Abstract
Highly efficient stereoregular polymerizations within template nanospaces using free radical initiators, based on stereocomplexes formed between isotactic and syndiotactic methacrylate polymers are reviewed. Ultrathin films composed of double-stranded helical or van der Waals contacted stereocomplex nanostructures were successfully prepared by the layer-by-layer assembly method, and fundamental aspects of film preparation were summarized. Template nanospaces were prepared by the selective solvent extraction of a single component from stereocomplex films composed of it-poly(methyl methacrylate) and st-poly(methacrylic acid). The resulting porous films with designed nanospaces were used for template polymerizations. Methacrylate polymers with high iso- and syndiotacticities were synthesized within nanospaces. Structural information not only of template stereoregularity but also of template chain length was efficiently transferred to synthesized polymers.
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Serizawa, T., Akashi, M. Stereoregular Polymerization within Template Nanospaces. Polym J 38, 311–328 (2006). https://doi.org/10.1295/polymj.38.311
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DOI: https://doi.org/10.1295/polymj.38.311