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Cohesive Energy Density of Polystyrene

Abstract

Bristow and Watson1 have recently described the determination of the cohesive energy densities of polymers by swelling and viscosity measurements. This communication summarizes the results of viscosity measurements on polystyrene solutions directed towards a similar end. The measurements cover a slightly different range of solvents from that of Bristow and Watson, and in some solvents a range of molecular weights has been investigated.

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References

  1. Bristow, G. M., and Watson, W. F., Trans. Farad. Soc., 54, 1567, 1731, 1742 (1958).

    Article  CAS  Google Scholar 

  2. Flory, P. J., and Fox, T. G., J. Amer. Chem. Soc., 73, 1904 (1951).

    Article  CAS  Google Scholar 

  3. Streeter, D. J., and Boyer, R. F., Indust. Eng. Chem., 43, 1790 (1951).

    Article  CAS  Google Scholar 

  4. Schick, A. F., quoted in Boundy, R. H., and Boyer, R. F., “Styrene, its Polymers, Copolymers and Derivatives”, 390 (Reinhold, New York, 1952).

    Google Scholar 

  5. Bawn, C. E. H., Freeman, R. F. J., and Kamaliddin, A. R., Trans. Farad. Soc., 46, 677 (1950). Bawn, C. E. H., and Wajid, M. A., ibid., 52, 1458 (1956).

    Article  CAS  Google Scholar 

  6. Flory, P. J., “Principles of Polymer Chemistry”, 602 (Cornell, New York, 1953).

    Google Scholar 

  7. Bawn, C. E. H., Freeman, R. F. J., and Kamaliddin, A. R., Trans. Farad. Soc., 46, 1107 (1950).

    Article  CAS  Google Scholar 

  8. Huggins, M. L., J. Chem. Phys., 9, 440 (1951).

    Article  ADS  Google Scholar 

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GREEN, J. Cohesive Energy Density of Polystyrene. Nature 183, 818–819 (1959). https://doi.org/10.1038/183818a0

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