1. Department of Chemical Engineering, Stanford University, Stanford, California 94305, USA
2. Department of Chemistry and Biochemistry and Exotic Materials Institute, Department of Materials Science and Engineering, University of California-Los Angeles, Los Angeles, California 90095, USA

Correspondence to: Zhenan Bao¹ Correspondence and requests for materials should be addressed to Z.B. (Email: zbao@chemeng.stanford.edu).

Abstract

Field-effect transistors made of organic single crystals are ideal for studying the charge transport characteristics of organic semiconductor materials¹. Their outstanding device performance^{2, 3, 4, 5, 6, 7, 8}, relative to that of transistors made of organic thin films, makes them also attractive candidates for electronic applications such as active matrix displays and sensor arrays. These applications require minimal cross-talk between neighbouring devices. In the case of thin film systems, simple patterning of the active semiconductor layer^{9, 10} minimizes cross-talk. But when using organic single crystals, the only approach currently available for creating arrays of separate devices is manual selection and placing of individual crystals—a process prohibitive for producing devices at high density and with reasonable throughput. In contrast, inorganic crystals have been grown in extended arrays^{11, 12, 13}, and efficient and large-area fabrication of silicon crystalline islands with high mobilities for electronic applications has been reported^{14, 15}. Here we describe a method for effectively fabricating large arrays of single crystals of a wide range of organic semiconductor materials directly onto transistor source–drain electrodes. We find that film domains of octadecyltriethoxysilane microcontact-printed onto either clean Si/SiO₂ surfaces or flexible plastic provide control over the nucleation of vapour-grown organic single crystals. This allows us to fabricate large arrays of high-performance organic single-crystal field-effect transistors with mobilities as high as 2.4 cm² V^-1 s^-1 and on/off ratios greater than 10⁷, and devices on flexible substrates that retain their performance after significant bending. These results suggest that our fabrication approach constitutes a promising step that might ultimately allow us to utilize high-performance organic single-crystal field-effect transistors for large-area electronics applications.

1. Department of Chemical Engineering, Stanford University, Stanford, California 94305, USA
2. Department of Chemistry and Biochemistry and Exotic Materials Institute, Department of Materials Science and Engineering, University of California-Los Angeles, Los Angeles, California 90095, USA

Correspondence to: Zhenan Bao¹ Correspondence and requests for materials should be addressed to Z.B. (Email: zbao@chemeng.stanford.edu).

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