Compound 1a

(E)-Methyl 3-(1H-naphtho[1,8-de][1,3,2]diazaborinin-2(3H)-yl)acrylate

From: Enantioselective preparation and chemoselective cross-coupling of 1,1-diboron compounds

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InChIKey JXSTUGKQHAKCLR-CMDGGOBGSA-N

Synthetic procedure: See article for the definitive version of this procedure and for full experimental details.

Compound 1a was prepared according to a literature procedure (Lee, J. C. H& Hall, D. G. Chiral Boronate Derivatives via Catalytic Enantioselective Conjugate Addition of Grignard Reagents on 3-Boronyl Unsaturated Esters and Thioesters. J. Am. Chem. Soc. 132, 5544–5555 (2010))