News & Views |
Featured
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Article |
Electric-field-induced colour switching in colloidal quantum dot molecules at room temperature
Current quantum dot emitters are limited to small-spectral-range colour tuning accompanied by intensity reduction. Electric-field-induced reversible emission colour switching without intensity loss can be achieved on a single-particle level in quantum dot molecules with two coupled emission centres.
- Yonatan Ossia
- , Adar Levi
- & Uri Banin
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News & Views |
A new spin on impact ionization
Quantum dots are engineered to use dopant states to achieve substantially enhanced impact ionization, which is potentially useful for light-harvesting applications.
- Miri Kazes
- & Dan Oron
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Article
| Open AccessSpin-exchange carrier multiplication in manganese-doped colloidal quantum dots
Carrier multiplication generates multiple excitons for each absorbed photon but is normally limited by fast phonon-assisted relaxation. Here the authors achieve a threefold enhancement in multiexciton yields in Mn-doped PbSe/CdSe quantum dots, due to very fast spin-exchange interactions between Mn ions and the quantum dots that outpace energy losses arising from phonon emission.
- Ho Jin
- , Clément Livache
- & Victor I. Klimov
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News & Views |
Locking exciton fine-structure splitting
Ensemble-level experimental evidence of exciton fine-structure splitting in perovskite quantum dots has been demonstrated, correlated to the intrinsic symmetry of these nanocrystals.
- Gabriele Rainò
- & Maksym V. Kovalenko
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Article |
Lattice distortion inducing exciton splitting and coherent quantum beating in CsPbI3 perovskite quantum dots
Halide perovskites feature highly dynamic lattices, but their impact on exciton fine structure remains unexplored. Here, the authors show that these lattices lead to a bright-exciton fine structure gap, enabling observation of quantum beats in a non-uniform ensemble.
- Yaoyao Han
- , Wenfei Liang
- & Kaifeng Wu
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Article |
Ultrafast exciton transport at early times in quantum dot solids
Understanding exciton dynamics in quantum dots is important for realizing their potential in optoelectronics. Here, the authors use femtosecond transient absorption microscopy to reveal ultrafast exciton transport, enhanced at larger interdot distance and taking place within hundreds of femtoseconds after generation.
- Zhilong Zhang
- , Jooyoung Sung
- & Akshay Rao
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Article |
Interface polarization in heterovalent core–shell nanocrystals
Controlled synthesis of heterostructured III-V–II-VI nanocrystals shows that dipole moments formed at the core–shell interface can tune the optoelectronic properties of these nanomaterials and their performance in light-emitting devices.
- Byeong Guk Jeong
- , Jun Hyuk Chang
- & Wan Ki Bae
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News & Views |
Hole spin qubits work at mT magnetic fields
A singlet-triplet hole spin qubit in a Ge quantum well is demonstrated to be fast, coherent, and compatible with operation at magnetic fields below 10 mT, opening the door to integration with superconducting technologies.
- Floris Braakman
- & Pasquale Scarlino
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Article |
A singlet-triplet hole spin qubit in planar Ge
A singlet-triplet spin qubit using holes in a Ge quantum well is demonstrated, and can be operated at low magnetic fields of a few millitesla.
- Daniel Jirovec
- , Andrea Hofmann
- & Georgios Katsaros
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Article |
Spin–layer locking of interlayer excitons trapped in moiré potentials
The optical properties of two species of localized interlayer excitons in a van der Waals heterostructure are shown to depend on their spin–valley–layer configuration, enabling the identification of the moiré atomic registry and offering insights for engineering quantum states in two-dimensional materials.
- Mauro Brotons-Gisbert
- , Hyeonjun Baek
- & Brian D. Gerardot
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Article |
Dipolar interactions between localized interlayer excitons in van der Waals heterostructures
Repulsive dipole–dipole interactions between localized interlayer excitons are shown to modify the optical response of van der Waals heterobilayers, forming the basis to obtain strong optical nonlinearity and excitonic many-body states in two-dimensional materials.
- Weijie Li
- , Xin Lu
- & Ajit Srivastava
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News & Views |
Confined yet free to go
Electrons are shown to move quickly while still presenting features typical of quantum confinement in films of mercury telluride quantum dots.
- Uwe Kortshagen
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Article |
Quantum dot solids showing state-resolved band-like transport
High charge mobility while retaining signatures of quantum-confined states is obtained in films of surface-passivated HgTe quantum dots.
- Xinzheng Lan
- , Menglu Chen
- & Dmitri V. Talapin
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Article |
Collective topo-epitaxy in the self-assembly of a 3D quantum dot superlattice
A structural investigation on the formation of 3D superlattices of colloidal PbSe quantum dots reveals a topotactic transition from the self-assembled phase of ligand-capped quantum dots to the epitaxially fused phase typical of conductive solids.
- Alex Abelson
- , Caroline Qian
- & Matt Law
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Article |
Scalable in operando strain tuning in nanophotonic waveguides enabling three-quantum-dot superradiance
Local tuning of quantum dots embedded in a photonic waveguide can be achieved through the strain produced by laser heating of a thin layer of HfO2 deposited around the waveguide. The method is exploited to tune three quantum dots in resonance.
- Joel Q. Grim
- , Allan S. Bracker
- & Daniel Gammon
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News & Views |
Shedding light on dark excitons
A magnetic-field-dependent spectroscopy study on single perovskite nanocrystals reveals the spectral signatures of an exciton dark state below the bright triplet states.
- Andries Meijerink
- & Freddy T. Rabouw
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Review Article |
Droplet epitaxy of semiconductor nanostructures for quantum photonic devices
The droplet epitaxy technique has emerged as an alternative to the most commonly used Stranski–Krastanov for fabricating semiconductor nanostructures. This Review discusses the important aspects of droplet epitaxy quantum dots, from the growth mechanism to device application.
- Massimo Gurioli
- , Zhiming Wang
- & Stefano Sanguinetti
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Article |
The ground exciton state of formamidinium lead bromide perovskite nanocrystals is a singlet dark state
Magneto-optical spectroscopy shows that the dark exciton state in single formamidinium lead bromide perovskite nanocrystals is located below the bright exciton triplet. Slow bright-to-dark relaxation explains the intense brightness of the nanoparticles.
- Philippe Tamarat
- , Maryna I. Bodnarchuk
- & Brahim Lounis
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Article |
Asymmetrically strained quantum dots with non-fluctuating single-dot emission spectra and subthermal room-temperature linewidths
Asymmetric strain intrinsic to core/shell nanocrystals based on lattice-mismatched wurtzite semiconductors leads to suppression of spectral fluctuation, narrowing of photoluminescence linewidth and reduced blinking in colloidal nanocrystals.
- Young-Shin Park
- , Jaehoon Lim
- & Victor I. Klimov
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Review Article |
Genesis, challenges and opportunities for colloidal lead halide perovskite nanocrystals
Lead-halide perovskites have entered the family of colloidal nanocrystals, showing excellent optical properties and easy synthesizability. This Review provides an insight into their chemical versatility, stability challenges and use in optoelectronics.
- Quinten A. Akkerman
- , Gabriele Rainò
- & Liberato Manna
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News & Views |
Virtues of defects
Defects in mercury telluride quantum dots can be exploited to achieve amplified spontaneous emission under continuous-wave optical pumping at ultralow power levels.
- Frank Wise
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News & Views |
Electrifying quantum dots for lasers
Compositional grading of colloidal quantum dots enables electrically driven amplification of light, bringing electrically driven lasers from these materials very close.
- Ifor Samuel
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Article |
Continuous-wave infrared optical gain and amplified spontaneous emission at ultralow threshold by colloidal HgTe quantum dots
Stimulated emission under continuous-wave excitation from mercury telluride quantum dots at very low thresholds (compatible with electrical injection) is achieved by exploiting surface traps that render the quantum dots into four-level systems.
- Pieter Geiregat
- , Arjan J. Houtepen
- & Zeger Hens
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Letter |
Measurement of the spin temperature of optically cooled nuclei and GaAs hyperfine constants in GaAs/AlGaAs quantum dots
Measurement of the nuclear polarization in GaAs/AlGaAs quantum dots through manipulation of the nuclear spin states with radiofrequency pulses reveals polarizations up to 80%.
- E. A. Chekhovich
- , A. Ulhaq
- & M. S. Skolnick
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News & Views |
The pathway to atomic alignment
Two independent studies provide insight on the formation of nanocrystal superlattices and their atomic alignment using real-time in situ X-ray scattering techniques.
- Yugang Zhang
- & Oleg Gang
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Article |
Hybrid organic–inorganic inks flatten the energy landscape in colloidal quantum dot solids
An improved ligand-exchange process allows the realization of solution-deposited films of quantum dots with reduced energetic disorder and, as a result, solar cells with improved open-circuit voltage, charge-carrier transport and stability.
- Mengxia Liu
- , Oleksandr Voznyy
- & Edward H. Sargent
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Letter |
In situ study of the formation mechanism of two-dimensional superlattices from PbSe nanocrystals
A real-time study of the growth of two-dimensional nanocrystal superlattices with square periodicity shows the formation mechanism leading to the oriented attachment of the nanocrystals.
- Jaco J. Geuchies
- , Carlo van Overbeek
- & Daniel Vanmaekelbergh
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Article |
Decoupling a hole spin qubit from the nuclear spins
Coherent population-trapping studies of a single hole spin in quantum dot field-effect devices with low charge-noise performance provide insight into the anisotropy of the hole hyperfine interaction between hole and nuclear spins.
- Jonathan H. Prechtel
- , Andreas V. Kuhlmann
- & Richard J. Warburton
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Article |
Crystal symmetry breaking and vacancies in colloidal lead chalcogenide quantum dots
X-ray scattering and density functional theory calculations reveal that ligand-induced tensile stress can distort the rock-salt structure of small PbS and PbSe colloidal quantum dots, creating a Pb-deficient core surrounded by a Pb-enriched shell.
- Federica Bertolotti
- , Dmitry N. Dirin
- & Norberto Masciocchi
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Article |
Kinetics of the self-assembly of nanocrystal superlattices measured by real-time in situ X-ray scattering
The self-assembly of lead sulfide nanocrystals into a body-centred cubic lattice can be tracked in real time by using in situ grazing-incidence X-ray scattering.
- Mark C. Weidman
- , Detlef-M. Smilgies
- & William A. Tisdale
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News & Views |
Nanowire–quantum dot epitaxy
The synthesis of crystalline quantum dots epitaxially incorporated into silicon nanowires holds promise for future device applications in various areas of opto- and quantum electronics.
- Peter Krogstrup
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Article |
Synthesis of nanostructures in nanowires using sequential catalyst reactions
The addition of nickel and other metal atoms in the liquid droplets that drive the vapour–liquid–solid growth of silicon nanowires leads to the formation of metal silicide nanocrystals that are epitaxially incorporated inside the nanowires.
- F. Panciera
- , Y.-C. Chou
- & F. M. Ross
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Editorial |
Let there be light
Inorganic semiconductors, organic emitters and colloidal quantum dots are pushing the LED revolution in lighting and displays.
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Commentary |
Complementary LED technologies
Organic semiconducting molecules and colloidal quantum dots both make for excellent luminescent materials. Compared with the more established solid-state light-emitting technologies, organic LEDs and quantum-dot LEDs are in their infancy, yet they offer unique properties.
- Sebastian Reineke
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Resonant energy transfer of triplet excitons from pentacene to PbSe nanocrystals
Triplet excitons generated in a pentacene layer by singlet exciton fission are transferred to lead selenide colloidal nanocrystals with high efficiency when their energy matches the bandgap of the nanocrystals.
- Maxim Tabachnyk
- , Bruno Ehrler
- & Akshay Rao
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Article |
Energy harvesting of non-emissive triplet excitons in tetracene by emissive PbS nanocrystals
Lead sulphide colloidal nanocrystals are now used to harvest non-emissive triplet excitons generated in a tetracene layer. Depending on the length of the ligands capping the nanocrystals, exciton transfer efficiency as high as 90% can be achieved.
- Nicholas J. Thompson
- , Mark W. B. Wilson
- & Marc A. Baldo
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Letter |
Redox shuttle mechanism enhances photocatalytic H2 generation on Ni-decorated CdS nanorods
Photocatalytic efficiency can be limited by slow transfer of photoexcited holes and high charge recombination rates. Using a hydroxyl anion–radical redox couple leads to enhanced photocatalytic H2 generation on Ni-decorated CdS nanorods.
- Thomas Simon
- , Nicolas Bouchonville
- & Jochen Feldmann
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News & Views |
The surface plays a core role
Mastering the impact of surface chemistry on the electronic properties and stability of colloidal quantum dots enables the realization of architectures with enhanced photovoltaic performance and air stability.
- Delia J. Milliron
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Letter |
Improved performance and stability in quantum dot solar cells through band alignment engineering
Fabricating low-temperature solution-processed solar cells with good power-conversion efficiency and stability in ambient conditions has proved challenging. The use of ligands that protect colloidal quantum dots from degradation in air and tune their energy levels is now shown to be a viable approach for the realization of spin-coated solar cells with very high efficiency.
- Chia-Hao M. Chuang
- , Patrick R. Brown
- & Moungi G. Bawendi
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Editorial |
Join the dots
The properties of semiconductor quantum dots can now be controlled down to the level of single electrons and spins. These solid-state 'artificial atoms' have inspired scientists to look at them as possible building blocks for realizations of quantum computers, with unexpected consequences.
- Hugo Ribeiro
- & Guido Burkard
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Commentary |
Nuclear spins keep coming back
Semiconducting quantum dots have been extensively investigated with the idea of using single spins for quantum computing. Whereas access to single electrons and their spins has become routine, the challenges posed by nuclear spins remain ever present.
- Hugo Ribeiro
- & Guido Burkard