Abstract
Homopolymerization and copolymerization of N-(4-carboxyphenyl)maleimide (CPMI) were performed at 70°C in the presence of azobisisobutyronitrile (AIBN) as an initiator in tetrahydrofuran. The initial rate of polymerization was Rp=k[AIBN]0.65 [CPMI]2.4, where k is an over-all rate constant. The monomer reactivity ratios (r1, r2) in the polymerization of CPMI (M1) with styrene (ST, M2), or with methyl methacrylate (MMA, M2) and Alfrey-Price Q, e values were determined as r1=0.019, r2=0.23, Q1=0.67, e1=1.53 for the CPMI-ST system; r1=0.24, r2=1.08, Q1=1.09, e1=1.56 for the CPMI-MMA system.
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Oishi, T., Iwahara, M. & Fujimoto, M. Polymerization and Copolymerization of N-(4-Carboxyphenyl)maleimide. Polym J 23, 1409–1417 (1991). https://doi.org/10.1295/polymj.23.1409
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DOI: https://doi.org/10.1295/polymj.23.1409
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