Unusual lattice vibrations have been discovered in scandium trifluoride — a simple compound that shrinks when heated. This finding may help to explain the phenomenon of negative thermal expansion.
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References
Li, C. W. et al. Phys. Rev. Lett. 107, 195504 (2011).
Greve, B. K. et al. J. Am. Chem. Soc. 132, 15496–15498 (2010).
Mary, T. A., Evans, J. S. O., Vogt, T. & Sleight, A. W. Science 272, 90–92 (1996).
Takenaka, K. & Takagi, H. Appl. Phys. Lett. 87, 261902 (2005).
Azuma, M. et al. Nature Commun. 2, 347 (2011).
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Attfield, J. A fresh twist on shrinking materials. Nature 480, 465–466 (2011). https://doi.org/10.1038/480465a
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DOI: https://doi.org/10.1038/480465a
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