Robust Room-Temperature Quantum Spin Hall Effect in Methyl-functionalized InBi honeycomb film

Abstract

Two-dimensional (2D) group-III-V honeycomb films have attracted significant interest for their potential application in fields of quantum computing and nanoelectronics. Searching for 2D III-V films with high structural stability and large-gap are crucial for the realizations of dissipationless transport edge states using quantum spin Hall (QSH) effect. Based on first-principles calculations, we predict that the methyl-functionalized InBi monolayer (InBiCH3) has no dynamic instability and hosts QSH state with a band gap as large as 0.29 eV, exhibiting an interesting electronic behavior viable for room-temperature applications. The topological characteristic is confirmed by s-pxy band inversion, topological invariant Z2 number and the time-reversal symmetry protected helical edge states. Noticeably, the QSH states are tunable and robust against the mechanical strain, electric field and different levels of methyl coverages. We also find that InBiCH3 supported on h-BN substrate maintains a nontrivial QSH state, which harbors the edge states lying within the band gap of substrate. These findings demonstrate that the methyl-functionalized III-V films may be a good QSH platform for device design and fabrication in spintronics.

Introduction

Two-dimensional (2D) topological insulators (TIs), known as quantum spin Hall (QSH) insulators, have attracted significant researches interest in condensed matter physics and materials science 1,2,3. The unique characteristic of 2D TI is generating 1D helical edge states inside the bulk-gap, where the states moving in opposite direction have opposite spin. Therefore, the backscattering is prohibited as long as the scattering potential does not break time-reversal symmetry (TRS) and such helical edge states provide a new mechanism to realize non-dissipative electronic transportation, which promises potential application in low-power and multi-functional device1,2. This opens a new avenue in the quest for searching and designing TIs in 2D systems. From this point of view, a 2D TI with a large gap, chemically stable under ambient condition exposure to air and easy to prepare experimentally, is highly desired4,5. The prototypical concept of QSH insulator is first proposed by Kane and Mele in graphene6,7, in which the spin-orbital coupling (SOC) opens a band gap at the Dirac point. However, due to the rather weak SOC, the associated gap is extremely small (~10–3 meV)8, which makes the QSH effect can only be observed at an unrealistically low temperature. Fortunately, this unobservable bulk band gap has predicted to be enhanced by constructing van der Waals heterostructures with graphene and other 2D materials which possess strong SOC effect, such as Bi2Se39, WS210 and chalcogenides BiTeX (X = Cl, Br and I)11. Quantized conductance through QSH edge states have been experimentally demonstrated in HgTe/CdTe12,13 and InAs/GaSb14,15 quantum wells, demonstrating an interesting in further experimental studies and possible applications.

Currently, searching for new QSH insulators with controllable quantum phase transitions and tunable electronic and spin properties is crucial for promoting TI technology. After the discovery of QSH phase in graphene, silicene, germancene and stanene are authenticated as QSH insulator sequentially16, in which the band gap in stanene reaches 0.1eV due to its stronger SOC16,17. Then the research focus extends to Group-V bilayer films and the results prove that Bi (111)18 bilayer is a QSH insulator intrinsically. Recently, the investigation emphasis is transferred to the 2D inversion-asymmetric materials which contain two different elements, such as Group III-V binary compounds19,20,21. According to prediction, suitable bulk band gap and isolated Dirac cone in these 2D III-V compounds make them suitable for room-temperature applications. A computational study22 has suggested the possible synthesis and potential applications for 2D III-V compounds. Moreover, due to the inversion-asymmetry in III-V films, they may host nontivial topological phenomena, such as crystalline-surface-dependent topological electronic states23,24, natural topological p-n junctions25 and topological magnetoelectric effects26. Nevertheless, the surface activity is a major problem for these materials, whose topology may be destroyed by substrate. Besides, some 2D transition-metal dichalcogenides27 and halide28 are predicted to be a new class of QSH insulator with a large band gaps.

Recent studies have highlighted that the orbital filtering effect (OFE) plays an important role on tuning the bulk band gap, which has received intense attentions in designing of QSH insulators16,17,29,30,31,32. The 2D films are advantageous in this aspect since their bonding properties are easy to be modified in the processes of synthesis to enhance SOC by surface adsorption. For instance, the band gap of stanene will be enhanced to 0.3 eV with the effect of halogenation17 and the SOC is confined in the pxy orbitals rather than pz in pristine one. The X-decorated plumbene monolayers (PbX; X = H, F, Cl, Br, I) is predicted as a 2D QSH insulator with giant bulk gaps from 1.03 eV to a record value of 1.34 eV33. Recently, it is reported that the functionalized dumbbell stanene also obtains large-gap QSH state34. The 2D BiX/SbX (X = H, F, Cl and Br) films are demonstrated as TIs with extraordinarily large band gap from 0.32 eV to 1.08 eV29. Also, the Bi and Sb films have been demonstrated to contain a large band gap using Si substrate as a tool to achieve OFE30,31. Recently, OFE is also applicable in materials with inversion-asymmetric sublattices. The Group IV non-centrosymmetric honeycomb lattices functionalized with halogen atoms are theoretically confirmed to be topological insulators with appropriate condition35. Meanwhile, for the functionalized III-Bi films, they can preferably realize nontrivial topological states, producing remarkable large Rashba spin splitting effect21,32. By the way, through the combination of Si (111) substrate and hydrogenation, it can still implement OFE in III-V compounds films36. These QSH insulators are essential for realizing many exotic phenomena and for fabricating new quantum devices that operates at room temperature. Unfortunately, though their band gap has been enhanced greatly, further experimental works37 find that the fluorination and hydrogenation exhibit quick kinetics, with rapid increasing of defects and lattice disorder even under short plasma exposures, which will disturb their potential applications completely. Therefore, the realization of these QSH insulators with high quality is rather difficult38,39,40.

Recently, the small molecule functionalization has been the focus to enhance the geometric stability and nontrivial band gap of new 2D films. For instance, the ethynyl (C2H) has been reported to be an efficient way to stabilize stanene by decoration on its surface and its band gap can be enhanced to 0.3 eV41. Methyl (CH3), another organic molecule, has also been suggested as a promising tool to stabilize 2D systems, such as methyl-functionalized germanane (GeCH3)42 and BiCH343, to realize large gap QSH insulators. Experimentally, GeCH3 film has been synthesized in recent work44. In contrast to hydrogenated germanane, the GeCH3 film has considerably enhanced thermal stability at high-temperature44. This raises an interesting question: can the methyl be applied to stabilize group III-V films and whether their band gap can be enhanced significantly in QSH phase?

In this work, we address the aforementioned question by demonstrating the effect of methyl-functionalization as an effective way to stabilize InBi monolayer (InBiCH3) as a representative for group III-V films. Indeed, the methyl removes the imaginary frequency modes from the phonon spectrum of InBi, indicating no dynamic instability. In this case, the band gap of InBiCH3 can be enhanced to 0.29 eV, which is larger than that of pristine InBi monolayer. The physical origin of QSH effect is confirmed by identifying the s-pxy band inversion, topological invariant Z2 = 1 and helical edge states in bulk band gap. Noticeably, the QSH effects are robust and tunable against the mechanical strain, electric field and different level of methyl coverages. In addition, the InBiCH3 on h-BN sheet is observed to support a nontrivial large gap QSH, which harbors the edge states lying within the band gap of h-BN sheet. Therefore, our work reveals a unique advantage of atomically thin III-V materials in realizing 2D topological phase.

Calculation Details

First-principles calculations based on density functional theory (DFT) were carried out using the plane wave basis Vienna ab initio simulation package45,46. The electron-ion potential was described by the projector-augmented wave (PAW) method47 and the electron exchange-correlation functional was approximated by generalized gradient approximation (GGA) in Perdew-Burke-Ernzerhof (PBE) form48. The energy cutoff of the plane waves was set to 500 eV with the energy precision of 10−5 eV. The vacuum space was applied at least 20 Å to eliminate the interactions between neighboring slabs in z-direction. We employed a k-point set generated by the 11 × 11 × 1 Monkhorst-Pack mesh49 for geometry optimizations and 17 × 17 × 1 for self-consistent calculations. The atomic coordinates were fully optimized until the force on each atom was less than 0.01 eV/Å. The SOC is included in self-consistent electronic structure calculations. The phonon spectra were calculated using a supercell approach within the PHONON code50.

Results and Discussion

Before discussing the electronic properties of the methyl-functionalized InBi, we examine the crystal structure, dynamic stability and electronic properties of the pristine InBi monolayer. Figure 1(a) presents the geometric structure of InBi, composed of a triangular lattice with In and Bi atoms located in two different sublattices. Our calculations indicate that, in analogy to buckled silicene51, InBi exhibits a hexagonal structure with a buckling parameter Δ = 0.873 Å, lattice constant a = 4.78 Å and bond length d = 2.89 Å, which consist with those reported in previous literature20,36, but are smaller than the cases in two films of InBi52 except Δ. The resultant band structure indicates that it is a QSH insulator, with a band gap of 0.16 eV. Such an upper limit, however, can be significantly broken through, as we will show in the following part. In addition, the phonon spectrum calculations in Fig. 1(c) indicate that it has obviously imaginary frequency modes, exhibiting a dynamically unstable structure.

Figure 1
figure1

Structural representation (top view and side view) of (a) InBi and (b) InBiCH3. (c,d) Corresponding phonon spectra along the high-symmetric points in the BZ.

To stabilize InBi monolayer, we saturate the uncoordinated In and Bi atoms with methyl alternating on both sides of InBi sheet, as shown in Fig. 1(b). In comparison with InBi monolayer, the lattice constant of InBiCH3 is stretched to a = 4.89 Å upon methyl-functionalization, along with the Ga−Bi bond length increasing by 0.08 Å. Noticing that this lattice constant is larger than hydrogenated case36, which will enhance the localization of atom orbitals, the methyl-functionalized InBi film may process a more favorable character than the hydrogenated one. Meanwhile, the In−CH3 and Bi−CH3 bonds are 2.23 and 2.30 Å, respectively. Importantly, the stability of 2D InBiCH3 is confirmed by phonon spectrum that clearly removes the imaginary frequencies from pristine InBi monolayer, as displayed in Fig. 1(d). Also, we calculate the formation energy of InBiCH3 defined as:

where E(InBiCH3) and E(InBi) are total energies of InBiCH3 and InBi, respectively, while E(CH3) is chemical potential of methyl. It is found to be Ef = −3.23 eV, greatly lager than the cases of GaBiCl253 and GeCH3 (−1.75 eV). These indicate that the methyl strongly binds to InBi monolayer by chemical bonds, showing a higher thermodynamic stability relative to their elemental reservoirs. Considering that the GeCH3 has been successfully synthesized44, InBiCH3 is also expected to be feasible experimentally.

Figure 2 displays the calculated band structures in InBiCH3 monolayer. In the absence of SOC, it is a semiconductor with a direct band gap of 0.21 eV at the Г point, as shown in Fig. 2(a,b). When SOC is switched on, there still has a direct band gap (EГ) of 0.31 eV at the Г point, which is twice larger than that of pristine one. However, the valence band minimum (VBM) moves slightly away from the Г point, leading to an indirect band gap (Eg) of 0.29 eV [Fig. 2(c,d)], which is significantly larger than the InBi film with hydrogenation(0.19 eV)36, verifying the assumption proposed above. The SOC-induced band structure deformation near the Fermi level is a strong indication of the existence of topologically nontrivial phase. To further reveal the effect of chemical decoration of methyl, we project the bands onto different atomic orbitals. The energetically degenerated VBM without SOC are mainly derived from pxy orbitals, whereas the conduction band minimum (CBM) is contributed by s orbital [Fig. 2(a)]. It is known that the s orbital locates typically above p orbitals in conventional III-V compounds. Consequently, the InBiCH3 exhibits a normal band order. However, the effect of SOC makes s and pxy components at the Γ point exchanged, resulting in an inverted band order, as shown in Fig. 2(c). Here, there is a nontrivial bulk band gap of 0.29 eV at the Fermi level, considerably exceeding the presumed upper limits settled by the system without decoration. Here, we highlight that the QSH states of InBiCH3 are markedly different from hydrogen- or methyl-functionalized stanene17 and germanene42, which are trivial TIs at the equilibrium state. In addition, due to the inversion-symmetry breaking in InBiCH3, we also find that the resulting band structure is different from stanene film16 and shows intriguing Rashba-type dispersions, as shown in Fig. 2(c,d). This spin splitting is also similar to what occurs for the hydrogenated InBi monolayer20.

Figure 2
figure2

Orbital resolved band structures of InBiCH3 without (a) and with SOC (c). (b) and (d) are the corresponding enlarged views of the bands near the Fermi level at the Г point. The orange and the light blue dots represent the s and pxy orbitals, respectively.

The most important performance for TIs is the existence of helical edge states with spin polarization protected by TRS, which can be calculated by the Wannier 90 package50. Based on maximally localized Wannier functions (MLWFs), the edge Green’s function54 of the semi-infinite lattice is constructed using the recursive method and the local density of state (LDOS) of the edges is presented in Fig. 3(a). We can see that all the edge bands connect completely the conduction and valence bands and span the 2D bulk band gap, yielding a 1D gapless edge states. Further, by identifying the spin-up (↑) and spin-down (↓) contributions in the edge spectral function [Fig. 3(b)], the counter-propagating edge states can exhibit opposite spin-polarization, in accordance with the spin-momentum locking of 1D helical electrons. Furthermore, the Dirac point located at the band gap are calculated to have a high Fermi velocity of ~2.0 × 106 m/s, comparable to that of 5.3  ×  105 m/s in HgTe/CdTe quantum well12,13. All these results consistently demonstrate that the InBiCH3 is an ideal 2D TI.

Figure 3
figure3

The calculated semi-infinite edge states of total (a) and spin (b) for InBiCH3. The red and green components in (b) denote the spin up and spin down polarization. The Fermi level is set to zero. (c) Evolutions of Wannier centers along ky. The evolution lines cross the arbitrary reference line (red dash line) parallel to ky odd times, yielding Z2 = 1.

The topological states can be further confirmed by calculating topological invariant Z2. Due to the inversion-symmetry breaking in InBiCH3, the method proposed by Fu and Kane55 cannot be used and thus, an alternative one independent of the presence of inversion-symmetry is needed. Here, we introduce the evolution of Wannier Center of Charges (WCCs)56 to calculate the Z2 invariant, which can be expressed as:

which indicates the change of time-reversal polarization (Pθ) between the 0 and T/2. Then the WFs related with lattice vector R can be written as:

Here, a WCC can be defined as the mean value of , where the is the position operator and is the state corresponding to a WF in the cell with R = 0. Then we can obtain

Assuming that with S = I or II, where summation in α represents the occupied states and A is the Berry connection. So we have the format of Z2 invariant:

The Z2 invariant can be obtained by counting the even or odd number of crossings of any arbitrary horizontal reference line.

Figure 3(c) displays the evolution lines of WCCs calculated for InBiCH3. One can see that the WCCs evolution curves cross any arbitrary reference lines odd times, which indicates Z2 = 1, verifying the existence of topologically nontrivial phase in InBiCH3.

Strain engineering is an efficient way of modulating the electronic and topological properties in 2D materials57,58. We employ in-plane strains to InBiCH3 by changing the lattices as ε = (a − a0)/a0, where a (a0) is lattice constant under the strain (equilibrium) condition. Figure 4(a) presents the variation of band gap (Eg, EГ) as a function of the biaxial strain. One can see that the nontrivial QSH phase survives in InBiCH3 over a wide range of strains. Under tensile strain, the EΓ enlarges monotonically and reaches a maximum of 0.79 eV at 20%. While in the compressive case, the Eg and EГ are almost consistent with each other and the s-pxy inversion maintains beyond critical point −7%. If the compressive strain keeps increasing, the trivial band order occurs, forming a normal insulator (NI). The characteristics of band inversion with respect to the strain are illustrated in the insert of Fig. 4(a). Here, we must point out that the crystal deformation occurs clearly with relatively large strains, suggesting a robustness of QSH effect against crystal deformation.

Figure 4
figure4

Variation of global gap (Eg) and the direct band gap (EГ) as a function of external strain (a) and electric field (b) for InBiCH3. The inserts are the diagram of evolution for atomic orbitals with strain. The evolution of atomic s and pxy orbitals at Г point is described as chemical bonding and SOC are switched on in sequence for ε < −7% (c) and ε > −7% (d). The horizontal black dashed lines indicate the Fermi level.

To elucidate the origin of band topology, we analyze the orbital evolution of InBiCH3 and the results are schematically presented in Fig. 4. Since the methyl hybridizes strongly with pz orbital of In and Bi atoms overlapping in the same energy range, it effectively removes pz bands away from the Fermi level, leaving only the s and px,y orbitals at the Fermi level. As shown in Fig. 4(c,d), the chemical bonding between In and Bi atoms make the s and px,y orbital split into the bonding and anti-bonding states, i.e., |s±> and |p±x,y>, which the superscripts + and − represent the parities of corresponding states, respectively. In the absence of SOC, the bands near the Fermi level are mainly contributed by the |s> and |px,y+>, with the |s> locating above |px,y+>, possessing a normal band order in the sequence of s-p. After taking SOC into account, the |px,y+> will further split into |p ± 3/2+> and |p ± 1/2+>, while the |p ± 3/2+> is pushed up and |p ± 1/2+> is shifted down in energy. The hopping between those atomic orbitals plays a vital role in tuning the splitting strength of |p ± 3/2+> and |p ± 1/2+>. In the case of ε < −7%, the compressive strain leads to a shorter bond length, which increases the splitting degree of bonding and antibonding states, generating a large energy difference between |px,y+> and |s>. Thus, the |p ± 3/2+> cannot inverse with |s>, indicating a trivial band order like conventional III-V compounds, as shown in Fig. 4(c). While for ε > −7%, a smaller energy separation introduced will be arisen and the SOC effect can easily promote the |p ± 3/2+> higher than |s> [Fig. 4(d)], leading to an extraordinary band inversion order in the sequence of p-s-p, namely inversion of parities, indicating the existence of QSH phase. Moreover, to further confirm the nontrivial topological properties, we calculate the edge states when the strain is 105%. The result is presented in Figure S1(a,b) and a pair of helical edge states can be observed obviously, indicating that it still maintains the QSH states except the change of bulk band gap compared with the equilibrium state. It is worth mentioning that this topological states originate from the s-p inversion mechanism, which is common in such III-V compounds rather than p-d or d-d band inversion in transition-metal compounds27,28. But it is still different from the case of InBi film with fluoridation32, in which the |px,y+> and |s> orbitals have inversed in the progress of chemical bonding and the bulk band gap is determined by the splitting of |px,y+> under the SOC effect, the bulk band gap in InBiCH3 film is the combined effect of functionalization and SOC, thus yields a smaller bulk band gap.

In addition to strain engineering, the effects of a perpendicular electric field (E-filed) on band topology are investigated for InBiCH3. We find that both Eg and EГ possess a near-linear dependency with respect to E-field, as illustrated in Fig. 4(b). The increases of the positive E-field leads to a larger band gap, while the negative E-field will make it decrease monotonically. More importantly, different from 1T’-MoS227 whose topological state will be destroyed by electric field, the InBiCH3 maintains its nontrivial TI nature all the way, indicating a robustness against E-field in the range of −1–1V/Å. Meanwhile, as a representative, the edge state of 0.5V/Å is shown in Figure S1(c,d), which is analogous to the case of strain [Figure S1(a,b)]. The nontrivial bulk band gaps are still very large (0.24−0.35 eV), allowing for viable applications at room temperature.

As discussed above, the methyl functionalization does not alter the band topology of InBi monolayer. Thus, we further examine the robustness of nontrivial TI phase by considering different levels of methyl coverages in InBiCH3. A 2 × 2 supercell is selected to simulate coverages of 0.25, 0.50 and 0.75 monolayer by removing/adding up to methyl molecules. Followed the previous work59, the methyl molecules are positioned on opposite sides of InBi sheet, yielding a greater stability. Figure 5 presents the relaxed structures and corresponding band structures for 0.25−0.75 monolayer coverage, respectively. Interestingly, all the methyl molecules are strongly hybridized with pz orbital of In and Bi atoms, thus the atomic states near the Fermi level is still mainly determined by the s and pxy orbitals. Meanwhile, the s-p band inversion can be observed, thus the band topology of these films is highly robust against chemical bonding effects of the environment, making these films particularly flexible to substrate choices for device applications. Besides, we also calculate the phonon spectrums of these different covered monolayers, as shown in Figure S2. According to the results, these structures still possess little imaginary frequency. So the best insurance method is functionalized the InBi film with methyl completely. However, even if it emerges with unsaturated position, it can still own the QSH state, which is a good guarantee. To further verify its robustness against the coverage, taking 0.25 monolayer as a representative, we straightforward construct a ribbon with zigzag edges. The width of this ribbon is 73.53 Å, which is large enough to ignore the effect between two sides. Meanwhile, to eliminate the interaction induced by periodicity, a sufficient vacuum slab is adopted and the edges are passivated by hydrogen atoms. Figure S3(a) presents the corresponding band structure. Different from the results of semi-infinite lattice, two pairs of helical edge states span the bulk energy gap connecting the valence and conduction bands. Due to the asymmetry for edges in zigzag ribbon, a pair of edge bands is determined by the In termination and the other is derived from the Bi termination, also they form two Dirac cones simultaneously at the M point. Noticeably, each pair of edge state crosses the Fermi level with odd number along the direction form M to Γ point which can adequately prove its nontrivial topological properties.

Figure 5
figure5

The structure diagram of InBiCH3 monolayer with coverages of (a) 0.25, (b) 0.50 and (c) 0.75. The corresponding band structures with SOC are located under the structural diagram. The orange and the light blue dots represent the s and pxy orbitals, respectively. The enlarged view of bands near the Fermi level at the Г point are shown in the right panel.

From the view of devices applications, selecting a suitable substrate for InBiCH3 is a very important issue. Considering that one film of InBi with hydrogenation deposited on Si(111) will annihilate its nontrivial topological states52, we hope to achieve it by constructing a van der Waals heterostructure for its growth. However, the h-BN has been reported to be an ideal substrate for 2D materials60,61, due to its large band gap with a high dielectric constant. Thus, we construct an InBiCH3@2 × 2h-BN heterobilayer (HBL), as shown in Fig. 6(a), in which the lattice mismatch is only 0.41% for both layers. After a full relaxation, the distance between adjacent layers is 3.11 Å from the bottom methyl to substrate, with a binding energy of −71 meV, indicating the InBiCH3 interacts weakly with h-BN substrate via van der Waals interaction62. Figure 6(b) presents the band structure of InBiCH3@2 × 2h-BN HBL with SOC. In these weakly coupled system, there is essentially no charge transfer between the adjacent layers and the HBL remains semiconducting property. By projecting the band structure, we find that the contributions of h-BN substrate locate far away from the Fermi level, the states around the Fermi level being dominantly determined by InBiCH3 with an inverted band order. In addition, based on aforesaid method about validation for edge states, we also investigate the band structure of InBiCH3@2 × 2h-BN ribbon. The edge states and odd number of crossing further verify the existence of nontrivial topological property and it is robust against substrate, as illustrated in Figure S3(b). If we compare the bands of InBiCH3 with and without h-BN substrate, little difference can be observed, which is analogous to the case of tetragonal Bi film on NaCl substrate63. As a result, the InBiCH3@2 × 2h-BN HBL is a robust QSH phase with a gap of 0.27 eV.

Figure 6
figure6

Geometry structure for InBiCH3 deposited on BN substrate from top view (a) and side view (b), as well as orbitals-resolved band structures with SOC (c). The purple dots represent the contribution of BN substrate. The orange and the light blue dots represent the s and pxy orbitals, respectively. The insert is the enlarged drawing of the bands near the Fermi level at the Г point.

Conclusions

In summary, on the basis of first-principles calculations, we have investigated the geometric and electronic properties of InBiCH3. The results indicate that InBiCH3 has no dynamic instability and is a QSH insulator with a band gap lager than 0.29 eV, suitable for room-temperature application. The topological characteristic can be confirmed by s-pxy band inversion, topological invariant Z2 = 1 and the time-reversal symmetry protected helical edge states. We also find that the band gap of InBiCH3 can be effectively tuned by external strain and electric field. The TI phase is robust against strain (−7–20%) and E-field (−1–1V/Å). Also, the InBiCH3 can preserve nontrivial topology under different levels of methyl coverages. In addition, the InBiCH3 on h-BN sheet is observed to support a nontrivial large-gap QSH, which harbors a Dirac cone lying within the band gap. These findings demonstrate that the methyl-functionalized III-V films may be a good QSH platform for device design and fabrication.

Additional Information

How to cite this article: Li, S.- et al. Robust Room-Temperature Quantum Spin Hall Effect in Methyl-functionalized InBi honeycomb film. Sci. Rep. 6, 23242; doi: 10.1038/srep23242 (2016).

References

  1. Hasan, M. Z. & Kane, C. L. Colloquium: Topological insulators. Rev. Mod. Phys. 82, 3045–3067 (2010).

    ADS  CAS  Article  Google Scholar 

  2. Qi, X.-L. Topological insulators and superconductors. Rev. Mod. Phys. 83, 1057 (1057).

    ADS  CAS  Article  Google Scholar 

  3. Yan, B. & Zhang, S. C. Topological materials. Rep. Prog. Phys. 75, 096501 (2012).

    ADS  PubMed  Article  CAS  Google Scholar 

  4. Moore, J. E. The birth of topological insulators. Nature 464, 194–198 (2010).

    ADS  CAS  Article  Google Scholar 

  5. Rasche, B. et al. Stacked topological insulator built from bismuth-based graphene sheet analogues. Nat. Mater. 12, 422–425 (2013).

    ADS  CAS  PubMed  Article  Google Scholar 

  6. Kane, C. L. & Mele, E. J. Quantum Spin Hall Effect in Graphene. Phys. Rev. Lett. 95, 226801 (2005).

    ADS  CAS  PubMed  PubMed Central  Article  Google Scholar 

  7. Kane, C. L. & Mele, E. J. Z2Topological Order and the Quantum Spin Hall Effect. Phys. Rev. Lett. 95, 146802 (2005).

    ADS  CAS  Article  Google Scholar 

  8. Yao, Y., Ye, F., Qi, X.-L., Zhang, S.-C. & Fang, Z. Spin-orbit gap of graphene: First-principles calculations. Phys. Rev. B 75, 041401 (2007).

    ADS  Article  CAS  Google Scholar 

  9. Kou, L. et al. Graphene-based topological insulator with an intrinsic bulk band gap above room temperature. Nano Lett. 13, 6251–6255 (2013).

    ADS  CAS  PubMed  Article  Google Scholar 

  10. Kaloni, T. P., Kou, L., Frauenheim, T. & Schwingenschlögl, U. Quantum spin Hall states in graphene interacting with WS2 or WSe2. Appl. Phys. Lett. 105, 233112 (2014).

    ADS  Article  CAS  Google Scholar 

  11. Liangzhi Kou, S.-C. W., Felser, C., Frauenheim, T., Chen, C. & Yan, B. Robust 2D Topological Insulators in van der Waals Heterostructures. ACS Nano 8, 10448 (2014).

    PubMed  Article  CAS  Google Scholar 

  12. Lima, E. N. & Schmidt, T. M. Topological phase driven by confinement effects in Bi bilayers. Phys. Rev. B 91, 075432 (2015).

    ADS  Article  CAS  Google Scholar 

  13. Dziawa, P. et al. Topological crystalline insulator states in Pb(1-x)Sn(x)Se. Nat Mater 11, 1023–1027 (2012).

    ADS  CAS  PubMed  Article  Google Scholar 

  14. Du, L., Knez, I., Sullivan, G. & Du, R.-R. Robust Helical Edge Transport in GatedInAs/GaSbBilayers. Phys. Rev. Lett. 114, 096802 (2015).

    ADS  PubMed  Article  Google Scholar 

  15. Liu, C., Hughes, T. L., Qi, X.-L., Wang, K. & Zhang, S.-C. Quantum Spin Hall Effect in Inverted Type-II Semiconductors. Phys. Rev. Lett. 100, 236601 (2008).

    ADS  PubMed  Article  CAS  Google Scholar 

  16. Liu, C.-C., Jiang, H. & Yao, Y. Low-energy effective Hamiltonian involving spin-orbit coupling in silicene and two-dimensional germanium and tin. Phys. Rev. B 84, 195430 (2011).

    ADS  Article  CAS  Google Scholar 

  17. Xu, Y. et al. Large-Gap Quantum Spin Hall Insulators in Tin Films. Phys. Rev. Lett. 111, 136804 (2013).

    ADS  Article  CAS  PubMed  Google Scholar 

  18. Koroteev, Y. M., Bihlmayer, G., Chulkov, E. V. & Blügel, S. First-principles investigation of structural and electronic properties of ultrathin Bi films. Phys. Rev. B 77, 045428 (2008).

    ADS  Article  CAS  Google Scholar 

  19. Li, X. et al. Prediction of large-gap quantum spin hall insulator and Rashba-Dresselhaus effect in two-dimensional g-TlA (A = N, P, As and Sb) monolayer films. Nano Res. 8, 2954–2962 (2015).

    CAS  Article  Google Scholar 

  20. Chuang, F. C. et al. Prediction of large-gap two-dimensional topological insulators consisting of bilayers of group III elements with Bi. Nano Lett. 14, 2505–2508 (2014).

    ADS  CAS  PubMed  Article  Google Scholar 

  21. Zhao, M., Chen, X., Li, L. & Zhang, X. Driving a GaAs film to a large-gap topological insulator by tensile strain. Sci. Rep. 5, 8441 (2015).

    ADS  CAS  PubMed  PubMed Central  Article  Google Scholar 

  22. Zhuang, H. L., Singh, A. K. & Hennig, R. G. Computational discovery of single-layer III-V materials. Phys. Rev. B 87, 165415 (2013).

    ADS  Article  CAS  Google Scholar 

  23. Bahramy, M. S., Yang, B. J., Arita, R. & Nagaosa, N. Emergence of non-centrosymmetric topological insulating phase in BiTeI under pressure. Nat. Commun. 3, 679 (2012).

    ADS  CAS  PubMed  PubMed Central  Article  Google Scholar 

  24. Murakami, S. Quantum spin Hall effect and enhanced magnetic response by spin-orbit coupling. Phys. Rev. Lett. 97, 236805 (2006).

    ADS  PubMed  Article  CAS  Google Scholar 

  25. Wang, J., Chen, X., Zhu, B.-F. & Zhang, S.-C. Topologicalp-njunction. Phys. Rev. B 85, 235131 (2012).

    ADS  Article  CAS  Google Scholar 

  26. Kuroda, K. et al. Experimental realization of a three-dimensional topological insulator phase in ternary chalcogenide TlBiSe(2). Phys. Rev. Lett. 105, 146801 (2010).

    ADS  CAS  PubMed  Article  Google Scholar 

  27. Xiaofeng Qian, J. L. & Liang Fu, Ju Li. Quantum spin Hall effect in two-dimensional transition metal dichalcogenides. Science 346, 1344 (2014).

    ADS  PubMed  Article  CAS  Google Scholar 

  28. Zhou, L. et al. New Family of Quantum Spin Hall Insulators in Two-dimensional Transition-Metal Halide with Large Nontrivial Band Gaps. Nano Lett. 15, 7867–7872 (2015).

    ADS  CAS  PubMed  Article  Google Scholar 

  29. Song, Z. et al. Quantum spin Hall insulators and quantum valley Hall insulators of BiX/SbX (X = H, F, Cl and Br) monolayers with a record bulk band gap. NPG Asia Materials 6, e147 (2014).

    CAS  Article  Google Scholar 

  30. Zhou, M. et al. Epitaxial growth of large-gap quantum spin Hall insulator on semiconductor surface. Proc. Natl. Acad. Sci. USA 111, 14378–14381 (2014).

    ADS  CAS  PubMed  Article  Google Scholar 

  31. Zhou, M. et al. Formation of quantum spin Hall state on Si surface and energy gap scaling with strength of spin orbit coupling. Sci. Rep. 4, 7102 (2014).

    PubMed  PubMed Central  Article  Google Scholar 

  32. Ma, Y. et al. Two-dimensional inversion-asymmetric topological insulators in functionalized III-Bi bilayers. Phys. Rev. B 91, 235306 (2015).

    ADS  Article  CAS  Google Scholar 

  33. Zhao, H. et al. Unexpected Giant-Gap Quantum Spin Hall Insulator in Chemically Decorated Plumbene Monolayer. Sci. Rep. 6, 20152 (2016).

    ADS  CAS  PubMed  PubMed Central  Article  Google Scholar 

  34. Wang, Y. P. et al. Large-gap quantum spin Hall state in functionalized dumbbell stanene. Appl. Phys. Lett. 17, 083036 (2016).

    Google Scholar 

  35. Ma, Y., Kou, L., Du, A. & Heine, T. Group 14 element-based non-centrosymmetric quantum spin Hall insulators with large bulk gap. Nano Res. 8, 3412–3420 (2015).

    CAS  Article  Google Scholar 

  36. Crisostomo, C. P. et al. Robust Large Gap Two-Dimensional Topological Insulators in Hydrogenated III-V Buckled Honeycombs. Nano Lett. 15(10), 6568–6574 (2015).

    ADS  CAS  PubMed  Article  Google Scholar 

  37. Wu, J. et al. Controlled chlorine plasma reaction for noninvasive graphene doping. J. Am. Chem. Soc. 133, 19668–19671 (2011).

    CAS  Article  Google Scholar 

  38. Becerril, A. H. et al. Evaluation of Solution-Processed Reduced Graphene Oxide Films as Transparent Conductors. ACS Nano 2, 463−470 (2008).

    CAS  Article  Google Scholar 

  39. Dahn, J. R., Way, B. M., Fuller, E. & Tse, J. S. Structure of siloxene and layered polysilane (Si6H6). Phys. Rev. B 48, 17872–17877 (1993).

    ADS  CAS  Article  Google Scholar 

  40. Yamanaka, S., Matsuura, H. & Ishikawa, M. New deintercalation reaction of calcium from calcium disilicide. Synthesis of layered polysilane. Mater. Res. Bull 31, 307−316 (1996).

    CAS  Article  Google Scholar 

  41. Zhang, R.-W. et al. Ethynyl-functionalized stanene film: a promising candidate as large-gap quantum spin Hall insulator. New J. Phys. 17, 083036 (2015).

    ADS  Article  CAS  Google Scholar 

  42. Ma, Y., Dai, Y., Wei, W., Huang, B. & Whangbo, M. H. Strain-induced quantum spin Hall effect in methyl-substituted germanane GeCH3. Sci. Rep. 4, 7297 (2014).

    ADS  CAS  PubMed  PubMed Central  Article  Google Scholar 

  43. Ma, Y., Dai, Y., Kou, L., Frauenheim, T. & Heine, T. Robust two-dimensional topological insulators in methyl-functionalized bismuth, antimony and lead bilayer films. Nano Lett. 15, 1083–1089 (2015).

    ADS  CAS  PubMed  Article  Google Scholar 

  44. Jiang, S. et al. Improving the stability and optical properties of germanane via one-step covalent methyl-termination. Nat Commun. 5, 3389 (2014).

    ADS  PubMed  Article  CAS  Google Scholar 

  45. Kresse, G. & Furthmüller, J. Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set. Mater. Sci. 6, 15−50 (1996).

    CAS  Google Scholar 

  46. Kresse, G. & Furthmüller, J. Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set. Phys. Rev. B. 54, 11169−11186 (1996).

    ADS  CAS  Article  Google Scholar 

  47. Kresse, G. & Joubert, D. From ultrasoft pseudopotentials to the projector augmented-wave methods. Phys. Rev. B 59, 1758−1775 (1999).

    ADS  CAS  Article  Google Scholar 

  48. Perdew, P. J., Burke, K. & Ernzerhof, M. Generalized Gradient Approximation Made Simple. Phys. Rev. Lett. 77, 3865−3868 (1996).

    ADS  CAS  PubMed  PubMed Central  Google Scholar 

  49. Monkhorst, H. J. & Pack, J. D. Special points for Brillouin-zone integrations. Phys. Rev. B 13, 5188–5192 (1976).

    ADS  MathSciNet  Article  Google Scholar 

  50. Mostofi, A. A. et al. wannier90: A tool for obtaining maximally-localised Wannier functions. Comput. Phys. Commun. 178, 685–699 (2008).

    ADS  CAS  MATH  Article  Google Scholar 

  51. Zhang, C.-w. & Yan, S.-s. First-Principles Study of Ferromagnetism in Two-Dimensional Silicene with Hydrogenation. J. Phys. Chem. C 116, 4163–4166 (2012).

    CAS  Article  Google Scholar 

  52. Yao, L. Z. et al. Predicted Growth of Two-Dimensional Topological Insulator Thin Films of III-V Compounds on Si(111) Substrate. Sci. Rep. 5, 15463 (2015).

    ADS  PubMed  PubMed Central  Article  CAS  Google Scholar 

  53. Li, L., Zhang, X., Chen, X. & Zhao, M. Giant topological nontrivial band gaps in chloridized gallium bismuthide. Nano Lett. 15, 1296–1301 (2015).

    ADS  CAS  PubMed  Article  Google Scholar 

  54. Sancho, P. L. M., Sancho, M. L. J. & Rubio, J. Quick iterative scheme for the calculation of transfer matrices: application to Mo (100). J. Phys. F: Met. Phys. 14, 1205 (1984).

    ADS  Article  Google Scholar 

  55. Fu, L. & Kane, C. L. Josephson current and noise at a superconductor/quantum-spin-Hall-insulator/superconductor junction. Phys. Rev. B 79, 161408 (2009).

    ADS  Article  CAS  Google Scholar 

  56. Yu, R., Qi, X. L., Bernevig, A., Fang, Z. & Dai, X. Equivalent expression of Z2 topological invariant for band insulators using the non-Abelian Berry connection. Phys. Rev. B 84, 075119 (2011).

    ADS  Article  CAS  Google Scholar 

  57. Hsieh, T. H. et al. Topological crystalline insulators in the SnTe material class. Nat. Commun. 3, 982 (2012).

    ADS  PubMed  Article  CAS  Google Scholar 

  58. Liu, J., Qian, X. & Fu, L. Crystal field effect induced topological crystalline insulators in monolayer IV-VI semiconductors. Nano Lett. 15, 2657–2661 (2015).

    ADS  CAS  PubMed  Article  Google Scholar 

  59. Chuang, F.-C., Huang, Z.-Q., Lin W.-H., Albao, A. M. & Su, W.-S. Structural and electronic properties of hydrogen adsorptions on BC3 sheet and graphene: a comparative study. Nanotechnology 22, 135703 (2011).

    ADS  PubMed  Article  CAS  Google Scholar 

  60. Britnell, L. et al. Field-Effect Tunneling Transistor Based on Vertical Graphene Heterostructures. Science. 335, 947–950 (2012).

    ADS  CAS  PubMed  Article  Google Scholar 

  61. Ju, L. et al. Photoinduced doping in heterostructures of graphene and boron nitride. Nat. Nanotechnol. 9, 348–352 (2014).

    ADS  CAS  PubMed  Article  Google Scholar 

  62. Klimeš, J., Bowler, D. R. & Michaelides, A. Van der Waals density functionals applied to solids. Phys. Rev. B 83, 195131 (2011).

    ADS  Article  CAS  Google Scholar 

  63. Liangzhi, K. et al. Tetragonal bismuth bilayer: a stable and robust quantum spin hall insulator. 2D Mater. 2, 045010 (2015).

    Article  CAS  Google Scholar 

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Acknowledgements

This work was supported by National Natural Science Foundation of China (Grant Nos 11434006, 11274143, 61172028 and 11304121), Natural Science Foundation of Shandong Province (Grant Nos ZR2013AL004, ZR2013AL002), Technological Development Program in Shandong Province Education Department (Grant No. J14LJ03), Research Fund for the Doctoral Program of University of Jinan (Grant Nos XBS1433, XBS1402, XBS1452).

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S.L. and C.Z. conceived the study and wrote the manuscript. P.L and P.W. performed the first-principles calculations. W.J. calculated the phonon spectrum. S.H., B.Z. and C.C. prepared figures. All authors read and approved the final manuscript.

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Li, Ss., Ji, Wx., Zhang, Cw. et al. Robust Room-Temperature Quantum Spin Hall Effect in Methyl-functionalized InBi honeycomb film. Sci Rep 6, 23242 (2016). https://doi.org/10.1038/srep23242

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