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Nature 436, 993-996 (18 August 2005) | doi:10.1038/nature03977; Received 18 May 2005; Accepted 27 June 2005

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Experimental measurement of the photonic properties of icosahedral quasicrystals

Weining Man1,2, Mischa Megens3, Paul J. Steinhardt1 & P. M. Chaikin1,2,4

  1. Department of Physics,
  2. Princeton Institute for the Science and Technology of Materials, Princeton University, Princeton, New Jersey, 08544, USA
  3. Philips Research Laboratories, Prof. Holstlaan 4, NL-5656 AA Eindhoven, The Netherlands
  4. Department of Physics and Center for Soft Condensed Matter Research, New York University, New York 10003, USA

Correspondence to: Paul J. Steinhardt1 Correspondence and requests for materials should be addressed to P.J.S. (Email: steinh@princeton.edu).

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Quasicrystalline structures may have optical bandgap properties—frequency ranges in which the propagation of light is forbidden—that make them well-suited to the scientific and technological applications for which photonic crystals1, 2, 3 are normally considered4. Such quasicrystals can be constructed from two or more types of dielectric material arranged in a quasiperiodic pattern whose rotational symmetry is forbidden for periodic crystals (such as five-fold symmetry in the plane and icosahedral symmetry in three dimensions). Because quasicrystals have higher point group symmetry than ordinary crystals, their gap centre frequencies are closer and the gaps widths are more uniform—optimal conditions for forming a complete bandgap that is more closely spherically symmetric. Although previous studies have focused on one-dimensional and two-dimensional quasicrystals4, 5, 6, 7, where exact (one-dimensional) or approximate (two-dimensional) band structures can be calculated numerically, analogous calculations for the three-dimensional case are computationally challenging and have not yet been performed. Here we circumvent the computational problem by doing an experiment. Using stereolithography, we construct a photonic quasicrystal with centimetre-scale cells and perform microwave transmission measurements. We show that three-dimensional icosahedral quasicrystals exhibit sizeable stop gaps and, despite their quasiperiodicity, yield uncomplicated spectra that allow us to experimentally determine the faces of their effective Brillouin zones. Our studies confirm that they are excellent candidates for photonic bandgap materials.

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