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| Open AccessHollow-core optical fibre sensors for operando Raman spectroscopy investigation of Li-ion battery liquid electrolytes
New analytical tools are needed to identify chemical degradation and failure mechanisms in Li-ion batteries. Here, the authors report an operando Raman spectroscopy method, based on hollow-core optical fibres, that enables monitoring the chemistry of liquid electrolytes during battery cycling.
- Ermanno Miele
- , Wesley M. Dose
- & Tijmen G. Euser
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Article
| Open AccessEpitaxial growth of an atom-thin layer on a LiNi0.5Mn1.5O4 cathode for stable Li-ion battery cycling
Transition metal dissolution from cathode materials limits the cycle life of Li-ion batteries. Here, the authors report an atomic-thin protecting layer on the surface of a high-voltage cathode material, enabling long-term Li-ion battery cycling.
- Xiaobo Zhu
- , Tobias U. Schülli
- & Lianzhou Wang
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Comment
| Open AccessMetrics and methods for moving from research to innovation in energy storage
Research activities are crucial for the advancement of energy storage technologies. However, not all the research lead to practical innovation. Here the author, focusing on supercapacitor devices, discusses the most challenging aspects to be considered to deliver practical innovation from fundamental research.
- Sebastian Pohlmann
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Article
| Open AccessA stable quasi-solid electrolyte improves the safe operation of highly efficient lithium-metal pouch cells in harsh environments
Solvent molecules under nanoconfinement dictates several key physical properties. Here, the authors reveal the behaviour of a quasi-solid electrolyte by using a microporous metal-organic framework with a small amount of liquid electrolyte influencing a number of properties in a lithium-metal pouch-cell.
- Zhi Chang
- , Huijun Yang
- & Haoshen Zhou
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Article
| Open AccessMismatching integration-enabled strains and defects engineering in LDH microstructure for high-rate and long-life charge storage
Layered double hydroxides (LDH) are ideal for charge storage, however, the sluggish reaction dynamics are obstacle to their development. Here, triggered by mismatching integration of Mn sites, the authors configure wrinkled Mn/NiCo-LDH with strains and defects, where promoted mass & charge transport behaviors are realized.
- Wei Guo
- , Chaochao Dun
- & Jieshan Qiu
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Article
| Open AccessExcellently balanced water-intercalation-type heat-storage oxide
There are few well-balanced heat storage materials up to date. Here, the authors report that δ-type K0.33MnO2 ∙ nH2O can be an excellently balanced heat storage material exhibiting a “water-intercalation mechanism”.
- Takuya Hatakeyama
- , Norihiko L. Okamoto
- & Tetsu Ichitsubo
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Article
| Open AccessHigh-energy and low-cost membrane-free chlorine flow battery
Flow batteries provide promising solutions for stationary energy storage but most of the systems are based on expensive metal ions or synthetic organics. Here, the authors show a chlorine flow battery capitalizing the electrolysis of saltwater where the redox reaction is stabilized by the saltwater-immiscible organic flow.
- Singyuk Hou
- , Long Chen
- & Chunsheng Wang
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Article
| Open AccessA dual-function liquid electrolyte additive for high-energy non-aqueous lithium metal batteries
Lithium metal batteries suffer from poor (electro)chemical stability of the electrodes during prolonged cycling. Here, the authors report a dual function liquid electrolyte additive to form protective interphases on both electrodes to produce lab-scale high energy lithium metal batteries.
- Yuji Zhang
- , Yuan Wu
- & Chengxin Wang
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Article
| Open AccessImproving the oxygen redox reversibility of Li-rich battery cathode materials via Coulombic repulsive interactions strategy
Tailoring the oxygen redox reactivity in Li-rich cathode is crucial for developing high-energy batteries. Here, the authors report a strategy to obtain a flexible crystal structure and enhance the oxygen redox reversibility.
- Qingyuan Li
- , De Ning
- & Xiangfeng Liu
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Article
| Open AccessA new approach exploiting thermally activated delayed fluorescence molecules to optimize solar thermal energy storage
Direct conversion of solar energy to stored chemical energy can be achieved through photoisomerization. Here, authors exploit thermally activated delayed fluorescence materials as a photosensitizer and signal transducer to harness solar energy, to maximize solar spectrum harvesting without sacrificing energy storage time.
- Fan-Yi Meng
- , I-Han Chen
- & Pi-Tai Chou
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Article
| Open AccessFew-layer bismuth selenide cathode for low-temperature quasi-solid-state aqueous zinc metal batteries
The performances of rechargeable batteries are detrimentally affected by low temperatures (e.g., < 0 °C). Here, the authors report a few-layer Bi2Se3 material capable of improving battery cycling performances when operational temperatures are shifted from +25 °C to −20 °C.
- Yuwei Zhao
- , Yue Lu
- & Chunyi Zhi
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Article
| Open AccessThermal-healing of lattice defects for high-energy single-crystalline battery cathodes
The lattice strain and defects in layered oxides is critical to the intercalation chemistry and battery performance. Here, the authors demonstrate a thermal-healing of lattice defects in single-crystalline cathodes caused by the thermal-induced release of lattice strain and the structure ordering.
- Shaofeng Li
- , Guannan Qian
- & Yijin Liu
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Comment
| Open AccessOpen challenges and good experimental practices in the research field of aqueous Zn-ion batteries
Aqueous Zn-based batteries represent a viable and cost-effective technology for electricity grid storage. Here, the authors discuss the most challenging aspects to bridge academic and industrial research and accelerate the adoption of this class of devices on a large scale.
- Giorgia Zampardi
- & Fabio La Mantia
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Article
| Open AccessCarbon-coated MoS1.5Te0.5 nanocables for efficient sodium-ion storage in non-aqueous dual-ion batteries
Sodium-based dual-ion batteries are promising electrochemical energy storage devices. Here, the authors report a source-template synthetic strategy to prepare carbon-coated MoS1.5Te0.5 nanocables and their use as anode active materials in Na-based dual ion cells.
- Yangjie Liu
- , Xiang Hu
- & Zhenhai Wen
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Article
| Open AccessAluminum-copper alloy anode materials for high-energy aqueous aluminum batteries
Aqueous Al-ion batteries are attractive post-lithium battery technologies. Here Al-Cu alloy lamellar heterostructures with periodic galvanic couplings are reported as efficient anode active material to produce high-energy aqueous Al-ion batteries.
- Qing Ran
- , Hang Shi
- & Qing Jiang
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Article
| Open AccessNative lattice strain induced structural earthquake in sodium layered oxide cathodes
Native crystallographic defects are often introduced during synthesis of battery materials, but has been overlooked. Here, using in situ synchrotron X-ray probes and electron microscopy, the authors have revealed their adverse effect during battery operation.
- Gui-Liang Xu
- , Xiang Liu
- & Khalil Amine
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Article
| Open AccessOperando monitoring of ion activities in aqueous batteries with plasmonic fiber-optic sensors
Operando tracking the ion dynamics/states of battery is critical to understanding of electrolyte-electrode interactions. Here the authors propose to use the surface plasmon waves to rapidly screen localized electrochemical events on a sub-μm-scale thickness adjacent to the electrode interface, without perturbing battery operation.
- Runlin Wang
- , Haozhe Zhang
- & Tuan Guo
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Article
| Open AccessMultifactorial engineering of biomimetic membranes for batteries with multiple high-performance parameters
Lithium–sulfur batteries have a high specific capacity, but lithium polysulfide diffusion (LPS) and dendrite growth reduce their cycle life. Here, the authors show a biomimetic aramid nanofiber membrane for effectively suppressing LPS diffusion as well as lithium dendrites while allowing lithium ions to be transported. The membranes resists performance degradation at high temperatures and can be produced at scale by Kevlar recycling.
- Mingqiang Wang
- , Ahmet E. Emre
- & Nicholas A. Kotov
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Article
| Open AccessSingle-dispersed polyoxometalate clusters embedded on multilayer graphene as a bifunctional electrocatalyst for efficient Li-S batteries
Efficient electrochemical energy storage in Li-S batteries is hindered by sluggish sulfur redox reactions. Here, the authors propose a polyoxometalate/multilayer graphene composite as a bifunctional electrocatalyst for battery performance improvement.
- Jie Lei
- , Xiao-Xiang Fan
- & Jia-Jia Chen
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Article
| Open AccessEffect of the supergravity on the formation and cycle life of non-aqueous lithium metal batteries
The behavior of lithium metal batteries at various gravity levels is not yet clearly understood. Here, the authors demonstrate the beneficial effect of supergravity in terms of battery performance improvement and favorable solid electrolyte interphase formation.
- Yuliang Gao
- , Fahong Qiao
- & Keyu Xie
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Article
| Open AccessZinc ion thermal charging cell for low-grade heat conversion and energy storage
Low-grade heat conversion has recently emerged and displayed great promise in sustainable electronics and energy areas. Here, the authors propose a new zinc ion thermal charging cell with hybrid behaviours for high value-added conversion from heat to electricity.
- Zhiwei Li
- , Yinghong Xu
- & Xiaogang Zhang
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Article
| Open AccessFlame retardant high-power Li-S flexible batteries enabled by bio-macromolecular binder integrating conformal fractions
Prime concerns of Li-S batteries revolve around the sulfur’s utility ranging from its performance to safety concerns. Here, the authors use biomacromolecular binder imparting conformal property to trigger high sulfur reactivity and modulate polysulfides while manifesting flame retardability.
- Chenrayan Senthil
- , Sun-Sik Kim
- & Hyun Young Jung
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Article
| Open AccessCoupling aqueous zinc batteries and perovskite solar cells for simultaneous energy harvest, conversion and storage
Accumulation of intermittent solar energy using secondary batteries is an appealing solution for future power sources. Here, the authors propose a device comprising of perovskite solar cells and aqueous zinc metal batteries connected via the sandwich joint electrode method.
- Peng Chen
- , Tian-Tian Li
- & Xue-Ping Gao
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Article
| Open AccessSuppressing electrolyte-lithium metal reactivity via Li+-desolvation in uniform nano-porous separator
Lithium dendrite and parasitic reactions are two major challenges for lithium metal anode. Here, the authors show suppression of lithium-dendrite and elimination of continuous parasitic reactions by tuning the reduction kinetics of lithium-ion through a uniform nano-porous separator.
- Li Sheng
- , Qianqian Wang
- & Xiangming He
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Article
| Open AccessA Mo5N6 electrocatalyst for efficient Na2S electrodeposition in room-temperature sodium-sulfur batteries
Incomplete conversion of sodium polysulfides represents a significant issue in room-temperature sodium-sulfur batteries. Here, the authors propose Mo5N6 as an electrocatalyst for efficient Na2S electrodeposition and improved cell cycling performances.
- Chao Ye
- , Huanyu Jin
- & Shi-Zhang Qiao
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Article
| Open AccessImproving the alkali metal electrode/inorganic solid electrolyte contact via room-temperature ultrasound solid welding
The practical application of solid-state rechargeable alkali metal batteries is hindered by the poor contact between the metal electrode and the solid electrolyte. Here, the authors report an ultrasound solid welding strategy to favor the contact between these cells components.
- Xinxin Wang
- , Jingjing Chen
- & Zhiyong Mao
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Article
| Open AccessA rechargeable aqueous manganese-ion battery based on intercalation chemistry
Multivalent metal batteries are considered a viable alternative to Li-ion batteries. Here, the authors report a novel aqueous battery system when manganese ions are shuttled between an Mn metal/carbon composite anode and inorganic or organic cathodes.
- Songshan Bi
- , Shuai Wang
- & Zhiqiang Niu
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Article
| Open AccessGrowth of lithium-indium dendrites in all-solid-state lithium-based batteries with sulfide electrolytes
Li-In alloys are widely used as reference materials in the research field of solid-state lithium-based batteries. Here, the authors report and discuss the instability of Li-In electrodes towards sulfide solid electrolytes in all-solid-state batteries.
- Shuting Luo
- , Zhenyu Wang
- & Xing Zhang
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Article
| Open AccessDefect engineering on V2O3 cathode for long-cycling aqueous zinc metal batteries
Aqueous Zn metal batteries are a promising system for high-power electrochemical energy storage. Here, the authors investigate a defective V2O3 cathode via neutron and X-ray techniques and test the material in Zn metal cell configuration for 30k cycles.
- Kefu Zhu
- , Shiqiang Wei
- & Li Song
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Article
| Open AccessPhotochemically driven solid electrolyte interphase for extremely fast-charging lithium-ion batteries
Extremely fast charging such as charging 80% of capacity within 15 min is a pressing requirement for current lithium-ion battery technology. Here the authors achieve this by incorporating an artificial solid-electrolyte interphase rich in inorganic components on the graphite electrode.
- Minsung Baek
- , Jinyoung Kim
- & Jang Wook Choi
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Article
| Open AccessA mechanistic investigation of the Li10GeP2S12|LiNi1-x-yCoxMnyO2 interface stability in all-solid-state lithium batteries
Fundamental investigations at the electrode/electrolyte interface are essential for developing high-energy batteries. Here, the authors investigate the degradation mechanisms at the LGPS/NCM622 interface providing a quantitative model to interpret the interfacial resistance growth.
- Tong-Tong Zuo
- , Raffael Rueß
- & Jürgen Janek
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Article
| Open AccessSelective cobalt and nickel electrodeposition for lithium-ion battery recycling through integrated electrolyte and interface control
Recovery of metals from Li-ion batteries is a key for sustainability. Here the authors demonstrate a Li-ion cell recycling process via selective electrochemical Co and Ni recovery by controlling the electrode interface and the electrolyte.
- Kwiyong Kim
- , Darien Raymond
- & Xiao Su
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Article
| Open AccessTransition metal-doped Ni-rich layered cathode materials for durable Li-ion batteries
Long-term efficient cycling stability is of paramount importance for the development of high-energy Li-ion batteries. Here, the authors investigate the effect of transition metal dopants on the electrochemical, morphological, and structural properties of Ni-rich cathode active materials.
- H. Hohyun Sun
- , Un-Hyuck Kim
- & Yang-Kook Sun
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Comment
| Open AccessUnderstanding Li-based battery materials via electrochemical impedance spectroscopy
Electrochemical impedance spectroscopy is a key technique for understanding Li-based battery processes. Here, the authors discuss the current state of the art, advantages and challenges of this technique, also giving an outlook for future developments.
- Miran Gaberšček
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Article
| Open AccessHigh dielectric barium titanate porous scaffold for efficient Li metal cycling in anode-free cells
The development of anode-free batteries requires current collectors able to deposit and remove Li metal upon cycling efficiently. Here, the authors report the use of high dielectric porous BaTiO3 to avoid the formation of inhomogeneous Li metal depositions during anode-free cell cycling.
- Chao Wang
- , Ming Liu
- & Marnix Wagemaker
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Article
| Open AccessStructural ceramic batteries using an earth-abundant inorganic waterglass binder
Structural batteries hold particular promise for decarbonizing the aviation industry. Here, the authors demonstrate that waterglass, an earth-abundant water-soluble silicate adhesive, can be used as a binder in structural batteries allowing them to both bear load and store electricity at the same time.
- Alan Ransil
- & Angela M. Belcher
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Article
| Open AccessEvolving contact mechanics and microstructure formation dynamics of the lithium metal-Li7La3Zr2O12 interface
All-solid-state batteries are promising alternatives to Li-ion batteries. Here, the authors investigate the chemo-mechanical changes at the lithium metal/solid electrolyte interface via operando acoustic transmission and magnetic resonance imaging.
- Wesley Chang
- , Richard May
- & Daniel Steingart
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Article
| Open AccessA Fe3N/carbon composite electrocatalyst for effective polysulfides regulation in room-temperature Na-S batteries
Room-temperature sodium-sulfur batteries are promising electrochemical energy storage systems. Here, the authors proposed a Fe3N/carbon composite to regulate the polysulfides chemistry and improve the performances of sodium-sulfur cells.
- Yuruo Qi
- , Qing-Jie Li
- & Maowen Xu
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Comment
| Open AccessThe importance of electrode interfaces and interphases for rechargeable metal batteries
Metal electrode interfaces and interphases are critical for the development of future high-energy metal batteries. Here, Dr Jelena Popovic-Neuber discusses the state of the art, issues and strategies to improve the stability of metal electrodes toward practical battery systems.
- Jelena Popovic
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Article
| Open AccessDeep learning-based segmentation of lithium-ion battery microstructures enhanced by artificially generated electrodes
Accurate 3D representations of lithium-ion battery electrodes can help in understanding and ultimately improving battery performance. Here, the authors report a methodology for using deep-learning tools to reliably distinguish the different electrode material phases where standard approaches fail.
- Simon Müller
- , Christina Sauter
- & Vanessa Wood
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Article
| Open AccessRational design of mechanically robust Ni-rich cathode materials via concentration gradient strategy
Mechanical integrity issues are one of the main causes of limited long-term cycle stability for Ni-rich cathode materials. Here the authors analyse the roles of cobalt and manganese and utilise a concentration gradient design to mitigate these issues.
- Tongchao Liu
- , Lei Yu
- & Khalil Amine
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Article
| Open AccessOn the crystallography and reversibility of lithium electrodeposits at ultrahigh capacity
Lithium metal batteries offer high-capacity electrical energy storage but suffer from poor reversibility of the metal anode. Here, the authors report that at very high capacities, lithium deposits as dense structures with a preferred crystallite orientation, yielding highly reversible lithium anodes.
- Qing Zhao
- , Yue Deng
- & Lynden A. Archer
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Article
| Open AccessQuantification of the Li-ion diffusion over an interface coating in all-solid-state batteries via NMR measurements
Development of all-solid-state batteries requires stable solid electrolyte-electrode interfaces. Here, via exchange-NMR measurements, the authors investigate the positive electrode-solid electrolyte interface, revealing the impact of an inorganic coating on the Li-ion transport properties.
- Ming Liu
- , Chao Wang
- & Marnix Wagemaker
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Article
| Open AccessAchieving stable Na metal cycling via polydopamine/multilayer graphene coating of a polypropylene separator
The development of future Na metal batteries relies on the cycling stability of the metallic anode. Here, the authors propose a polypropylene separator functionalized with polydopamine and multilayer graphene to enable stable and prolonged Na metal cell cycling.
- Jieqiong Qin
- , Haodong Shi
- & Zhong-Shuai Wu
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Article
| Open AccessA synergistic exploitation to produce high-voltage quasi-solid-state lithium metal batteries
The energy content increase is of paramount importance for the development of future Li-based batteries. Here, the authors propose a gel polymer electrolyte in combination with a positive electrode comprising of a Li-rich oxide active material and graphite to produce a high-energy Li metal cell.
- Junru Wu
- , Xianshu Wang
- & Guoxiu Wang
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Article
| Open AccessReversible electrochemical oxidation of sulfur in ionic liquid for high-voltage Al−S batteries
The sulfur cathode in metal-sulfur batteries normally undergoes electrochemical reduction to form metal sulfides. Here, the authors demonstrate the electrochemical oxidation of sulfur in ionic liquid for high-voltage aluminium-sulfur batteries.
- Huan Li
- , Rongwei Meng
- & Shi-Zhang Qiao
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Article
| Open AccessAn electron-deficient carbon current collector for anode-free Li-metal batteries
The development of anode-free batteries requires fundamental investigations at the current collector/electrolyte interface. Here, the authors report an atomically defective carbon current collector to improve the electrochemical behaviour of an anode-free Li-based cell.
- Hyeokjin Kwon
- , Ju-Hyuk Lee
- & Hee-Tak Kim
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Article
| Open AccessNanofluidic voidless electrode for electrochemical capacitance enhancement in gel electrolyte
Enhancing electrode capacitance without compromising one other metrics for solid-state supercapacitors is of high interest yet difficult to achieve. Here the authors demonstrate a strategy of using nanofluidic electrode with very low porosity to increase the electrochemical capacitance of gel-based solid state supercapacitor.
- Kefeng Xiao
- , Taimin Yang
- & Da-Wei Wang
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Article
| Open AccessActivation of anionic redox in d0 transition metal chalcogenides by anion doping
Activation of anionic redox in battery materials promises great benefits for battery materials, but remains an elusive phenomenon. Here, the authors present anion-doping as a novel strategy to unlock electrochemical activity in the cobalt/nickel free cathode material, Li2TiS3-xSex.
- Bernhard T. Leube
- , Clara Robert
- & Jean-Marie Tarascon