Article | Open | Published:

All-optical THz wave switching based on CH3NH3PbI3 perovskites

Scientific Reports volume 6, Article number: 37912 (2016) | Download Citation

Abstract

Hybrid structures of silicon with organic–inorganic perovskites are proposed for optically controllable switching of terahertz (THz) waves over a broad spectral range from 0.2 to 2THz. A 532-nm external laser was utilized to generate photoexcited free carriers at the devices and consequentially to control the terahertz amplitude modulation, obtaining a depth of up to 68% at a laser irradiance of 1.5 W/cm2. In addition, we compared the performances from three types of perovskite devices fabricated via different solution processing methods and suggested a stable and highly efficient THz switch based on a one-step processing. By this we demonstrated the possibility of perovskites as THz wave switching devices in addition to photovoltaics.

Introduction

Although over a couple of decades, tremendous progress in terahertz (THz) wave generators and detectors has been achieved, the realization of THz wave control devices is remained as a facing subject because studies of THz wave modulators and switches are still lagging behind. One approach for the development of THz wave switches has been based on the study of carrier-induced change in dielectric properties at simple structures of semiconductors1,2,3,4, and at hybrid structures of semiconductors with graphene5,6,7,8, metamaterials9,10,11,12, and organic–inorganic materials13,14,15. Zhang et al. have demonstrated optically controlled THz amplitude modulators with modulation depths (MD) of up to nearly 100% using a polymer and an organic film as deposited materials on a Si substrate with external laser pumping at a wavelength of 400 nm16,17,18.

Recent discoveries of photovoltaics in methylammonium lead halide perovskites (MAPbX3, where X = I, Cl, and Br) have significantly contributed to next-generation solar cells. Owing to their long electron–hole diffusion length (~100 nm for CH3HN3PbI3 and >1,000 nm for CH3NH3PbI3−xClx)19, low cost, and ease of fabrication with solution processing, perovskite-based solar cells have exhibited power conversion efficiencies of up to 20.5% experimentally20 and 31% theoretically21.

Moreover, there is additional scope for implementation of perovskite technology at THz frequencies, being of particular significance for THz switching. One recent report has shown an optically controlled THz amplitude modulator based on the hybrid structure of Si with a perovskite film fabricated via two-step solution processing22. However, the instability of perovskites under ambient conditions has remained problematic in practical applications23. Kang et al. have recently reported a comparative investigation of CH3NH3PbI3 perovskites according to their fabrication methods and identified that more suitable devices for practical uses are based on one-step solution processing owing to the narrow distribution of the device efficiency and the stability under ambient conditions24,25. In the present report, we conducted a quantitative study of perovskite-based THz switches. Hybrid structures of Si with perovskites (perovskite/Si) fabricated through three different processing methods were compared in terms of the MD, carrier density, conductivity, and mobility. Finally, we demonstrated a stable and highly efficient perovskite THz switch can be fabricated by a one-step processing method.

Results and Discussion

In the present experiment, we utilized a typical THz time-domain spectroscopy (THz-TDS) system with a spectral range from 0.2 to 2 THz based on a regenerative amplified femtosecond pulse laser system (Hurricane, Spectra-Physics). To modulate the THz wave transmission, an external continuous wave (cw) laser with a wavelength of 532 nm was used to illuminate a THz switching device at an oblique angle of 45° with a larger beam size than a THz spot, as shown in Fig. 1. We took note that the measurement of the THz modulation with hybrid perovskite/Si devices at the wavelength of 532 nm has never been reported even with the fact that green light is the most abundant spectral component in sunlight. So, in contrast to previous research on perovskite-based modulators with weak THz pulse and 400-nm optical pump22, we chose 532 nm of wavelength as optical pump and modulated intense THz pulse, which will be the realistic tool to characterize perovskite materials as solar devices.

Figure 1: Schematic diagram of optically controllable THz modulation of perovskite/Si.
Figure 1

The THz pulse was generated using a 1-mm-thick ZnTe crystal and was guided through two off-axis parabolic mirrors (each with a focal length of 100 mm) and two polymethylpentene (TPX) lenses (each with a focal length of 50 mm). The 532-nm cw laser illuminated the surface at an obilique angle of 45° with a spot size ~2 mm larger than a 1-mm THz spot.

Three types of CH3NH3PbI3 perovskites for THz wave switching were fabricated based on different representative solution-processing methods. The three processing methods were (1) CHP: one-step processing method with an additive, N-Cyclohexyl-2-pyrrolidone to the precursor solution, (2) CBdrp: one-step processing method by quickly dropping chlorobenzene on the spinning wet MAPbI3 films, and (3) IFF: two-step processing method with spin-coating by two precursor solutions, as explained in detail at ref. 25. Scanning electron microscope images of the perovskite surfaces were obtained with different morphologies (Fig. 2(a–c)), giving different modulation properties, which will be discussed later in this report.

Figure 2: Features and electical properties of perovskite devices.
Figure 2

Scanning microscope images of perovskite surfaces based on (a) CHP, (b) CBdrp, and (c) IFF fabrication methods, and (d) the corresponding external quantum efficiency.

Furthermore, external quantum efficiencies (EQEs) for three types of perovskites were obtained over a range from 300 to 800 nm as shown in Fig. 2(d). By the fact that the THz modulation is mainly affected by the number of generated free carriers16 equivalent to an EQE of a device, we estimated the relative MDs among three perovskite/Si devices with EQEs at a given 532-nm pump. The CHP- and IFF-based perovskites which show comparable EQEs of approximately 70% are expected to exhibit higher THz modulation than CBdrp-based perovskite with the EQE of 55%. Meanwhile, both CHP and CBdrp, one-step processing, are more stable under ambient conditions than IFF as mentioned above25, which therefore anticipates that CHP-based perovskite/Si device is the best candidate for THz switching at a 532-nm pumping owing to its good stability and high MD.

Several types of hybrid Si structures have exhibited higher and faster THz wave modulation compared to bare Si at low laser irradiance14,17,18, because energy band bending, which causes the drift of excited photocarriers towards the interface, occurs at the interface between Si and deposited materials. The conductivity at each region (Si, deposited materials, and the interface) naturally varies so that the photocarriers accumulate at the interface that gives a higher carrier density and an increase in THz wave absorption via electron–hole scattering, electron–phonon scattering, and electron–impurity scattering, which finally enhances the THz amplitude modulation than from both bare Si and the deposited material itself16. In this experiment, we used three types of CH3NH3PbI3 perovskites deposited onto a 500-μm-thick, high-resistivity (>1000 Ω cm), and undoped Si wafer. The conduction band edges from the vacuum state were −4.07, −4.08, −3.88, and −3.1 eV at CHP-, CBdrp-, and IFF-based perovskites and Si, respectively25. This mismatch of the band alignment between Si and each perovskite creates band-bending structures at the interface and causes the drift of the excited photocarriers14. The photocarrier mobility of perovskite (on the order of 10)26 is a factor of ~100 less than that of Si (on the order of 103)27, causing an accumulation of photocarriers at the interface and, subsequently, an increase in the THz modulation. In addition, this photo-doping effect by the external laser pump is enhanced at higher irradiance, causing the corresponding higher THz modulation.

Figure 3(a) and (b) show the amplitude modulation of the waveform and spectrum in THz transmission under various laser irradiances for CHP-based perovskite/Si. THz transmission decreased as the laser irradiance increased. CBdrp- and IFF-based perovskite/Si and bare Si followed the CHP-perovskite/Si in the THz modulation with different levels. For quantitative analysis, we introduced the MD defined as the change in the integrated THz transmission spectrum as

Figure 3: Optically controlled THz modulation results.
Figure 3

The modulated (a) waveform and (b) spectrum of the CHP device and (c) the modulation depth at each device under various laser irradiances.

where Son(ω) and Soff(ω) are the THz transmission spectra with and without the optical laser pumping, respectively. As expected, THz modulation for perovskite/Si devices was further enhanced comparing with bare Si, as shown in Fig. 3(c). The MDs for the three perovskite/Si devices were increased linearly at low irradiation and then saturated as the irradiation was increased (~0.5 W/cm2), whereas, for bare Si, the low linear growth of MD was observed within the experimental range (up to 2 W/cm2). We obtained an MD of up to 68% for both CHP- and IFF-based perovskite/Si devices at a laser irradiance of 1.5 W/cm2, although we used a 532 nm as an optical pump source relatively far from the peak absorption band near 400 nm in Si. The absorption coefficient of 7850 cm−1 in Si at 532 nm is a factor of ~4 smaller than the coefficient of 25500 cm−1 at 450 nm28, which indicates that the number of excited carriers involved in the THz modulation at 532 nm was highly decreased when compared to at 450 nm. Nevertheless, we observed the clear enhancement of THz modulation at perovskite/Si devices.

To investigate the modulation mechanism in detail, we deduced the optical constants of the perovskite/Si devices via THz-TDS under various laser irradiances. The complex dielectric constant was obtained by comparing the THz transmission at the perovskite/Si devices to bare Si. We extracted the refractive index and the absorption coefficient from the time-frequency spectrogram based on the Gabor wavelet transform (Gabor WT)29 to calculate the complex dielectric constant, εcomplex = ε1+ iε2, as shown in Fig. 4(a). The real and imaginary parts of dielectric constant were 10.86 and 0.10 at 0.75 THz, respectively, which are higher than those of 9.9 and 0.01 reported by Li et al.30. This can be explained by the fact that the photo-doping on Si by external laser pump in our experiment changed the dielectric property31.

Figure 4: Freqeuncy-dependent complex constants extracted by THz-TDS based on the Gabor WT and the Drude model.
Figure 4

(a) Complex dielectric constants of bare Si and the corresponding complex conductivities of (b) CHP, (c) CBdrp, and (d) IFF devices under various irradiances.

Complex photoconductivity was extracted based on a simple Drude model as

with

where εcore, equal to εcomplex(∞), is the core dielectric constant, Nc is the photocarrier density, e is the electron charge, m is the effective carrier mass, τ = 1/γ is the averaging collision time, and γ is the damping rate. The corresponding frequency-dependent photoconductivities for three perovskite/Si devices under various laser irradiances are shown in Fig. 4(b–d), being consistent with the previous reports on the conductivities of doped Si31,32.

The electric constants were deduced from the Drude fit. By the photo-doping effect, the both carrier density (Nc) and dc conductivity (σdc) increased as the irradiance increased, as shown in Fig. 5(a) and (b), respectively. As we can expect from the EQEs in Fig. 2(d), CHP- and IFF-based perovskite/Si devices showed almost the same carrier density which is higher than that of CBdrp. Figure 5(b) shows dc conductivities for three perovskite/Si have different behavior to the irradiance, which is because the difference in morphology occurred during the fabrication, where crystal orientation, growth, and corresponding electronic properties differ25. This result implicates that the IFF-based perovskite/Si device with the highest σdc gives the highest enhancement in MD under an external electric bias18. In addition, we obtained the increase in MD with higher carrier density accordingly as expected (Fig. 5(c)). Figure 5(d) shows the change of mobility as a function of carrier density. At low carrier density regime (<1015/cm3), the photocarrier mobility showed a steep decline and, at high density regime, it asymptotically approached to the value of <1000 cm2/Vs, which was consistent with the mobility for Si given by Exter et al.27 and Nashima et al.33.

Figure 5: Frequency-independent electrical constants of perovsktie/Si devices.
Figure 5

(a) Carrier density and (b) dc conductivity under various irradiances. (c) MD and (d) mobility according to the carrier density.

Conclusion

We investigated the optically controllable THz switching properties for hybrid structures of Si with three organic–inorganic perovskites fabricated through the different solution-processing methods: CHP, CBdrp, and IFF. As we expected on high MDs of CHP-and IFF-based perovskite/Si devices from the EQE values, a maximum 68% of amplitude modulation was obtained for the both devices at an external 532-nm laser irradiance of 1.5 W/cm2, where the extracted maximum photocarrier density was 3.8 × 1015 cm−3 via THz-TDS and the Gabor WT. From this comparative study, the CHP-based perovskite/Si device fabricated with one-step processing showed good performance in its modulation efficiency and stability, which may assure that this device can be a good candidate for a practical THz switch.

Methods

Terahertz time-domain spectroscopy

The THz-TDS system utilized a regenerated amplified Ti:sapphire laser system (Hurricane, Spectra-Physics) with a time duration of 190 fs, a wavelength of 800 nm, and a repetition rate of 1 kHz. A typical THz-TDS setup was utilized with two ZnTe crystals for a THz source and electro-optic detection, providing a spectral range of 0.2–2 THz. Through time-frequency spectrograms based on the Gabor WT, we obtained the temporal delay on each frequency and the relative spectrum ratio by comparing the reference (from bare Si without optical laser pumping) and sample signal (from perovskite/Si with the pumping). The Gabor WT analysis increase an accuracy in calculation than from the Fourier transformation (FT), because the temporal delay in each spectral component was directly extracted to obtain a refractive index at the corresponding frequency instead of using the relative spectral phase shift that are typically used in FT which is sensitive to experimental conditions and gives an experimental error.

Sample fabrication

Hybrid structures of Si with CH3NH3PbI3 perovskite were fabricated via three different solution-processing methods. Si substrates were rinsed with acetone, DI water and isopropyl alcohol, followed by UV-O3 treated for 20 min, and then CH3NH3PbI3 films were fabricated according to the procedure in the previous report25.

Additional Information

How to cite this article: Lee, K.-S. et al. All-optical THz wave switching based on CH3NH3PbI3 perovskites. Sci. Rep. 6, 37912; doi: 10.1038/srep37912 (2016).

Publisher's note: Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

References

  1. 1.

    , & Subnanosecond optical switching of far infrared radition. Opt. Commun. 47, 340–342 (1983).

  2. 2.

    & Amplitude-, phase-, and frequency modulation of far-infrared radiation by optical excitation of silicon. Infrared Phys. 32, 1–11 (1991).

  3. 3.

    , , , & High-speed switching of far-infrared radiation by photoionization in a semiconductor. Appl. Opt. 31, 329–337 (1992).

  4. 4.

    , & Moduation of submillimeter wave radiation by laser-produced free carriers in semiconductors. Electron. Comm. Jpn. 2 80, 6 (1997).

  5. 5.

    et al. Spectrally wide-band terahertz wave modulator based on ptically tuned graphene. ACS Nano 6, 9118–9124 (2012).

  6. 6.

    et al. Switching terahertz waves with gate-controlled active graphene metamaterials. Nat. Mater. 11, 936–941 (2012).

  7. 7.

    et al. Graphene based all-optical spatial terahertz modulator. Sci. Rep. 4, 7409 (2014).

  8. 8.

    et al. Active graphene-silicon hybrid diode for terahertz waves. Nat. Commun. 6, 7082 (2015).

  9. 9.

    et al. Active terahertz metamaterial devices. Nature 444, 597–600 (2006).

  10. 10.

    et al. Experimental demonstration of frequency-agile terahertz metamaterials. Nat. Photonics 2, 295–298 (2008).

  11. 11.

    et al. Broadband blueshift tunable metamaterials and dual-band switches. Phys. Rev. B 79, 161102(R) (2009).

  12. 12.

    , , , & Dynamical electric and magnetic metamaterial response at terahertz frequencies. Phys. Rev. Lett. 96, 107401 (2006).

  13. 13.

    et al. Organic conjugated material-based broadband terahertz wave modulators. Appl. Phys. Lett. 99, 061108 (2011).

  14. 14.

    , , & Mechanism of optical terahertz-transmission modulation in an organic/inorganic semiconductor interface and tis application to active metamaterials. Opt. Lett. 38, 4632–4635 (2013).

  15. 15.

    , , , & Terahertz modulation on angle-dependent photoexcitation in organic-inorganic hybrid structures. Appl. Phys. Lett. 103, 151116 (2013).

  16. 16.

    et al. Conjugated polymer-based broadband terahertz wave modulator, Opt. Lett. 39, 6110–6113 (2014).

  17. 17.

    et al. High-efficiency THz modulator based on phthalocyanine-compound organic films. Appl. Phys. Lett. 106, 053303 (2015).

  18. 18.

    et al. Conjugated polymer based active electric-controlled terahertz device. Appl. Phys. Lett. 108, 103301 (2016).

  19. 19.

    et al. Electron-hole diffusion lengths exceeding 1 micrometer in an organometal trihalide perovskite absorber. Science 342, 341–344 (2013).

  20. 20.

    et al. A vacuum flash-assisted solution process for high-efficiency large-area perovskite solar cells. Science 353, 58–62 (2016).

  21. 21.

    , , & The efficiency limit of CH3NH3Pbl3 perovskite solar cells. Appl. Phys. Lett. 106, 221104 (2015).

  22. 22.

    et al. Active terahertz device based on optically controlled organometal halide perovskite. Appl. Phys. Lett. 107, 093301 (2015).

  23. 23.

    , & Review of recent progress in chemical stability of perovskite solar cells. J. Mater. Chem. A 3, 8970–8980 (2015).

  24. 24.

    et al. Optimized organometal halide perovskite planar hybrid solar cells via control of solvent evaporation rate. J. Phys. Chem. C 118, 26513–26520 (2014).

  25. 25.

    et al. Exploration of fabrication methods for planar CH3NH3PbI3 perovskite solar cells. Nano Energy 27, 175–184 (2016).

  26. 26.

    , , , & High charge carrier mobilities and lifetimes in organolead trihalide perovskites, Adv. Mater. 26, 1584–1589 (2014).

  27. 27.

    & Carrier dynamics of electrons and holes in moderately doped silicon. Phys. Rev. B 41, 12140–12149 (1990).

  28. 28.

    & Optical properties of intrinsic silicon at 300K. Prog. Photovoltaics 3, 189–192 (1995).

  29. 29.

    & A Denoising Method for Detecting Reflected Waves from Buried Objects by Ground-Penetrating Radar. Electron. Commun. Jpn. 96, 631–641 (2013).

  30. 30.

    & Dielectric properties of silicon in terahertz wave region. Microw. Opt. Technol. Lett. 50, 1143–1146 (2008).

  31. 31.

    & Nature of conduction in doped silicon. Phys. Rev. Lett. 78, 1106–1109 (1997).

  32. 32.

    , , & Measurement of optical properties of highly doped silicon by terahertz time domain reflection spectroscopy. Appl. Phys. Lett. 79, 3923–3925 (2001).

  33. 33.

    , , & Temperature dependence of optical and electronic properties of moderately doped silicon at terahertz frequencies. J. Appl. Phys. 90, 837–842 (2001).

Download references

Acknowledgements

This research was supported by the National Research Foundation of Korea (NRF) grants funded by the Korean government (MSIP) (Grant Nos NRF-2015M2A2A4A03044653 and NRF-2015R1A5A1009962), and was further supported by the “TBP program” and the “Ultrashort Quantum Beam Facility Program” through grants provided by Gwangju Institute of Science and Technology in 2016.

Author information

Affiliations

  1. Department of Physics and Photon Science, Gwangju Institute of Science and Technology (GIST), Gwangju 61005, Republic of Korea

    • Kyu-Sup Lee
    • , Byungwoo Son
    •  & Do-Kyeong Ko
  2. Radiation Research Division for Industry and Environment, Korea Atomic Energy Research Institute, Jeongup, Jeollabuk-do 56212, Republic of Korea

    • Rira Kang
  3. School of Materials Science and Engineering, Heeger Center for Advanced Materials, GIST, Gwangju 61005, Republic of Korea

    • Dong-Yu Kim
  4. Advanced Photonics Research Institute, GIST, Gwangju 61005, Republic of Korea

    • Nan Ei Yu

Authors

  1. Search for Kyu-Sup Lee in:

  2. Search for Rira Kang in:

  3. Search for Byungwoo Son in:

  4. Search for Dong-Yu Kim in:

  5. Search for Nan Ei Yu in:

  6. Search for Do-Kyeong Ko in:

Contributions

This work was conceived by K.-S.L. and mainly supervised by D.-K.K. R.K. fabricated the device with the supervision form D.-Y.K. K.-S.L. carried out the experiment and analysis with the contribution form B.S. N.E.Y. also supervised the demonstration of THz-TDS system. All authors discussed the results and commented on the manuscript.

Competing interests

The authors declare no competing financial interests.

Corresponding author

Correspondence to Do-Kyeong Ko.

About this article

Publication history

Received

Accepted

Published

DOI

https://doi.org/10.1038/srep37912

Comments

By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.