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| Open AccessNanoscale mechanism of UO2 formation through uranium reduction by magnetite
In anoxic environments, soluble hexavalent uranium is reduced and immobilized, however, the underlying molecular-scale reduction mechanism remains unknown. Here, the authors find that U reduction can occur on the surface of magnetite via transient U nanowire structures which collapse into ordered UO2 nanoclusters, which may have implications for understanding nuclear waste evolution and remediation of uranium contamination.
- Zezhen Pan
- , Barbora Bártová
- & Rizlan Bernier-Latmani
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Article
| Open AccessA nature-inspired hydrogen-bonded supramolecular complex for selective copper ion removal from water
Heavy metals and metalloids pose major threats to health and environmental ecosystems, thus systems for low-cost remediation are needed. Here the authors report the scalable design of a hydrogen-bonded organic–inorganic framework for selective removal of trace heavy metal ions from water.
- Ngoc T. Bui
- , Hyungmook Kang
- & Jeffrey J. Urban
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Article
| Open AccessGas hydrate dissociation linked to contemporary ocean warming in the southern hemisphere
Ocean warming could enable the release of methane related to hydrate dissociation from the ocean floor, a process thought to have triggered abrupt climate changes in Earth history. Here the authors detect this process in action, observing a massive release of methane from a site in the South Atlantic Ocean.
- Marcelo Ketzer
- , Daniel Praeg
- & José A. Cupertino
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Article
| Open AccessAsteroid shower on the Earth-Moon system immediately before the Cryogenian period revealed by KAGUYA
Ancient impact events on Earth are not well characterized due to continuous re-surfacing of Earth. Here, the authors study impact craters on the Moon with ages up to 800 million years ago and present a cross correlation to Earth, linking up to mass extinction events throughout Earth’s history.
- Kentaro Terada
- , Tomokatsu Morota
- & Mami Kato
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Article
| Open AccessAnthropogenic stressors impact fish sensory development and survival via thyroid disruption
Anthropogenic stressors affect many aspects of marine organismal health. Here, the authors expose surgeonfish to temperature and pesticide stressors and show that the stressors, separately and in combination, have adverse effects on thyroid signaling, which disrupts several sensory systems and important predation defenses.
- Marc Besson
- , William E. Feeney
- & David Lecchini
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Article
| Open AccessA scalable method for preparing Cu electrocatalysts that convert CO2 into C2+ products
Selective reduction of carbon dioxide to high-value products is key for advancing carbon capture and utilization technologies. Here the authors prepare a copper catalyst for electrocatalytic conversion of carbon dioxide to C2+ products with enhanced selectivity that is attributed to a high density of surface defects.
- Taehee Kim
- & G. Tayhas R. Palmore
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Article
| Open AccessIon sieving by a two-dimensional Ti3C2Tx alginate lamellar membrane with stable interlayer spacing
Two dimensional lamellar membranes are attractive for anomalous water and ion transfer, but performance is hindered by swelling. Here, the authors stabilize a MXene membrane laminar architecture with fixed nanochannels, achieving highly selective acid recovery from iron-based wastewater.
- Jin Wang
- , Zhijie Zhang
- & Lei Wang
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Article
| Open AccessAtmospheric transport is a major pathway of microplastics to remote regions
Plastic pollution is a critical concern across diverse ecosystems, yet most research has focused on terrestrial and aquatic transport, neglecting other mechanisms. Here the authors show that atmospheric transport is a major pathway for road plastic pollution over remote regions.
- N. Evangeliou
- , H. Grythe
- & A. Stohl
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Article
| Open AccessMethylmercury produced in upper oceans accumulates in deep Mariana Trench fauna
Monomethylmercury is a toxin that humans can be exposed to after consumption of seafood in which it has bioaccumulated. Here the authors show that amphipods in the deepest point of the global ocean contain monomethylmercury with surface origins, suggesting rapid sinking of this toxin on particles.
- Ruoyu Sun
- , Jingjing Yuan
- & Congqiang Liu
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Article
| Open AccessContactless probing of polycrystalline methane hydrate at pore scale suggests weaker tensile properties than thought
The authors here report tensile properties of polycrystalline methane hydrate at the micron scale by applying a contactless, thermos-induced stress to a tenuous shell of hydrate grown in a thin glass capillary. The results suggest that the cohesive strength of methane hydrate in marine settings may be an order of magnitude less than currently thought.
- Dyhia Atig
- , Daniel Broseta
- & Ross Brown
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Article
| Open AccessCoastal sedimentation across North America doubled in the 20th century despite river dams
The proliferation of dams since 1950 has promoted sediment deposition in reservoirs, which is thought to be starving the coast of sediment and decreasing resistance to storms and sea-level rise. Here, the authors show that century-long records of sediment mass accumulation rates and sediment accumulation rates more than doubled after 1950 in coastal depocenters around North America.
- A. B. Rodriguez
- , B. A. McKee
- & A. N. Atencio
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Article
| Open AccessRapid glacier retreat and downwasting throughout the European Alps in the early 21st century
Glaciers in the European Alps are strongly affected by global warming, yet there is no methodologically consistent alpine-wide analysis on glacier changes. Here the authors show significant glacier retreat and an ice mass loss of 1.3 ± 0.2 Gt a−1, derived from contemporaneous measurements of glacier areas and elevations.
- Christian Sommer
- , Philipp Malz
- & Matthias H. Braun
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Perspective
| Open AccessScientists’ warning on affluence
Current environmental impact mitigation neglects over-consumption from affluent citizens as a primary driver. The authors highlight the role of bottom-up movements to overcome structural economic growth imperatives spurring consumption by changing structures and culture towards safe and just systems.
- Thomas Wiedmann
- , Manfred Lenzen
- & Julia K. Steinberger
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Article
| Open AccessAssessing the effectiveness of a national protected area network for carnivore conservation
Assessing the effectiveness of protected areas for wildlife conservation is challenging. Here, Terraube et al. combine statistical matching and hurdle mixed-effects models to show that PAs have limited impact on population densities of large carnivores across Finland.
- J. Terraube
- , J. Van doninck
- & M. Cabeza
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Article
| Open AccessNon-natural ruthenium isotope ratios of the undeclared 2017 atmospheric release consistent with civilian nuclear activities
A cloud of enhanced ruthenium concentrations has been observed over Europe in 2017, but no country has acknowledged responsibility for this nuclear release. Here, the authors show that the stable isotopic composition of ruthenium emitted from nuclear fuel reprocessing during the 2017 event is consistent with the isotopic signature of civilian Russian nuclear reactor fuel.
- Timo Hopp
- , Dorian Zok
- & Georg Steinhauser
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Article
| Open AccessQuantifying the drivers and predictability of seasonal changes in African fire
Fire is an important component of many African ecosystems, but prediction of fire activity is challenging. Here, the authors use a statistical framework to assess the seasonal environmental drivers of African fire, which allow for a better prediction of fire activity.
- Yan Yu
- , Jiafu Mao
- & Yaoping Wang
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Article
| Open AccessFast sulfate formation from oxidation of SO2 by NO2 and HONO observed in Beijing haze
How sulfur dioxide emitted through coal combustion is oxidized to sulfate particles during winter haze pollution events has been the subject of debate. Here, the authors show that rapid oxidation takes place by nitrogen dioxide and nitrous acid, producing nitrous oxide together with sulfate.
- Junfeng Wang
- , Jingyi Li
- & Daniel J. Jacob
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Article
| Open AccessFires prime terrestrial organic carbon for riverine export to the global oceans
Black carbon is a recalcitrant and unique form of organic carbon formed from incomplete combustion. Here the authors use global sampling to reduce uncertainty in the flux of terrestrial black carbon to the oceans, predicting that 34% of black carbon produced by fires has an oceanic fate.
- Matthew W. Jones
- , Alysha I. Coppola
- & Timothy A. Quine
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Article
| Open AccessA big data approach to improving the vehicle emission inventory in China
There lacks a method to measure the rapid changes of vehicle emissions. Here the authors proposed a big data approach ‘TrackATruck’, and their estimates using the new approach show that the heavy-duty trucks (HDT) emissions of primary cargo routes/terminals were underestimated by 2–10 times in proxy-based emission inventories.
- Fanyuan Deng
- , Zhaofeng Lv
- & Huan Liu
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Article
| Open AccessChemical multi-fingerprinting of exogenous ultrafine particles in human serum and pleural effusion
Exposure to ambient particulate matter is one of the leading global health risks. Here, the authors reveal, by means of chemical multi-fingerprinting, the presence of exogenous ultrafine particles with diverse species and morphology in non-occupational human serum and pleural effusion.
- Dawei Lu
- , Qian Luo
- & Guibin Jiang
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Article
| Open AccessMicroplastics affect sedimentary microbial communities and nitrogen cycling
Plastic pollution has infiltrated every ecosystem, but few studies have quantified the biogeochemical or ecological effects of plastic. Here the authors show that microplastics in ocean sediment can significantly alter microbial community structure and nitrogen cycling.
- Meredith E. Seeley
- , Bongkeun Song
- & Robert C. Hale
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Article
| Open AccessMapping global urban land for the 21st century with data-driven simulations and Shared Socioeconomic Pathways
Here the authors develop a set of global, long-term, spatial projections of urban land expansion for understanding the planet’s potential urban futures. The global total amount of urban land increases by a factor of 1.8-5.9 over the 21st century, and the developed world experiences as much new urban development as the developing world.
- Jing Gao
- & Brian C. O’Neill
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Article
| Open AccessMapping global carbon footprint in China
There lacks a spatially explicit mapping of global carbon footprint in China that considers both international and interprovincial trade. Here the authors map the carbon footprints of global regions in China and show the hotspots concentrated in key manufacturing hubs, including the Yangtze River Delta, Pearl River Delta, and North China Plain.
- Yuantao Yang
- , Shen Qu
- & Ming Xu
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Article
| Open AccessArsenic contamination of Bangladesh aquifers exacerbated by clay layers
Generally it is thought that confining clay layers provide protection to low-arsenic groundwaters against intrusion of shallower, high-arsenic groundwater bodies. Here, the authors show that impermeable clay layers can increase arsenic input to underlying groundwater systems due to reduction of iron oxides coupled to carbon oxidation.
- Ivan Mihajlov
- , M. Rajib H. Mozumder
- & Alexander van Geen
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Article
| Open AccessFire deficit increases wildfire risk for many communities in the Canadian boreal forest
A primary element of modern wildfire management is to aggressively suppress small fires before they become large, but benefits can be offset by the fact that these practices promote older forests that are more ‘flammable’. Here the authors show that this downside puts numerous human communities at elevated risk of fires in boreal Canada.
- Marc-André Parisien
- , Quinn E. Barber
- & Sean A. Parks
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Article
| Open AccessLocal conditions and policy design determine whether ecological compensation can achieve No Net Loss goals
Countries are adopting ecological compensation policies aimed at achieving no net loss of biodiversity and ecosystem services. Here, Sonter and colleagues apply spatial simulation models to case studies in Australia, Brazil, Indonesia, and Mozambique to show that compensation alone is not sufficient to preserve biodiversity.
- Laura J. Sonter
- , Jeremy S. Simmonds
- & Martine Maron
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Comment
| Open AccessOpportunities for big data in conservation and sustainability
Big data reveals new, stark pictures of the state of our environments. It also reveals ‘bright spots’ amongst the broad pattern of decline and—crucially—the key conditions for these cases. Big data analyses could benefit the planet if tightly coupled with ongoing sustainability efforts.
- Rebecca K. Runting
- , Stuart Phinn
- & James E. M. Watson
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Article
| Open AccessBiological weed control to relieve millions from Ambrosia allergies in Europe
Invasive plants can adversely affect ecosystems and economic costs. Here, the authors quantify the impact of the invasive plant Ambrosia artemisiifolia on seasonal allergies and health costs across Europe, finding that the costs are considerably higher than what previously reported, and estimate also the reduction in the number of patients and health costs that may be obtained with biological control
- Urs Schaffner
- , Sandro Steinbach
- & Heinz Müller-Schärer
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Article
| Open AccessNon-linear interaction modulates global extreme sea levels, coastal flood exposure, and impacts
The non-linear interaction between tide and non-tidal residual impacts current and future extreme water levels. Here, based on 620 gauge records, the authors find a large non-linear interaction in the US East Coast, North Sea and parts of southern Japan, that results in a reduction of extreme sea levels.
- Arne Arns
- , Thomas Wahl
- & Jürgen Jensen
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Article
| Open AccessInvasive earthworms unlock arctic plant nitrogen limitation
Arctic plant growth is predominantly nitrogen limited, where the slow nitrogen turnover in the soil is commonly attributed to the cold arctic climate. Here the authors show that the arctic plant-soil nitrogen cycling is also constrained by the lack of larger detritivores like earthworms.
- Gesche Blume-Werry
- , Eveline J. Krab
- & Jonatan Klaminder
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Article
| Open AccessBionic 3D printed corals
Corals have evolved as finely tuned light collectors. Here, the authors report on the 3D printing of coral-inspired biomaterials, that mimic the coral-algal symbiosis; these bionic corals lead to dense microalgal growth and can find applications in algal biotechnology and applied coral science.
- Daniel Wangpraseurt
- , Shangting You
- & Silvia Vignolini
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Article
| Open AccessHigh-performance particulate matter including nanoscale particle removal by a self-powered air filter
Particulate matter (PM) pollutants have been considered serious threats to public health but effective removal of nanoscale particles (NPs) by filter materials is challenging. Here, the authors fabricate an ionic liquid based self-powered air filter that can be used in high-efficiency removal of PM, including NPs.
- Guo-Hao Zhang
- , Qiu-Hong Zhu
- & Guo-Hong Tao
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Article
| Open AccessPrompt rewetting of drained peatlands reduces climate warming despite methane emissions
Drained peatlands are sources of CO2, and though rewetting could curb emissions, this strategy results in elevated methane release. Here, the authors model peatland emissions scenarios and show that rewetting is a critical way to mitigate climate change despite potential methane increases.
- Anke Günther
- , Alexandra Barthelmes
- & John Couwenberg
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Article
| Open AccessEstimating the size distribution of plastics ingested by animals
Plastic pollution is an escalating problem and there is a need to predict the range of plastic sizes that an organism of interest could feasibly ingest. Here the authors use previously published data to develop an allometric equation for plastic size ingested as a function of animal body size, a relationship which could help predict risk of plastic introduction into food webs.
- Ifan B. Jâms
- , Fredric M. Windsor
- & Isabelle Durance
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Article
| Open AccessUrban vacant lands impart hydrological benefits across city landscapes
The authors investigate the infiltration potential of more than 500 vacant lots in the City of Buffalo, NY, USA. They found that the expanding footprint of pervious cover as urban vacant land provides stormwater volume retention benefits on an event and annual basis.
- Christa Kelleher
- , Heather E. Golden
- & William Shuster
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Article
| Open AccessMapping anthropogenic mineral generation in China and its implications for a circular economy
While a large quantity of underground mineral resources can be converted into manufactured products, a majority is still solid waste disposal. Here the authors found a large increase in total weight of anthropogenic mineral from 2010 to 2050 with faster growth rate for precious metals.
- Xianlai Zeng
- , Saleem H. Ali
- & Jinhui Li
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Article
| Open AccessSustainability of global Golden Inland Waterways
The exploitation of rivers has been at the detriment of river ecosystems. Here the authors propose a concept of Golden Inland Waterways (GIWs) to represent large waterways and find that the exploitation ratio threshold around the turning point for most GIWs appear to be less than 80%, subject to ecological constraints.
- Yichu Wang
- , Xiabin Chen
- & Jinren Ni
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Article
| Open AccessSingle-atom catalysts reveal the dinuclear characteristic of active sites in NO selective reduction with NH3
Identification of active sites is one key prerequisite for rational design of efficient catalysts. Here, the authors achieve a common feature of catalytic active sites for NO selective reduction with NH3, which assists precise identification of active sites and effective design of optimal catalysts.
- Weiye Qu
- , Xiaona Liu
- & Yaxin Chen
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Article
| Open AccessCoral skeletons reveal the history of nitrogen cycling in the coastal Great Barrier Reef
Coastal pollution degrades ecosystems, but long term impacts are unknown in Australia’s Great Barrier Reef. Using a 333 year record of coral skeleton nitrogen isotopes, Erler and colleagues show that increasing nutrient inputs since European settlement have led to unexpected feedback responses.
- Dirk V. Erler
- , Hanieh Tohidi Farid
- & Janice M. Lough
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Article
| Open AccessStronger policy required to substantially reduce deaths from PM2.5 pollution in China
Chinese government has implemented the air pollution control measure-the Air Pollution Prevention and Control Action Plan in 2013, whose effects have not been fully studied. Here the authors show that from 2013 to 2017, the plan has achieved substantial public health benefits.
- Huanbi Yue
- , Chunyang He
- & Brett A. Bryan
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Article
| Open AccessCarbon dots-fed Shewanella oneidensis MR-1 for bioelectricity enhancement
Bacterial fuel cells have generated attention with the prospect of green energy production; current research is focused on optimising the system to improve efficiency. Here, the authors report on the feeding of carbon dots to S. oneidensis MR-1 to enhance metabolic activity and bioelectric generation.
- Chenhui Yang
- , Hüsnü Aslan
- & Miao Yu
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Article
| Open AccessChanges in global groundwater organic carbon driven by climate change and urbanization
Groundwater is Earth’s largest source of freshwater, but the cost and ease with which it is turned to drinking water is dependent on the concentration of organic carbon. Here the authors show that climate change and urbanization will likely elevate future levels of groundwater dissolved organic carbon across the globe.
- Liza K. McDonough
- , Isaac R. Santos
- & Andy Baker
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Article
| Open Access233U/236U signature allows to distinguish environmental emissions of civil nuclear industry from weapons fallout
The dominant emission sources of anthropogenic radionuclides come from either atmospheric nuclear weapons tests or the nuclear industry (i.e., reprocessing plants or reactor accidents). Here, the authors identify a new environmental isotope tracer (\(^{233}\)U/\(^{236}\)U) which can help distinguish emissions from nuclear weapons tests, and can also provide constraints on past weapon designs and fuel sources, for which many details remain classified or lost.
- K. Hain
- , P. Steier
- & A. Sakaguchi
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Article
| Open AccessUltra-high open-circuit voltage of tin perovskite solar cells via an electron transporting layer design
Despite the lower device efficiency, tin perovskite based solar cells are preferred choices compared to lead-based counterparts due to much lower toxicity. Here Jiang et al. use a fullerene derivative to greatly suppress carrier interface recombination and obtain record high cell efficiency of 12%.
- Xianyuan Jiang
- , Fei Wang
- & Zhijun Ning
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Article
| Open AccessMeasured greenhouse gas budgets challenge emission savings from palm-oil biodiesel
Palm oil biofuels are touted as a sustainable alternative to fossil fuels. Meijide and colleagues use greenhouse gas measurements to update life cycle assessments of oil palm growth scenarios and show that despite the promise, emission savings do not meet sustainability standards.
- Ana Meijide
- , Cristina de la Rua
- & Alexander Knohl
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Article
| Open AccessPredominant regional biophysical cooling from recent land cover changes in Europe
Land cover change contributes to regional climate trends. Here, the authors use high-resolution land cover maps and state-of-the-art climate modelling to assess land cover change effects across Europe over 1992-2015, showing widespread cooling after agricultural abandonment but also different, region-specific effects.
- Bo Huang
- , Xiangping Hu
- & Francesco Cherubini
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Article
| Open AccessActivating low-temperature diesel oxidation by single-atom Pt on TiO2 nanowire array
Supported metal single-atom catalysts face challenges on both durability and practicality. Here, the authors demonstrate that a sustained 90% diesel oxidation conversion at ~160 oC is achieved by single-atom Pt on TiO2 nanowire-array integrated catalytic converter.
- Son Hoang
- , Yanbing Guo
- & Pu-Xian Gao
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Article
| Open AccessCarbon footprint of global natural gas supplies to China
The carbon footprints of natural gas supplies at the field level are unclear. Here the authors analysed the GHG intensities of gas supplies from 104 fields and show that their GHG intensities range from 6.2 to 43.3 g CO2eq MJ-1.
- Yu Gan
- , Hassan M. El-Houjeiri
- & Michael Wang
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Article
| Open AccessRanking environmental degradation trends of plastic marine debris based on physical properties and molecular structure
Accumulation of micro and nano-plastic in the oceans has emerged as a global challenge. Here, the authors predict a hierarchy of features that regulate their degradation and surface erosion by a thorough analysis of polymer structure, composition, physical properties and degradation data.
- Kyungjun Min
- , Joseph D. Cuiffi
- & Robert T. Mathers