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Study of the Oxidation of Hindered Phenols by Electron Spin Resonance

Abstract

THE detection by electron spin resonance of the 2,6,-di-t-butyl-4-methylphenoxy radical during the oxidation of the corresponding phenol with lead dioxide has been reported recently1. The purpose of this communication is to report a similar investigation of the free radicals formed during the oxidation of solutions of the hindered phenols 2,6,-di-t-butyl-4-R-phenol [where R ≡ methyl (I); ethyl (II); and t-butyl (III)] with an alkaline solution of potassium ferricyanide.

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References

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BENNETT, J. Study of the Oxidation of Hindered Phenols by Electron Spin Resonance. Nature 186, 385–386 (1960). https://doi.org/10.1038/186385a0

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