This fluid can be used to create remarkable magnetic levitation and patterning effects.
Abstract
In magnetic levitation, a strong and spatially varying magnetic field exerts an upward force on a body that is sufficient to counteract its weight due to gravity. Here we show that this effect can be enhanced by immersing the body in cold oxygen gas, which provides a further strong and adjustable buoyancy force that allows a wide range of materials to be levitated in an open, unpressurized vessel. The buoyancy of magnetized liquid oxygen is sufficient to float even gold and platinum, suggesting that this technique could find application in mineral separation. An interesting periodic pattern is created on the surface of this pure elemental paramagnetic fluid.
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Magnetic levitation occurs when the force on a diamagnetic body, due to an inhomogeneous magnetic field, is strong enough to balance the body's weight due to Earth's gravity1. The levitation force per unit volume of the body is given by (χv/µ0)BdB/dz, where χv is the volume magnetic susceptibility, µ0 is the permeability of free space, B is the magnetic field and dB/dz is the vertical field gradient. Immersing the body in a paramagnetic fluid, such as gaseous oxygen, enhances the levitation by providing buoyancy through the magneto–Archimedes effect. This technique has been used to levitate sodium chloride (density, 2.17 g ml−1) in a closed vessel containing oxygen at a pressure of 60 atmospheres (6 megapascals) at room temperature2.
We exploit two well-known laws of physics to levitate a wider range of diamagnetic materials, including crystals of quartz (2.65 g ml−1), potassium bromide (2.75 g ml−1) and diamond (3.51 g ml−1), in an open vessel of cold oxygen gas at atmospheric pressure. According to Boyle's law, at a fixed pressure the gas density varies inversely with temperature; Curie's law states that the paramagnetic susceptibility is also inversely proportional to the temperature. Near the boiling point of liquid oxygen (90 K), the magnetic buoyancy of oxygen gas is therefore about ten times stronger than at room temperature. This enhanced levitation is shown in Fig. 1a (and see movie in supplementary information).
Liquid oxygen provides still greater buoyancy, which is sufficient to float, at relatively low magnetic-field strengths, the densest diamagnetic objects and even weakly paramagnetic objects. Figure 1b shows a silicon crystal, a gallium arsenide crystal, a £1 coin, a piece of lead and a gold coin, all floating in the liquid oxygen. Each object floats at the point at which the local magneto–Archimedes force balances its weight, so its levitation position can be adjusted by changing the magnetic-field strength. This feature could be of use in mineral-separation technology.
We also noted the formation of a regular pattern of peaks on the surface of slowly boiling liquid oxygen; this pattern is held as a membrane at the centre of the magnet bore (Fig. 1a, c, d). The peaks arise from a combination of magnetic and surface-energy effects and have been observed before in synthetic ferrofluids3, but their appearance in a pure elemental paramagnetic liquid merits further investigation.
At high magnetic-field strengths (B > 13 tesla), a simple square-lattice structure, decorated by edge dislocations, can be formed inside a small rectangular frame. In weaker fields, hexagonal close-packed crystallites are evident. When the heat input to the liquid oxygen is sufficiently great, the fluid exhibits convection and turbulence, which causes complicated motion of the microcrystallites and dislocations (see supplementary information). This could provide an experimental test bed for models of crystal formation and dynamics.
References
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Cowley, M. D. & Rosensweig, R. E. J. Fluid Mech. 30, 671–688 (1967).
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Catherall, A., Eaves, L., King, P. et al. Floating gold in cryogenic oxygen. Nature 422, 579 (2003). https://doi.org/10.1038/422579a
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DOI: https://doi.org/10.1038/422579a
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