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SINGLE-ATOM CHEMISTRY

Probing precipitation properties

Superheavy elements are short-lived and only available on a single-atom level, making their chemical properties very challenging to study. Now, through their co-precipitation with samarium, single atoms of rutherfordium have been shown to form hydroxide complexes but not ammine ones.

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Fig. 1: SHEs and their (relative) availability for chemical studies.
Fig. 2: Schematic view of the co-precipitation process.

References

  1. Oganessian, Y. T. & Utyonkov, V. K. Rep. Prog. Phys. 78, 036301 (2015).

    Article  Google Scholar 

  2. Pyykkö, P. Adv. Quantum Chem. 11, 353–409 (1978).

    Article  Google Scholar 

  3. Schwerdtfeger, P., Smits, O. R. & Pyykkö, P. Nat. Rev. Chem. 4, 359–380 (2020).

    Article  CAS  Google Scholar 

  4. Kasamatsu, Y. et al. Nat. Chem. https://doi.org/10.1038/s41557-020-00634-6 (2020).

  5. Chemical Precipitation Processes for the Treatment of Aqueous Radioactive Waste Technical Reports Series No. 337 (IAEA, 1992).

  6. Kasamatsu, Y. et al. Appl. Radiat. Isot. 118, 105–116 (2016).

    Article  CAS  Google Scholar 

  7. Kasamatsu, Y. et al. J. Nucl. Radiochem. Sci. 14, 7–11 (2014).

    Article  CAS  Google Scholar 

  8. Kolthoff, I. M. J. Phys. Chem. 36, 860–881 (1932).

    Article  CAS  Google Scholar 

  9. Türler, A., Eichler, R. & Yakushev, A. Nucl. Phys. A 944, 640–689 (2015).

    Article  Google Scholar 

  10. Nagame, Y., Kratz, J. V. & Schädel, M. Nucl. Phys. A 944, 614–639 (2015).

    Article  CAS  Google Scholar 

  11. Fricke, B. & Waber, J. T. Actinides Rev. 1, 433 (1971).

    CAS  Google Scholar 

Download references

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Correspondence to Alexander Yakushev.

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Yakushev, A. Probing precipitation properties. Nat. Chem. 13, 213–215 (2021). https://doi.org/10.1038/s41557-020-00625-7

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