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| Open AccessNeon encapsulation by a hydroquinone organic crystalline clathrate under ambient conditions
It is difficult to store noble gases in solids due to their chemical inertness and relative lightness. Here, a hydroquinone organic clathrate can stably capture neon at atmospheric pressure and room temperature and be released at elevated temperatures.
- Sol Geo Lim
- , Jong-Won Lee
- & Ji-Ho Yoon
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Article
| Open AccessCavity vat photopolymerisation for additive manufacturing of polymer-composite 3D objects
There is an ongoing drive for new additive manufacturing processes that produce complex parts. Here, cavity vat polymerisation is introduced, in which cavities are filled with a dual-curing resin that forms an elastomer/thermoset covalently bonded interface, creating hard-shell/soft-core parts.
- Joel Bachmann
- , Philip Obst
- & Olaf Hinrichsen
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Article
| Open AccessThe moment of initial crystallization captured on functionalized nanoparticles
Understanding the mechanism of supercooling suppression by crystallization seeds is important for designing semiclathrate hydrates for latent heat storage materials. Here, we show that 10-30 nm cluster formation around silver nanoparticles promotes crystallization of supercooled aqueous solutions.
- Hironobu Machida
- , Takeshi Sugahara
- & Izumi Hirasawa
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Article
| Open AccessShaping and silane coating of a diamine-grafted metal-organic framework for improved CO2 capture
Metal organic frameworks (MOFs) are promising for CO2 capture. Here, the Mg2(dobpdc) MOF is synthesized as micron-sized beads with a silane coating resulting in > 11 wt% CO2 absorption, which is retained after three days in a humid environment at 140 °C.
- Jong Hyeak Choe
- , Jeoung Ryul Park
- & Chang Seop Hong
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Article
| Open AccessInstantaneous fibrillation of egg white proteome with ionic liquid and macromolecular crowding
The applicability of protein fibrils as functional biomaterials is limited due to low scalability of production process, slow kinetics, and requirement of expensive purified proteins. Here, instantaneous production of protein fibrils from egg white proteome using cholinium tosylate as a fibrillation agent is shown, with the obtained fibrils displaying enhanced mechanical stiffness and cytocompatibility.
- Pankaj Bharmoria
- , Dibyendu Mondal
- & Mara G. Freire