Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • News & Views
  • Published:

Reaction dynamics

Surrounded by complications

There is a long history of gas-phase studies of bimolecular reactions, but the presence of surrounding molecules complicates analogous studies in solution. Now, advances in ultrafast laser technology have enabled the detailed study of vibrational energy release in a reaction in solution.

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Figure 1: Schematic plots of energy along the reaction coordinate for the reaction of an alkane with CN.

References

  1. Brouard, M. & Vallance, C. Tutorials in Molecular Reaction Dynamics (Royal Society of Chemistry, 2010).

    Google Scholar 

  2. Polanyi, J. C. Accounts Chem. Res. 5, 161–168 (1972).

    Article  CAS  Google Scholar 

  3. Greaves, S. J. et al. Science 10.1126/science.1197796 (2011).

  4. Crim, F. F. Proc. Natl Acad. Sci. USA 105, 12654–12661 (2008).

    Article  CAS  Google Scholar 

  5. Owrutsky, J. C., Raftery, D. & Hochstrasser, R. M. Annu. Rev. Phys. Chem. 45, 519–555 (1994).

    Article  CAS  Google Scholar 

  6. Elles, C. G. & Crim, F. F. Annu. Rev. Phys. Chem. 57, 273–302 (2006).

    Article  CAS  Google Scholar 

  7. Raftery, D., Gooding, E., Romanovsky, A. & Hochstrasser, R. M. J. Chem. Phys. 101, 8572–8579 (1994).

    Article  CAS  Google Scholar 

  8. Crowther, A. C., Carrier, S. L., Preston, T. J. & Crim, F. F. J. Phys. Chem. A 112, 12081–12089 (2008).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to F. Fleming Crim.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Crim, F. Surrounded by complications. Nature Chem 3, 344–345 (2011). https://doi.org/10.1038/nchem.1034

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1038/nchem.1034

This article is cited by

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing