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Interface-mediated noble metal deposition on transition metal dichalcogenide nanostructures
The deposition of noble metals onto two-dimensional transition metal dichalcogenides is crucial for practical applications, including in catalysis and sensing, yet this process has remained difficult to control. Now, gold and silver have been shown to grow on colloidal transition metal dichalcogenide nanosheets into either atomically thin layers or nanoparticles whose sizes and morphologies depend on the relative strengths of the interfacial noble metal–chalcogen bonds.
- Yifan Sun
- , Yuanxi Wang
- & Raymond E. Schaak
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Ionic solutions of two-dimensional materials
Isolating nanoscale species in liquids permits their scalable manipulation, enabling numerous fundamental and applied processes. Thus, achieving true dissolution of 2D materials is particularly desirable. Now, ionic salts of a range of important layered materials have been shown to spontaneously dissolve, yielding solutions of charged, monodisperse, undamaged and easy-to-manipulate 2D nanosheets.
- Patrick L. Cullen
- , Kathleen M. Cox
- & Christopher A. Howard
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Multistep nucleation of nanocrystals in aqueous solution
Crystals grow from nuclei. In systems where nuclei are nanometre-sized and form quickly, it is difficult to determine the mechanism of their formation. Now, through in situ TEM, the demixing of a supersaturated aqueous gold solution into metastable gold-poor and gold-rich liquid phases is observed, the latter yielding stable clusters that become nuclei for nanocrystal growth.
- N. Duane Loh
- , Soumyo Sen
- & Utkur Mirsaidov
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Controlled growth of high-density CdS and CdSe nanorod arrays on selective facets of two-dimensional semiconductor nanoplates
Controlling the morphology and composition of hybrid nanostructures is desirable for applications, but it has proven challenging to precisely combine different nucleation sites and growth modes. Now, three types of hierarchical 1D/2D nanostructures have been prepared by selectively growing semiconductor nanorod arrays (CdS or CdSe) on the different facets of hexagonal nanoplates.
- Xue-Jun Wu
- , Junze Chen
- & Hua Zhang