Abstract
UNDER the title “Partition Isotherms and Gas-Liquid Chromatography,” Freeguard and Stock1 have reported that for all the systems studied by them, symmetrical elution peaks would be expected under normal gas-chromatographic conditions. Partition isotherms, however, when determined over partial pressures greater than those normally used in gas-chromatography, were found to be convex to the pressure axis.
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References
Freeguard, G. F., and Stock, R., Nature, 192, 257 (1961).
Gregg, S. J., and Stock, R., Gas Chromatography 1960, 90 edit. by Desty, D. H. (Butterworths, London, 1960).
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SCOTT, C. Adsorption Isotherms and Linear Gas-Solid Chromatography. Nature 193, 159–160 (1962). https://doi.org/10.1038/193159a0
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DOI: https://doi.org/10.1038/193159a0
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