Compound 4h

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InChIKey AGTQETPKLNIDGU-UHFFFAOYSA-N

Compound data: CIF

Synthetic procedure: See article for the definitive version of this procedure and for full experimental details.

A typical experimental procedure is given for compound 4a. ¹H NMR (400.13 MHz, CD₂Cl₂, 30 °C): δ 7.84 – 7.18 (m, 30 ArH), δ 3.37 – 2.87 (m, 8 Aliph-H); ³¹P{¹H} NMR (162.0 MHz, CD₂Cl₂, 30 °C): δ 45.9 (s, ¹J_P-Pt= 3140 Hz). HRMS (ESI): m/z calcd for C₄₀H₃₈ClP₂PtS₂ [M-2BF₄+Cl]⁺: 874.1226, found: 874.1248. Single crystals suitable for X-Ray studies were grown by slow diffusion of diethyl ether, layered on top of a dichloromethane solution of 4h in a NMR tube.