MoO3 give rise to highly directional polariton propagation, in monoclinic and triclinic systems, novel hyperbolic shear polaritons can be supported. These modes were first reported using the wide bandgap, monoclinic semiconductor β-Ga2O311 using Otto configuration experiments (Fig. 4a), then imaged in real space in both β-Ga2O3 (Fig. 4a) and another monoclinic material CdWO445 via s-SNOM. In triclinic crystals, the three crystallographic axes are not orthogonal, while in monoclinic crystals there is one axis that is not orthogonal to the other two. The implication of this is that the permittivity tensor cannot be diagonalized, and thus, off-diagonal real and imaginary contributions to the tensors are induced. With the monoclinic axis within the plane of the crystal surface (e.g. the (010) surface of β-Ga2O3), the loss of mirror symmetry also results in a breaking of the symmetry in the polariton dispersion (Fig. 4a).
While originally observed within a bulk crystal, exfoliation of β-Ga2O3 is possible, in conjunction with a plethora of monoclinic and triclinic 2D materials. As free-carrier injection into semiconductors can introduce an amplification of off-diagonal loss contribution, it provides a means to dictate the polariton shear and tilted wavefront via electrostatic gating and/or optical pumping to control polariton propagation for on-chip photonics.
The surface of uniaxial crystals whose optic axis is tilted with respect to the surface normal (Fig. 4b) can then accommodate the ghost polariton46—the special case of the electromagnetic ghost wave47. These ghost polaritons feature a hyperbolic character that is both propagating as well as evanescent in the crystal bulk, leading to slanted phase wavefronts. Engineering the dispersion of ghost polaritons using off-cut calcite crystals has revealed propagation lengths up to 20 μm (Fig. 4b), providing new opportunities for nanoscale wave manipulation46.
Twisted bilayers and magic angles
There has been recent interest in a new type of polaritonic topological transition using twisted bilayers of planar hyperbolic materials48. The topological transition from hyperbolic to elliptical states occurs at so-called ‘magic angles’, in close analogy to the newly emerging field of twistronics in condensed matter49. The basic principle relies on the variation of the number of crossing points between the hyperbolic isofrequency surfaces of the top and bottom layers as a function of the twist angle48. Due to the interaction between polaritons, these degeneracy points in k-space create an anti-crossing. The number of these anti-crossing points (NACP) governs whether the topology of the isofrequency surface of the twisted bilayer polariton is elliptical or hyperbolic. At the twist angle corresponding to the topological transition (referred to as the ‘magic angle’), the polariton propagation occurs in the canalization regime where a highly directional diffraction-less propagation is observed, as shown in Fig. 4c, realized in α-MoO3. This phenomenon is topological in the sense that the opening or closing of the isofrequency surface and the magic angle features are not influenced by disorder or imperfections but only by the topological index NACP in k-space.
Twisted polaritonics can also inherit other new optical properties. For example, chiral plasmons in twisted atomic bilayers are featured with a unique phase relationship of ±π/2 phase difference between their transverse-electric and transverse-magnetic wave components50. Such a unique phase relationship for chiral plasmons can lead to unconventional longitudinal spin of plasmons50, besides the usual transverse spin of plasmons51. Looking forward, it is anticipated that other emergent phenomena might arise from twisted hyperbolic polaritonics.
Tuning via metal ion intercalations
Recently efforts have also been geared towards demonstrating the active tunability of planar hyperbolic phonon polaritons in 2D materials, with particular emphasis on polariton switching applications. Since the interlayer distance in α-MoO3 single crystals is quite large, metal ion intercalation offers a potentially effective tuning knob. This technique was demonstrated for the first time via Sn ion intercalation in α-MoO39. Intercalation can modify the phonon polaritons in three ways. First, this results in lattice distortion, in particular the expansion of the vertical Mo–O bond, which in turn modifies the out-of-plane vibrational modes. Secondly, the Sn ions might act as scattering centers for phonon polaritons resulting in their increased damping. Thirdly, the Sn intercalation results in the introduction of free electronic carriers in α-MoO3 via doping, potentially enabling the excitation of plasmon modes, which are inherently lossier, as well as the potential for plasmon–phonon polariton coupling. Similar efforts using sodium ion intercalation have also been shown to result in tunable Reststrahlen bands in α-V2O5 (see Fig. 4d) providing frequency shifts as large as 30 cm−137, with no significant deterioration of polariton lifetimes being observed. Subsequently, a reversible tuning of these planar hyperbolic phonon polaritons was also demonstrated via hydrogen intercalation in CVD-grown films52.
Hypercrystals
Photonic hypercrystals (PHCs) represent a new class of artificial photonic media distinct from the more widely used systems: metamaterials and photonic crystals53. In fact, the PHCs take on the best of both and offer unprecedented control over light propagation and light-matter interactions. The unit cells are sub-wavelength in dimension, yet their response is markedly distinct from the effective medium response seen in metamaterials. This distinction has been exploited to overcome some of the limitations of metamaterials such as out-coupling issues54 and the prediction of Dirac physics and singularities55.
Hypercrystals in 2D vdW materials can be realized by introducing a periodic modulation of the hyperbolic medium through twisting and dielectric modulation. A schematic of the Moire pattern and the associated modulation of hyperbolic (H) and dielectric (D) regimes are provided in Fig. 4e. Further work is needed to establish the guiding principles governing the tuning parameters to realize such a modulation. Indeed, local changes in the environment56, where refraction of hyperbolic phonon polaritons, were achieved using the phase change material VO2. In that work, by working close to the phase transition temperature, local domains of dielectric and metallic VO2 coexisted, causing the wavevector of the hyperbolic modes to be locally modulated56. Further work illustrated the potential of this approach for realizing reconfigurable metasurfaces, via placing the 2D hyperbolic material on a pre-patterned dielectric substrate as shown schematically in Fig. 4f or by directly patterning features into the medium57 as shown in Fig. 4g.
Heterostructures for hybrid polaritons
The advent of vdW materials has enabled the ability to design and fabricate versatile heterostructures with atomic-level precision stacking. In h-BN-based vdW heterostructures, hyperbolic polaritons can be dynamically tuned when placed onto graphene58 and phase change materials59,60. There have been several recent efforts in achieving the tunability of planar hyperbolic phonon polaritons in α-MoO3 by coupling them to graphene plasmons61,62,63. On the other hand, the character of plasmon and exciton–polaritons are amenable to the influence of electric fields, via carrier doping or band bending, allowing for dynamic electric control of their ray-like propagations21. Such ray-like propagation is at the heart of applications such as hyperlensing64 and controllable nanoscale focusing65, to be discussed later.
In addition, other emerging physical properties in vdW systems, including superconductivity49, magnetism66, and ferroelectricity67 may also couple with natural hyperbolic polaritons for augmented functionality of these nano-optical modes. Practical examples include natural hyperbolic materials with 2D ferroelectric and/or ferromagnetic substrates illustrated in Fig. 4h, where the strong hysteresis can be exploited for polariton memory. We will revisit these emerging new functional materials in the next section.
Hyperbolic image polaritons
When polaritons in a vdW material couple with their image charges across a tiny dielectric gap, a virtual mode called an image polariton68 can be formed. One possible scheme utilizes a mirror plane that is separated from a vdW film by a nanometer-thin insulator (see Fig. 4i–4k). In this configuration, a polariton mode coupled with its image charge distribution can enhance the field confinement inside the nanometric gap. Image polaritons in vdW materials have been the focus of intense research as they can provide extreme light confinement beyond what is possible with conventional metal-based plasmons. However, such tight confinement leads to large momentum mismatches with free-space photons and also increased optical losses. Hyperbolic image phonon polaritons in hBN can address both of these challenges and have been shown to exhibit effective refractive index of up to 132 and quality factors as high as 500 in isotopically enriched hBN68.
The key advantage of this approach is that unpatterned pristine vdW materials can be used in contrast to other resonator designs based on patterned vdW structures. Since 2D polaritons are tightly confined, it is crucial to minimize unwanted surface roughness and etch-induced damage during the fabrication process. The fabrication of the multi-layer substrate, which includes metal ribbons, an optical spacer, and a reflector, was accomplished via a template-stripping process68 to create ultraflat metal surfaces69. The optical spacer and the reflector further boost the coupling efficiency by recycling the transmitted waves back to the image polaritons when the quarter-wavelength condition is satisfied. A similar strategy can be used to harness planar hyperbolic image polaritons toward efficiently launching ultra-low-loss and ultra-compressed polariton modes.
Functional hyperbolic materials
Besides the foregoing 2D materials, we anticipate many potential candidates that exhibit planar hyperbolicity in the class of vdW materials. Selected 2D materials with planar structural anisotropy are shown in Fig. 5, which have all been exfoliated from their known bulk crystal form70. More interesting are the diverse functional properties that many of these materials possess, such as ferromagnetism, ferroelectricity, piezoelectricity and thermoelectricity. In Fig. 5, we sort these materials according to their bandgaps that span across the metallic to semiconducting and insulating range, potentially hosting various polaritons across different spectral ranges.
Ferromagnetic biaxial vdW crystals
Ferromagnetic orderings offer a novel route to modulating the plasmonic modes through magneto-optical effects71 and open up the possibility of non-volatile tuning of plasmon polaritons via the magnetization induced in the host material. As experimentally observed, the plasmon-polariton wavevector can be effectively modulated by switching the direction of the magnetization71. Most notably, magnetized materials have been demonstrated to enable breaking of time-reversal symmetry to introduce non-reciprocity72. Moreover, excitation of the surface plasmon polariton was also shown to depend on the magneto-optical properties of the medium73. Magneto-optic and non-reciprocal effects with magnetic materials offer broad promise for enriching the physics of hyperbolic polaritons such as enabling the selective directional control of the hyperbolic rays74.
As shown in Fig. 5, CrSe2, VSe2, CrTe2, VBr2, and FeCl270 are 2D ferromagnetic materials and adopt the structure characterized by edge-sharing octahedra75. Their frequency-dependent dielectric functions have been found to display linear optical birefringence76. CrI2 is also a vdW ferromagnetic material with the same 1T\({}^{{\prime} }\) crystal structure as WTe2. It is antiferromagnetic at the monolayer limit, but it can transition to ferromagnetic as the layer thickness increases due to interlayer vdW interactions77. It is worth mentioning that most of the 2D ferromagnetic materials possess relatively low intrinsic Curie temperature, but monolayer 1T-VSe2 has been found to retain ferromagnetic ordering above room temperature78. These new magneto-optic materials, with their potential for hyperbolic polaritons, can be the basis for a new class of polaritonic memories.
Ferroelectric biaxial vdW crystals
Ferroelectric materials are known to host soft optical phonon modes accompanied by large dipole moments. Hence, anisotropic vdW ferroelectric materials offer fertile ground for tunable hyperbolic polaritons in the far infrared79. GeS, SnS, GeSe, SnSe, and GaTeCl80 have all been predicted to display spontaneous room-temperature ferroelectricity in the monolayer limit based on first-principle simulations. Subsequently, ferroelectricity at the monolayer limit in SnTe, SnS, and SnSe were confirmed through electron microscopy images and spatially resolved differential conductance spectra81,82. In particular, the robust planar polar distortion80,83 in these materials is responsible for the structural, electronic, and optical planar anisotropy84.
Phonon polaritons in ferroelectric materials should in general exhibit wider Reststrahlen bands, owing to the larger splitting between the longitudinal and transverse optic phonon modes79. This is the result of the large Born effective charge associated with the enhanced polarization in ferroelectric materials. A larger Reststrahlen band would imply hyperbolic phonon polaritons that can be supported over a larger spectral bandwidth. In a similar fashion to magnetic materials, the polariton dispersion and damping are observed to be strongly influenced by the polar phonons, due to the cross-anharmonic couplings between ferroelectric modes and normal-mode lattice vibrations79. In addition, the remnant ferroelectric polarization can also drive carrier modulation in a semimetal 2D layer on a ferroelectric substrate via electrostatic doping85. Hence, both plasmon and phonon polaritons are controllable with applied electric fields, mediated by the polarization modulation.
One-dimensional vdW materials
We also searched the class of quasi-one-dimensional (quasi-1D) materials, as illustrated in Fig. 5. In these materials, the atoms are strongly bonded by covalent or ionic bonds along the intrachain direction but mediated by weak vdW forces along the interchain direction, which results in significantly anisotropic electronic, and structural properties. For example, K2Cr3As386, Cs2Cr3As387 and Tl2Mo6Se688 were experimentally found to possess quasi-1D ferromagnetic ordering and display anisotropic superconductivity, magnetoresistance, and electronic transport. A series of quasi-1D ferroelectric materials BaTiS389, BaVS390 and WOBr491 have been found to develop robust ferroelectric distortions within each chain unit.
Similar to the aforementioned functional 2D vdW materials, the quasi-1D ferromagnetic, ferroelectric and piezoelectric materials may exhibit even stronger anisotropic optical properties89. Moreover, another possible hyperbolic quasi-1D material is the two-dimensional ordered carbon nanotube film that has been crystallized through a simple vacuum filtration technique92. Low-dimensional plasmons originated from longitudinal charge oscillations enable high-quality terahertz and infrared optical applications at deep subwavelength scales93. Metallic single-walled carbon nanotubes were also experimentally observed to develop Luttinger-liquid plasmons that exhibit extraordinary spatial confinement and high-quality factor94.
Potential applications
Quantum and spin photonic applications
For applications such as quantum photonic nodes, highly efficient coherent energy transfer and quantum simulators95,96, engineering the interaction between multiple quantum emitters is a key prerequisite95. Here, 2D planar hyperbolic polaritons are uniquely suited as reconfigurable one-dimensional waveguides mediating long-range dipole–dipole interactions and entanglement97. This has interesting implications for developing on-chip architectures for quantum information processing, significantly reducing the fabrication constraints.
Recent studies have shown that the light emission of a quantum emitter placed atop a 2D hyperbolic (Fig. 6a), can be selectively channeled into particular hyperbolic modes through prudent control of the emitter polarization74. For efficient routing of the quantum emitter spin states into these photonic modes, an important direction to pursue is in the development of 2D hyperbolic material-based devices that can exhibit a helicity-dependent response98.
In free space, the spin of the photon is always collinear with the direction of propagation. For surface waves on isotropic 2D materials, due to the electric (TM) or magnetic (TE) fields rotating in the plane perpendicular to the interface, the spin angular momentum is instead transverse to the wave vector99. When two quantum emitters are placed near a 2D material, they interact via surface waves supported by this material. However, due to the spin-momentum locking of these surface waves, such interaction will depend on the orientation of the spin of these quantum emitters and will therefore be asymmetric due to the coupling with the momentum direction. A critical and unique functionality is offered by 2D hyperbolic materials—the ability to electrically tune the spin angular momentum of surface waves from transverse to longitudinal99. Figure 6b depicts the vision of the dynamical control of the interaction in say, one-dimensional arrays of quantum emitters100 placed on the surface of these 2D hyperbolic materials—a key platform for the realization of quantum information processing protocols100,101.
Thermal photonic applications
With the miniaturization of electronic circuits, the heat transfer between two components in the sub-wavelength vicinity of each other will strongly deviate from Stefan–Boltzmann law102. The control of radiative heat flow at the nanoscale is an important area of application for 2D materials103. Near-field radiative heat transfer via surface EM modes enables extremely efficient energy transport exceeding the black body limit104,105. The driving applications include high-temperature coatings, near-field thermophotovoltaics, radiative cooling and heat sinks106. The use of hyperbolic phonon polaritons might lead to super-Planckian near-field thermal emission103, a subject that is of great current interest107. In recent work, systematic thermal transport measurements confirm the remarkable heat conduction mediated by surface phonon polaritons in SiC nanowires108. One tool for observing and measuring this effect would be near-field thermal emission spectroscopy where a near-field heated tip thermally excites hyperbolic modes and studies their spectral distribution (Fig. 6c).
Comparing the near-field radiative heat transfer between two uniaxial hyperbolic crystals and two biaxial hyperbolic materials has revealed the superiority of the latter case. For instance, it has been shown that the near-field radiative heat flux between two α-MoO3 flakes at a vacuum gap of 20 nm is about 2200 kW m−2, which is an order of magnitude larger than the flux between two hBN crystals by an order of magnitude109. Twist engineering of planar hyperbolic materials would also offer interesting avenues to near-field thermal effects. In the far field, super-Planckian thermal emission is not possible, however, 2D planar hyperbolic media could provide unique spin-resolved thermal emission110, an effect that has yet to be observed experimentally.
Sensing applications
The vibrational spectrum of a substance in the mid-infrared range provides a unique fingerprint enabling its chemical identification. As a rule of thumb, the stronger the polaritonic field confinement, the more sensitive the sensor is to minute changes in the nearby dielectric environment. 2D materials provide a very promising platform for sensing as they support extremely confined polaritons111. Moreover, many 2D polaritons appear in the mid-infrared regime (3–20 μm), where most molecular vibrational or rovibrational (for gases) excitations occur (Fig. 6d). Since in planar hyperbolic materials, the polaritons can be guided along effective 1D channels, these could be used to sense molecules at specific locations on the 2D sheet. In principle, it is possible to have an actively tunable sensor that can provide location-specific information about the target molecule orientation and position, as well as their identification112,113. Since the quasi-transverse magnetic hyperbolic mode is much more strongly confined compared to quasi-transverse electric modes114, the light–matter interaction is dominated by the former.
Recently, materials that support hyperbolic phonon polaritons (like h-BN) are being considered, due to their higher quality factor and the potential of ultra-high EM confinement. In a recent work115, arrays of hBN resonators (made with monoisotopic boron (B10 or B11) to reduce isotope scattering), were covered with a 10 nm thin layer of organic molecules 4,4\({}^{{\prime} }\)-bis(N-carbazolyl)-1,1\({}^{{\prime} }\)-biphenyl(CBP), that features a C–N vibrational absorption band at 1450 cm−1, which is within one of the h-BN Reststrahlen bands. Moreover, the experiments showed that CBP vibrations and h-BN polaritons were in a strong coupling regime. On the other hand, twisted bilayers of 2D hyperbolic materials can also be an appealing platform for near-field chiral plasmons and chiral sensing, since the physical chirality naturally breaks all mirror plane symmetry. Theoretical studies in twisted bilayer graphene suggest strong near-field chirality116.
Subwavelength focusing and transformation optics
A unique type of subwavelength focusing (Fig. 6e) via planar hyperbolic materials was proposed35. Simulations have shown35 that depending on the polarization of the excitation beam, the image is composed of anisotropic wavefronts, whose shape is determined by the group velocity direction of the isofrequency surface. While such phenomena can be observed with elliptical materials as well, the subwavelength resolution offers a unique capability of hyperbolic systems as shown in Fig. 6e. Such polarization-dependent focusing could lead to new applications in light trapping and photodetection117,118. Recently, there have also been demonstrations of subwavelength focusing of planar hyperbolic polaritons, where using α-MoO3, as a polaritonic hyperlens, a resolution of λ0/50 and a bend-free refraction was shown119, where λ0 is the free space wavelength.
Graphene was the first 2D material that was shown to be an excellent candidate for realizing transformation optics devices owing to the gate tunability of its optical conductivity with nanoscale precision120. The field has its origins in Einstein’s general theory of relativity, where the form invariance of Maxwell’s equations under coordinate transformations can be represented as changes in the permittivity and permeability tensors121. Hence it is intriguing to be able to realize tunable and anisotropic forms of these constitutive parameters for universal transformation optics.
Polarization and emission engineering
Planar hyperbolic media are most relevant in the development of ultrathin polarization controllers as shown in Fig. 6f122,123,124. Size is a bottleneck in traditional polarization controllers, for instance, a state-of-the-art quarter-wave plate uses bulky linear birefringent crystals, since it requires a significant propagation distance to establish the phase difference between orthogonal polarizations. Recent work has shown that stacks of anisotropic vdW materials can facilitate the building of optical elements with Jones matrices of unitary, Hermitian, non-normal, singular, degenerate, and defective classes. These twisted stacks with electrostatic control can function as arbitrary-birefringent wave-plates or arbitrary polarizers with tunable degrees of non-normality, which in turn gives access to a plethora of polarization transformers including rotators, pseudorotators, symmetric and ambidextrous polarizers125.
An interesting application of planar hyperbolic materials is in the development of nonreciprocal spontaneous emission enhancement, opening the door for non-inverse dynamics between degenerate transitions in quantum emitters and coherence generation via anisotropic vacuum126. In the context of valleytronics127, it is known that the two valleys in gapped Dirac materials emit circularly polarized photons with opposite helicity. However, if these two valleys are not coherently excited, the degree of linear polarization at the output can be very low128. In order to overcome this problem, it has been shown that placing these gapped Dirac materials in the near field of planar hyperbolic materials such as α-MoO3 can result in the spontaneous generation of coherence between the two valley states without the requirement of any external coherent laser source for excitation62,129. This is an outcome of the extreme anisotropy of planar hyperbolic materials, which makes the EM vacuum anisotropic resulting in modifications of the respective spontaneous emission rates130.
Conclusions and outlook
In summary, planar hyperbolic polaritons in vdW materials represent an interesting new frontier in nanophotonics, featuring highly directional and confined EM modes with ray-like character on a planar medium allowing for active tunability and ease of coupling to these modes from free space. Planar nanophotonics is appealing as today’s silicon electronics and photonics are based on planar technologies. Looking forward, we have identified the vast engineering space of these planar hyperbolic modes, their new and emerging optical physics, their most promising and interesting applications, and the untapped opportunities that new functional vdW materials can offer to this field. In fact, planar hyperbolic polaritons should be the norm in low-symmetry biaxial or uniaxial vdW materials, and polaritons in many of these materials have yet to be explored. Since these polaritons generally reside in the infrared, access to large areas of vdW materials is essential for most polariton experiments. Polaritonic loss remains an outstanding issue and should be addressed for practical applications. Besides continual improvements in vdW materials growth quality, loss mitigation strategies such as isotropic engineering131 and gain media132 are viable approaches.
References
Basov, D. N., Asenjo-Garcia, A., Schuck, P. J., Zhu, X. & Rubio, A. Polariton panorama. Nanophotonics 10, 549–577 (2021).
Landau, L. D. & Lifshitz, E. M. Electrodynamics of Continuous Media (Pergamon, New York, 1984).
Low, T. et al. Polaritons in layered two-dimensional materials. Nat. Mater. 16, 182–194 (2017).
Basov, D., Fogler, M. & De Abajo, F. G. Polaritons in van der waals materials. Science 354, aag1992 (2016).
Chen, J. et al. Optical nano-imaging of gate-tunable graphene plasmons. Nature 487, 77–81 (2012).
Caldwell, J. D. et al. Sub-diffractional volume-confined polaritons in the natural hyperbolic material hexagonal boron nitride. Nat. Commun. 5, 5221 (2014).
Zhang, Y., Yi, H.-L. & Tan, H.-P. Near-field radiative heat transfer between black phosphorus sheets via anisotropic surface plasmon polaritons. ACS Photonics 5, 3739–3747 (2018).
Wang, F. et al. Prediction of hyperbolic exciton-polaritons in monolayer black phosphorus. Nat. Commun. 12, 5628 (2021).
Zheng, Z. et al. Highly confined and tunable hyperbolic phonon polaritons in van der Waals semiconducting transition metal oxides. Adv. Mater. 30, 1705318 (2018).
Hu, G. et al. Topological polaritons and photonic magic angles in twisted α-MoO3 bilayers. Nature 582, 209–213 (2020).
Matson, J. et al. Controlling the propagation asymmetry of hyperbolic shear polaritons in beta-gallium oxide. Nat. Commun. 14, 5240 (2023).
Smolyaninov, I. I. & Narimanov, E. E. Metric signature transitions in optical metamaterials. Phys. Rev. Lett. 105, 067402 (2010).
D’yakonov, M. New type of electromagnetic wave propagating at an interface. Sov. Phys. JETP 67, 714–716 (1988).
Takayama, O., Crasovan, L., Artigas, D. & Torner, L. Observation of Dyakonov surface waves. Phys. Rev. Lett. 102, 043903 (2009).
Jacob, Z. & Narimanov, E. E. Optical hyperspace for plasmons: Dyakonov states in metamaterials. Appl. Phys. Lett. 93, 221109 (2008).
Smolyaninov, I. I., Hung, Y.-J. & Davis, C. C. Magnifying superlens in the visible frequency range. Science 315, 1699–1701 (2007).
High, A. A. et al. Visible-frequency hyperbolic metasurface. Nature 522, 192–196 (2015).
Gomez-Diaz, J. S. & Alu, A. Flatland optics with hyperbolic metasurfaces. ACS Photonics 3, 2211–2224 (2016).
Estevâm da Silva, R. et al. Far-infrared slab lensing and subwavelength imaging in crystal quartz. Phys. Rev. B 86, 155152 (2012).
Dai, S. et al. Tunable phonon polaritons in atomically thin van der Waals crystals of boron nitride. Science 343, 1125–1129 (2014).
Nemilentsau, A., Low, T. & Hanson, G. Anisotropic 2D materials for tunable hyperbolic plasmonics. Phys. Rev. Lett. 116, 066804 (2016).
Ma, W. et al. In-plane anisotropic and ultra-low-loss polaritons in a natural van der Waals crystal. Nature 562, 557–562 (2018).
Wang, C. et al. Van der Waals thin films of WTe2 for natural hyperbolic plasmonic surfaces. Nat. Commun. 11, 1158 (2020).
Maier, S. A. et al. Plasmonics: Fundamentals and Applications (Springer, 2007).
Ozbay, E. Plasmonics: merging photonics and electronics at nanoscale dimensions. Science 311, 189–193 (2006).
Cortes, C. L. & Jacob, Z. Photonic analog of a van Hove singularity in metamaterials. Phys. Rev. B 88, 045407 (2013).
Poddubny, A., Iorsh, I., Belov, P. & Kivshar, Y. Hyperbolic metamaterials. Nat. Photonics 7, 948 (2013).
Yan, W., Wubs, M. & Mortensen, N. A. Hyperbolic metamaterials: Nonlocal response regularizes broadband supersingularity. Phys. Rev. B 86, 205429 (2012).
Narimanov, E. E. & Kildishev, A. V. Naturally hyperbolic. Nat. Photonics 9, 214–216 (2015).
Kumar, A., Low, T., Fung, K. H., Avouris, P. & Fang, N. X. Tunable light–matter interaction and the role of hyperbolicity in graphene–hBN system. Nano Lett. 15, 3172–3180 (2015).
Wang, H. & Low, T. Hyperbolicity in two-dimensional transition metal ditellurides induced by electronic bands nesting. Phys. Rev. B 102, 241104 (2020).
Cardona, M. & Peter, Y. Y. Fundamentals of Semiconductors (Springer, 2005).
Li, Y. et al. Measurement of the optical dielectric function of monolayer transition-metal dichalcogenides: MoS2, MoSe2, WS2, and WSe2. Phys. Rev. B 90, 205422 (2014).
Born, M. & Huang, K. Dynamical Theory of Crystal Lattices (Clarendon Press, 1954).
Zheng, Z. et al. A mid-infrared biaxial hyperbolic van der Waals crystal. Sci. Adv. 5, eaav8690 (2019).
Wang, G. et al. Colloquium: excitons in atomically thin transition metal dichalcogenides. Rev. Mod. Phys. 90, 021001 (2018).
Taboada-Gutiérrez, J. et al. Broad spectral tuning of ultra-low-loss polaritons in a van der Waals crystal by intercalation. Nat. Mater. 19, 964–968 (2020).
Folland, T. G., Nordin, L., Wasserman, D. & Caldwell, J. D. Probing polaritons in the mid- to far-infrared. J. Appl. Phys. 125, 191102 (2019).
Ni, G. et al. Fundamental limits to graphene plasmonics. Nature 557, 530–533 (2018).
Tamagnone, M. et al. High quality factor polariton resonators using van der Waals materials. arXiv:1905.02177 (2019).
Yan, H. et al. Damping pathways of mid-infrared plasmons in graphene nanostructures. Nat. Photonics 7, 394–399 (2013).
Guo, P. et al. Hyperbolic dispersion arising from anisotropic excitons in two-dimensional perovskites. Phys. Rev. Lett. 121, 127401 (2018).
Sternbach, A. et al. Programmable hyperbolic polaritons in van der Waals semiconductors. Science 371, 617–620 (2021).
Ruta, F. et al. Hyperbolic exciton polaritons in a van der Waals magnet. Preprint at https://doi.org/10.21203/rs.3.rs-3239594/v1 (2023).
Hu, G. et al. Real-space nanoimaging of hyperbolic shear polaritons in a monoclinic crystal. Nat. Nanotechnol. 18, 64–70 (2023).
Ma, W. et al. Ghost hyperbolic surface polaritons in bulk anisotropic crystals. Nature 596, 362–366 (2021).
Narimanov, E. Ghost resonance in anisotropic materials: negative refractive index and evanescent field enhancement in lossless media. Adv. Photonics 1, 1 (2019).
Sheinfux, H. H. & Koppens, F. H. L. The rise of twist-optics. Nano Lett. 20, 6935–6936 (2020).
Cao, Y. et al. Unconventional superconductivity in magic-angle graphene superlattices. Nature 556, 43–50 (2018).
Lin, X. et al. Chiral plasmons with twisted atomic bilayers. Phys. Rev. Lett. 125, 077401 (2020).
Rodríguez-Fortuño, F. J. et al. Near-field interference for the unidirectional excitation of electromagnetic guided modes. Science 340, 328–330 (2013).
Wu, Y. et al. Chemical switching of low-loss phonon polaritons in α-MoO3 by hydrogen intercalation. Nat. Commun. 11, 2646 (2020).
Narimanov, E. E. Photonic hypercrystals. Phys. Rev. X 4, 041014 (2014).
Galfsky, T., Gu, J., Narimanov, E. E. & Menon, V. M. Photonic hypercrystals for control of light–matter interactions. Proc. Natl Acad. Sci. 114, 5125–5129 (2017).
Narimanov, E. E. Dirac dispersion in photonic hypercrystals. Faraday Discuss. 178, 45–59 (2015).
Fali, A. et al. Refractive index-based control of hyperbolic phonon-polariton propagation. Nano Lett. 19, 7725–7734 (2019).
Zhang, X. et al. Guiding of visible photons at the ångström thickness limit. Nat. Nanotechnol. 14, 844–850 (2019).
Dai, S. et al. Graphene on hexagonal boron nitride as a tunable hyperbolic metamaterial. Nat. Nanotechnol. 10, 682–686 (2015).
Dai, S. et al. Phase-change hyperbolic heterostructures for nanopolaritonics: a case study of hBN/VO2. Adv. Mater. 31, 1900251 (2019).
Chaudhary, K. et al. Polariton nanophotonics using phase-change materials. Nat. Commun. 10, 4487 (2019).
Zeng, Y. et al. Tailoring topological transitions of anisotropic polaritons by interface engineering in biaxial crystals. Nano Lett. 22, 4260–4268 (2022).
Bapat, A., Dixit, S., Gupta, Y., Low, T. & Kumar, A. Gate tunable light–matter interaction in natural biaxial hyperbolic van der Waals heterostructures. Nanophotonics 11, 2329–2340 (2022).
Álvarez-Pérez, G. et al. Active tuning of highly anisotropic phonon polaritons in van der Waals crystal slabs by gated graphene. ACS Photonics 9, 383–390 (2022).
He, M. et al. Ultrahigh-resolution, label-free hyperlens imaging in the mid-IR. Nano Lett. 21, 7921–7928 (2021).
Hu, H. et al. Doping-driven topological polaritons in graphene/α-MoO3 heterostructures. Nat. Nanotechnol. 17, 940–946 (2022).
Gibertini, M., Koperski, M., Morpurgo, A. & Novoselov, K. Magnetic 2D materials and heterostructures. Nat. Nanotechnol. 14, 408–419 (2019).
Wang, C., You, L., Cobden, D. & Wang, J. Towards two-dimensional van der waals ferroelectrics. Nat. Mater. 22, 542 (2023).
Lee, I.-H. et al. Image polaritons in boron nitride for extreme polariton confinement with low losses. Nat. Commun. 11, 3649 (2020).
Nagpal, P., Lindquist, N. C., Oh, S.-H. & Norris, D. J. Ultrasmooth patterned metals for plasmonics and metamaterials. Science 325, 594–597 (2009).
Mounet, N. et al. Two-dimensional materials from high-throughput computational exfoliation of experimentally known compounds. Nat. Nanotechnol. 13, 246–252 (2018).
Belotelov, V. et al. Enhanced magneto-optical effects in magnetoplasmonic crystals. Nat. Nanotechnol. 6, 370–376 (2011).
Sounas, D. L. & Alu, A. Non-reciprocal photonics based on time modulation. Nat. Photonics 11, 774–783 (2017).
Belotelov, V., Doskolovich, L. & Zvezdin, A. Extraordinary magneto-optical effects and transmission through metal-dielectric plasmonic systems. Phys. Rev. Lett. 98, 077401 (2007).
Nemilentsau, A., Stauber, T., Gómez-Santos, G., Luskin, M. & Low, T. Switchable and unidirectional plasmonic beacons in hyperbolic two-dimensional materials. Phys. Rev. B 99, 201405 (2019).
Botana, A. S. & Norman, M. R. Electronic structure and magnetism of transition metal dihalides: Bulk to monolayer. Phys. Rev. Mater. 3, 044001 (2019).
Reshak, A. H. & Auluck, S. Electronic and optical properties of the 1T phases of TiS2, TiSe2, and TiTe2. Phys. Rev. B 68, 245113 (2003).
Zhang, J., Yang, J., Lin, L. & Zhu, J. An antiferromagnetic two-dimensional material: chromium diiodides monolayer. J. Semicond. 41, 122502 (2020).
Bonilla, M. et al. Strong room-temperature ferromagnetism in VSe2 monolayers on van der Waals substrates. Nat. Nanotechnol. 13, 289–293 (2018).
Bakker, H., Hunsche, S. & Kurz, H. Coherent phonon polaritons as probes of anharmonic phonons in ferroelectrics. Rev. Mod. Phys. 70, 523 (1998).
Fei, R., Kang, W. & Yang, L. Ferroelectricity and phase transitions in monolayer group-IV monochalcogenides. Phys. Rev. Lett. 117, 097601 (2016).
Higashitarumizu, N. et al. Purely in-plane ferroelectricity in monolayer sns at room temperature. Nat. Commun. 11, 2428 (2020).
Chang, K. et al. Microscopic manipulation of ferroelectric domains in snse monolayers at room temperature. Nano Lett. 20, 6590 (2020).
Chang, K. et al. Discovery of robust in-plane ferroelectricity in atomic-thick SnTe. Science 353, 274–278 (2016).
Huang, L., Wu, F. & Li, J. Structural anisotropy results in strain-tunable electronic and optical properties in monolayer GeX and SnX (X = S, Se, Te). J. Chem. Phys. 144, 114708 (2016).
Jin, D., Kumar, A., Hung Fung, K., Xu, J. & Fang, N. X. Terahertz plasmonics in ferroelectric-gated graphene. Appl. Phys. Lett. 102, 201118 (2013).
Watson, M. et al. Multiband one-dimensional electronic structure and spectroscopic signature of Tomonaga–Luttinger liquid behavior in K2Cr3As3. Phys. Rev. Lett. 118, 097002 (2017).
Tang, Z.-T. et al. Superconductivity in quasi-one-dimensional Cs2Cr3As3 with large interchain distance. Sci. China Mater. 58, 16–20 (2015).
Nakayama, K. et al. Observation of Dirac-like energy band and unusual spectral line shape in quasi-one-dimensional superconductor Tl2Mo6Se6. Phys. Rev. B 98, 140502 (2018).
Niu, S. et al. Giant optical anisotropy in a quasi-one-dimensional crystal. Nat. Photonics 12, 392–396 (2018).
Jiang, X. & Guo, G. Electronic structure and exchange interactions in BaVS3. Phys. Rev. B 70, 035110 (2004).
Lin, L.-F., Zhang, Y., Moreo, A., Dagotto, E. & Dong, S. Quasi-one-dimensional ferroelectricity and piezoelectricity in WOX4 halogens. Phys. Rev. Mater. 3, 111401 (2019).
Ho, P.-H. et al. Intrinsically ultrastrong plasmon–exciton interactions in crystallized films of carbon nanotubes. Proc. Natl Acad. Sci. USA 115, 12662–12667 (2018).
Falk, A. L. et al. Coherent plasmon and phonon-plasmon resonances in carbon nanotubes. Phys. Rev. Lett. 118, 257401 (2017).
Shi, Z. et al. Observation of a Luttinger-liquid plasmon in metallic single-walled carbon nanotubes. Nat. Photonics 9, 515–519 (2015).
Bluvstein, D. et al. Controlling quantum many-body dynamics in driven Rydberg atom arrays. Science 371, 1355–1359 (2021).
Chen, J.-Y., He, L., Wang, J.-P. & Li, M. All-optical switching of magnetic tunnel junctions with single subpicosecond laser pulses. Phys. Rev. Appl. 7, 021001 (2017).
Fang, W. & Yang, Y. Directional dipole radiations and long-range quantum entanglement mediated by hyperbolic metasurfaces. Opt. Express 28, 32955 (2020).
Mazor, Y. & Alù, A. Routing optical spin and pseudospin with metasurfaces. Phys. Rev. Appl. 14, 014029 (2020).
Yermakov, O. Y. et al. Spin control of light with hyperbolic metasurfaces. Phys. Rev. B 94, 075446 (2016).
Cirac, J. I., Zoller, P., Kimble, H. J. & Mabuchi, H. Quantum state transfer and entanglement distribution among distant nodes in a quantum network. Phys. Rev. Lett. 78, 3221–3224 (1997).
Lodahl, P. et al. Chiral quantum optics. Nature 541, 473–480 (2017).
Polder, D. & Van Hove, M. Theory of radiative heat transfer between closely spaced bodies. Phys. Rev. B 4, 3303–3314 (1971).
Guo, Y., Cortes, C. L., Molesky, S. & Jacob, Z. Broadband super-Planckian thermal emission from hyperbolic metamaterials. Appl. Phys. Lett. 101, 131106 (2012).
Cuevas, J. C. & García-Vidal, F. J. Radiative heat transfer. ACS Photonics 5, 3896–3915 (2018).
Biehs, S.-A. et al. Near-field radiative heat transfer in many-body systems. Rev. Mod. Phys. 93, 025009 (2021).
Guo, Y. & Jacob, Z. Thermal hyperbolic metamaterials. Opt. Express 21, 15014 (2013).
Xiao, Y., Sheldon, M. & Kats, M. A. Super-Planckian emission cannot really be ‘thermal’. Nat. Photonics 16, 397–401 (2022).
Pan, Z. et al. Remarkable heat conduction mediated by non-equilibrium phonon polaritons. Nature 623, 307–312 (2023).
Liu, R. et al. Near-field radiative heat transfer in hyperbolic materials. Int. J. Extrem. Manuf. 4, 032002 (2022).
Khandekar, C., Khosravi, F., Li, Z. & Jacob, Z. New spin-resolved thermal radiation laws for nonreciprocal bianisotropic media. N. J. Phys. 22, 123005 (2020).
Yang, X. et al. Nanomaterial-based plasmon-enhanced infrared spectroscopy. Adv. Mater. 30, 1704896 (2018).
Hu, C. et al. A metasurface with bidirectional hyperbolic surface modes and position-sensing applications. NPG Asia Mater. 10, 417–428 (2018).
Palermo, G. et al. Hyperbolic dispersion metasurfaces for molecular biosensing. Nanophotonics 10, 295–314 (2020).
Gomez-Diaz, J. S., Tymchenko, M. & Alu, A. Hyperbolic plasmons and topological transitions over uniaxial metasurfaces. Phys. Rev. Lett. 114, 233901 (2015).
Autore, M. et al. Boron nitride nanoresonators for phonon-enhanced molecular vibrational spectroscopy at the strong coupling limit. Light Sci. Appl. 7, 17172–17172 (2017).
Stauber, T., Low, T. & Gómez-Santos, G. Plasmon-enhanced near-field chirality in twisted van der Waals heterostructures. Nano Lett. 20, 8711–8718 (2020).
Deng, G., Dereshgi, S. A., Song, X., Wei, C. & Aydin, K. Phonon-polariton assisted broadband resonant absorption in anisotropic α-phase MoO3 nanostructures. Phys. Rev. B 102, 035408 (2020).
Castilla, S. et al. Plasmonic antenna coupling to hyperbolic phonon-polaritons for sensitive and fast mid-infrared photodetection with graphene. Nat. Commun. 11, 4872 (2020).
Martín-Sánchez, J. et al. Focusing of in-plane hyperbolic polaritons in van der Waals crystals with tailored infrared nanoantennas. Sci. Adv. 7, eabj0127 (2021).
Vakil, A. & Engheta, N. Transformation optics using graphene. Science 332, 1291–1294 (2011).
McCall, M. et al. Roadmap on transformation optics. J. Opt. 20, 063001 (2018).
Sahoo, N. R. et al. High temperature mid-IR polarizer via natural in-plane hyperbolic van der Waals crystals. Adv. Opt. Mater. 10, 2101919 (2021).
Dereshgi, S. A. et al. Lithography-free IR polarization converters via orthogonal in-plane phonons in α-MoO3 flakes. Nat. Commun. 11, 5771 (2020).
Dixit, S., Sahoo, N. R., Mall, A. & Kumar, A. Mid infrared polarization engineering via sub-wavelength biaxial hyperbolic van der Waals crystals. Sci. Rep. 11, 1–9 (2021).
Khaliji, K., Martín-Moreno, L., Avouris, P., Oh, S.-H. & Low, T. Twisted two-dimensional material stacks for polarization optics. Phys. Rev. Lett. 128, 193902 (2022).
Kornovan, D., Petrov, M. & Iorsh, I. Noninverse dynamics of a quantum emitter coupled to a fully anisotropic environment. Phys. Rev. A 100, 033840 (2019).
Schaibley, J. R. et al. Valleytronics in 2D materials. Nat. Rev. Mater. 1, 1–15 (2016).
Jha, P. K., Shitrit, N., Ren, X., Wang, Y. & Zhang, X. Spontaneous exciton valley coherence in transition metal dichalcogenide monolayers interfaced with an anisotropic metasurface. Phys. Rev. Lett. 121, 116102 (2018).
Nalabothula, M., Jha, P. K., Low, T. & Kumar, A. Engineering valley quantum interference in anisotropic van der Waals heterostructures. Phys. Rev. B 102, 045416 (2020).
Agarwal, G. S. Anisotropic vacuum-induced interference in decay channels. Phys. Rev. Lett. 84, 5500–5503 (2000).
Giles, A. J. et al. Ultralow-loss polaritons in isotopically pure boron nitride. Nat. Mater. 17, 134–139 (2018).
Park, S. H., Sammon, M., Mele, E. & Low, T. Plasmonic gain in current biased tilted Dirac nodes. Nat. Commun. 13, 7667 (2022).
Lee, I.-H., Yoo, D., Avouris, P., Low, T. & Oh, S.-H. Graphene acoustic plasmon resonator for ultrasensitive infrared spectroscopy. Nat. Nanotechnol. 14, 313–319 (2019).
Acknowledgements
H.W. and T.L. are partially supported by NSF DMREF-1921629. H.W. is supported by the Program for Science and Technology Innovation Team in Zhejiang (Grant No. 2021R01004). H.W., T.L., and J.-P.W. acknowledged partial support from SMART, one of the seven centers of nCORE, an SRC program, sponsored by NIST. A.K. acknowledges funding support from the Department of Science and Technology via the grant CRG/2022/001170. T.L. and J.C. acknowledge partial support from the Office of Naval Research MURI grant N00014-23-1-2567. S.D. acknowledges support from NSF under grant DMR-2005194 and ACS PRF fund 66229-DNI6. X.L. acknowledges the support partly from the National Natural Science Fund for Excellent Young Scientists Fund Program (Overseas) of China, the National Natural Science Foundation of China (NSFC) under Grant No. 62175212, Zhejiang Provincial Natural Science Fund Key Project under Grant No. LZ23F050003, and the Fundamental Research Funds for the Central Universities (2021FZZX001-19). Z.J. was supported by the U.S. Department of Energy (DOE), Office of Basic Sciences under DE-SC0017717. S.-H.O. acknowledges support from the Samsung Global Research Outreach (GRO) Program and the Sanford P. Bordeau Chair. V.M. was supported through NSF DMR- 2130544 and the Army Research Office through W911NF-22-1-0091. Y.D.K. was supported by the National Research Foundation of Korea (2021K1A3A1A32084700, 2022R1A4A3030766, 2022M3H4A1A04096396). L.M.M. acknowledges Project PID2020-115221GB-C41, financed by MCIN/AEI/10.13039/501100011033, and the Aragon Government through Project Q-MAD.
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T.L. initiated, coordinated, and supervised the project. T.L. and A.K. contributed with the introduction and concluding remarks. H.W. contributed with the subsections “Physical origin of plasmonic hyperbolicity"; “Hyperbolicity induced by excitons"; “Plasmonic planar hyperbolicity observed"; “Experiments on hyperbolic exciton polaritons", and the section “Functional Hyperbolic Materials". A.K. contributed with the subsections “Planar hyperbolicity via phonons"; “Experiments on planar hyperbolic phonon polaritons"; “Twisted bilayers and magic angles"; “Tuning via Metal ion intercalations", and the section “Potential applications". S.D., X.L., S.-H.O., V.M., E.N., and J.C. contributed to the section “Engineering planar hyperbolic materials”. J.-P.W., P.A. contributed to the section “Functional hyperbolic materials”. X.L., L.M.M., Z.J., and Y.D.K. contributed to the section “Potential applications”. T.L., A.K., H.W., J.C., L.M.M., E.N., and P.A. discussed and contributed to the crafting of the opening paragraphs of this perspective, detailed in the section “Hyperbolic polaritons in flatland". All authors commented on the manuscript.
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Wang, H., Kumar, A., Dai, S. et al. Planar hyperbolic polaritons in 2D van der Waals materials. Nat Commun 15, 69 (2024). https://doi.org/10.1038/s41467-023-43992-8
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DOI: https://doi.org/10.1038/s41467-023-43992-8
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