Article abstract


Nature Physics 4, 643 - 648 (2008)
Published online: 11 July 2008 | doi:10.1038/nphys1024

Subject Categories: Condensed-matter physics | Materials physics

Heavy electrons and the symplectic symmetry of spin

Rebecca Flint, M. Dzero & P. Coleman


The recent discovery of two heavy-fermion materials PuCoGa5 and NpPd5Al2, which transform directly from Curie paramagnets into superconductors, reveals a new class of superconductors where local moments quench directly into the superconducting condensate. Unlike other heavy-electron superconductors, where Cooper pairing is thought to be driven by spin fluctuations, these higher-transition-temperature materials do not seem to be close to a magnetic instability. Large-N expansions have been invaluable in describing heavy-fermion metals, but so far cannot treat superconductivity. Here, we introduce a new class of large-N expansion that uses symplectic symmetry to protect the odd time-reversal parity of spin and sustain Cooper pairs as well-defined singlets. We show that when a lattice of magnetic ions exchange spin with their metallic environment in two distinct symmetry channels, they can simultaneously satisfy both channels by forming a condensate of composite pairs between local moments and electrons. In the tetragonal crystalline environment relevant to PuCoGa5 and NpPd5Al2, the lattice structure selects a natural pair of spin exchange channels, predicting a unique anisotropic paired state with either d- or g-wave symmetry. This pairing mechanism also predicts a large upturn in the NMR relaxation rate above Tc and strong enhancement of Andreev reflection in tunnelling measurements.

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  1. Center for Materials Theory, Rutgers University, Piscataway, New Jersey 08854, USA

Correspondence to: P. Coleman e-mail: coleman@physics.rutgers.edu



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