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The development of molecule-based porous material families and their future prospects

Metal–organic frameworks, porous coordination network materials constructed with metal ions and organic molecules, have grown over the past 20 years into an innovative chemistry that has contributed to solutions for the problems faced by humanity in the environment, resources, energy and health.

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Fig. 1: Major MOF discoveries and developments over the past 20 years.
Fig. 2: Porous materials can manipulate gases, ions and macromolecules and contribute to society in many aspects.

References

  1. Yaghi, O. M. et al. Nature 423, 705–714 (2003).

    Article  CAS  Google Scholar 

  2. Kitagawa, S., Kitaura, R. & Noro, S. Angew. Chem. Int. Ed. 43, 2334–2375 (2004).

    Article  CAS  Google Scholar 

  3. Bennett, T. D. et al. Nat. Mater. 20, 1179–1187 (2021).

    Article  CAS  Google Scholar 

  4. Devic, T. & Serre, C. Chem. Soc. Rev. 43, 6097–6115 (2014).

    Article  CAS  Google Scholar 

  5. Lee, J. et al. Chem. Soc. Rev. 38, 1450–1459 (2009).

    Article  CAS  Google Scholar 

  6. Chen, L. & Xu, Q. Matter 1, 57–89 (2019).

    Article  Google Scholar 

  7. Horike, S., Shimomura, S. & Kitagawa, S. Nat. Chem. 1, 695–704 (2009).

    Article  CAS  Google Scholar 

  8. Deng, H. et al. Nat. Chem. 2, 439–443 (2010).

    Article  CAS  Google Scholar 

  9. Bon, V. et al. Adv. Funct. Mater. 30, 1907847 (2020).

    Article  CAS  Google Scholar 

  10. Tan, J. C., Bennett, T. D. & Cheetham, A. K. Proc. Natl Acad. Sci. USA 107, 9938–9943 (2010).

    Article  CAS  Google Scholar 

  11. Xie, L. S., Skorupskii, G. & Dincă, M. Chem. Rev. 120, 8536–8580 (2020).

    Article  CAS  Google Scholar 

  12. Stassen, I. et al. Nat. Mater. 15, 304–310 (2016).

    Article  CAS  Google Scholar 

  13. Allendorf, M. D. et al. Chem. Eur. J. 17, 11372–11388 (2011).

    Article  CAS  Google Scholar 

  14. Horcajada, P. et al. Chem. Rev. 112, 1232–1268 (2012).

    Article  CAS  Google Scholar 

  15. He, C., Liu, D. & Lin, W. Chem. Rev. 115, 11079–11108 (2015).

    Article  CAS  Google Scholar 

  16. Bennett, T. D. & Horike, S. Nat. Rev. Mater. 3, 431–440 (2018).

    Article  Google Scholar 

  17. Chung, Y. G. et al. Chem. Mater. 26, 6185–6192 (2014).

    Article  CAS  Google Scholar 

  18. Zhu, Y. et al. Nat. Mater. 16, 532–536 (2017).

    Article  CAS  Google Scholar 

  19. Cliffe, M. J. et al. Nat. Commun. 5, 4176 (2014).

    Article  CAS  Google Scholar 

  20. Lin, J. B. et al. Science 374, 1464–1469 (2021).

    Article  CAS  Google Scholar 

  21. Datta, S. J. et al. Science 376, 1080–1087 (2022).

    Article  CAS  Google Scholar 

  22. Butler, K. T. et al. Chem. Sci. 7, 6316–6324 (2016).

    Article  CAS  Google Scholar 

Download references

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Correspondence to Satoshi Horike or Susumu Kitagawa.

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Nature Materials thanks Christian Serre and the other, anonymous, reviewer(s) for their contribution to the peer review of this work.

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Horike, S., Kitagawa, S. The development of molecule-based porous material families and their future prospects. Nat. Mater. 21, 983–985 (2022). https://doi.org/10.1038/s41563-022-01346-7

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