Abstract
A highly efficient third generation catalyst, CaCu3Ti4O12 (CCTO) shows excellent photoelectrochemical (PEC) and photocatalytic ability. As only 4% part of the solar spectrum covers UV light, thus it is highly desirable to develop visible light active photocatalyst materials like CCTO for effective solar energy conversion. A direct band transition with a narrow band gap (1.5 eV) was observed. Under light irradiation, high photocurrent density was found to be 0.96 mA/cm2, indicating the visible light induced photocatalytic ability of CCTO. Visible light mediated photocatalytic and photoelectrocatalytic degradation efficiency of CaCu3Ti4O12 pellets (CCTO) was investigated for three classes of pharmaceutical waste: erythrosin (dye), ciprofloxacin (antibiotic) and estriol (steroid). It is found that the degradation process follows first order kinetic reaction in electrocatalysis, photocatalysis and photoelectrocatalysis and high kinetic rate constant was observed in photoelectrocatalysis. This was quite high in comparison to previously reported methods.
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Introduction
Photocatalysis has attracted great interest in recent years due to its potential to degrade various pollutants into environmental-benign chemicals at low cost1,2,3. Photoelectrochemical (PEC) water splitting along with photocatalytic oxidation is a sustainable process for the conversion of solar energy for energy production. First time in 1972, Fujishima and Honda demonstrated the prospect of creating a clean and sustainable fuel through PEC process4. The other aspect of using this solar energy is the degradation of harmful, widely used pharmaceutical wastes in to non- toxic chemicals in the process of water treatment. Pollutants from pharmaceuticals and industrial wastages have serious and long-term effects on human health and aquatic environment. These pollutants enter into the environment through the discharge of manufacturing plants, industrial waste water and sewage treatment plants (STP). Pharmaceutical waste water contains dyes, antibiotics, estrogens, steroids and other drugs5,6,7. Fluoroquinolone antibiotics and estrogenic hormones such as ciprofloxacin, norfloxacin, enrofloxacin, 17β- estradiol (E2),17α- ethylestradiol and estriol are largely used to treat diseases and infection. However, incomplete degradation of these drugs releases harmful residual components in surface water8,9. Similarly, a low concentration of antibiotics, which are commonly used in agriculture to promote growth and prevent disease, can cause proliferation of drug resistant bacteria causing a potential threat for human health and ecosystem10,11. For example, Erythrosine which is extensively being used for artificial coloring for foods and drugs like ibuprofen, its toxicological test shows sensitivity to light and increase thyroid hormone levels and lead to hyperthyroidism12,13. Thus alternative cost-effective techniques are highly required to degrade this environmental discharge of pharmaceuticals and hazardous dyes.
A PEC cell provides a sustainable process to transform solar energy into chemical fuel and electricity. This is a highly efficient operation can be triggered simply by sunlight. PEC water splitting is the most direct mechanism which can be used for hydrogen generation, solar energy harvesting and waste water treatment. Water splitting is an endergonic process requiring an energy input of 237 kJ/mol of water. Solar light can be an efficient source for the necessary energy input. However, that energy needs to be efficiently collected through absorption processes and transferred into a water molecule to break its chemical bonds. Photoelectrochemical splitting of water into oxygen and hydrogen has emerged as a potentially viable option for the efficient degradation of pollutants.
Many of the first generation photocatalyst like metal oxides have been used for photoelectrochemical solar cell and photocatalytic degradation of antibiotics, endocrine disrupting chemicals (EDCs) and various pollutants but they have limitations like low yield and redistricted catalysis process occuring only in UV irradiation14,15,16. Various strategies have been used to develop visible light active photocatalysts, e.g. metal (Cr, Co, V and Fe) doping, non-metal (N, F, S and C) doping, dye sensitization and doping of supported nanoparticles17,18,19,20,21. These systems are classified as second generation of photocatalyst materials. Most of these second generation of photocatalysts have the inefficiency due to instability and charge recombination processes. Thus large interest arose for the third generation photocatalysts which have multiphoton excitation due to heterojunction of low band gap photoactive materials and TiO2 22,23. ABO3 perovskite and layered structures have great potential for the visible light photocatalysis and considered as third generation photocatalyst. The band structure of these materials can be tailored by substitution of A and B sites24. The double perovskite structures like A2InNbO6 and A3CoNb2O9 have shown their potential for water splitting under visible light25,26,27.
The photocatalytic and photoelectrochemical performance of a catalyst mainly depend upon (i) the light absorption properties, (ii) reduction and oxidation rates on the surface by the electron and hole and (iii) the electron-hole recombination rate. CaCu3Ti4O12 (CCTO) is a combination of well-known highly UV active photocatalyst TiO2 and visible light absorbing CuO. CaCu3Ti4O12 (CCTO) is a cubic double-perovskite which has Cu+2 and Ca+2 on A site and Ti+4 on the B site. It is extensively studied for the energy storage and microelectronics applications due to its high dielectric constant28,29,30,31. In this paper, we demonstrate the visible light induced photoelectrochemical behavior and photocatalytic activity of CCTO ceramic for the three different classes of pharmaceuticals: dyes, antibiotics and steroid hormones. To the best of our knowledge, this is the first report for the enhanced visible light photocatalytic activity of CCTO ceramic pellets for the pharmaceutical pollutants.
Results and Discussion
Ceramic samples of CCTO prepared from the oxalate precursor route had been studied by different characterization techniques. The X-ray diffraction patterns were recorded on the as prepared CCTO powders (Fig. 1a(i)), the pellets sintered at 1130 °C (Fig. 1a(ii)) are compared well with ICDD data (01-075-1149) (Fig. 1a(iii)), demonstrating the single phase nature of CCTO. In the XRD- pattern of sintered CCTO pellet, there is not any peaks for CuO and TiO2 which shows that phase pure CCTO can be synthesized using this process. The crystallite size was calculated using Scherer formula and observed as 26 nm for powder and 64 nm for sintered pellets of CCTO. The heat treatment around 1130°C resulted sintering of the particles and increment in crystallite size. Figure 1b shows the SEM micrograph of CCTO pellets sintered at 1130 °C for 2 h.
The optical properties of CCTO had been studied using UV-visible spectroscopy32 and Fig. 2a shows the diffuse reflectance spectra for the CCTO powder. A broad absorption band was observed between 200–700 nm with highest absorption at 305 nm. The absorption cutoff wavelength for the CCTO powder is 750 nm. Figure 2b shows the plot between Kubelka-Munk function (F(R)hʋ)1/ 2 and photon energy (hʋ)33. A direct transition of 1.5 eV was estimated from the tangent line in the plot which corresponds to the visible light absorption and low band gap of CCTO powder. In CCTO, three possible mechanisms are attributed for photogenerated hole formation for 3d9 (i) dx2-y2 → dxy (ii) dx2-y2 → dz2 (iii) dx2-y2 → dzx, yz. Clark et al. reports the visible light activity of Pt-CCTO complex for dye degradation32. The observed absorbance data shows that CCTO has a direct transition in the visible region. In CCTO, the higher energy absorption edge arises due to direct transition from Cu 3d- O 2p hybridized valance band to the Ti-3d conduction band and the lower energy absorption is attributed as transition between valance band and unoccupied Cu 3d band. CCTO have visible light activity due to photo-induced charge transition from Cu2+, Ti4+ ground state to Cu3+, Ti3+ excited state32. The visible light activity and the photo induced charge transfer show its potential for photoelectrochemical solar cell and photocatalytic pollutant removal process. CCTO has large absorption spectrum in visible region which is favorable for activity of CCTO as catalyst under visible light. Therefore, CCTO was used for pollutant degradation and photoelectrodes under visible light irradiation.
The photocatalytic activity of as prepared CCTO pellet was evaluated by the degradation of erythrosine, ciprofloxacin and estriol. Fig. 3a shows the variation in absorbance spectra of an aqueous solution of erythrosine in the presence of CCTO pellets irradiated by a visible light source. The absorption peak corresponding to erythrosine dye was observed at 525 nm and the peak intensity decreases rapidly with the prolonged exposure time. The pink solution of erythrosine turned into colorless solution after only 40 minute exposure. Erythrosine dye molecules react with ˙O2 or ˙OH radicals generated during splitting of H2O in photocatalysis process which further perform mineralization of erythrosine molecules34. Figure 3b shows the images of time dependent degradation of erythrosine in the presence of CCTO. Under visible light irradiation, the pink color of the erythrosine started fading within 15 minutes and turned colorless within 30 minutes. However, in the dark, we did not observe any detectable color change. That indirectly proves that CCTO is photocatalytically degrading the erythrosine molecules. Figure 3c shows the change in concentration of ciprofloxacin aqueous solution during photocatalysis with CCTO pellet under exposure of visible light. The results show that the absorption peak of ciprofloxacin molecules decreases with the irradiation time at 276 nm. Photocatalytic degradation of estriol using CCTO pellet was analyzed by fluorescence spectroscopy. Estriol shows a strong emission peak at 306 nm when excited with 240 nm source wavelength. Figure 3d shows the rapid decrease in fluorescence intensity of estriol molecules during photocatalysis using CCTO pellets under visible light exposure which attributed as degradation in concentration of estriol molecules.
The degradation efficiency (D %) of CCTO pellets for the pollutants is calculated using
where C0 is the initial concentration of drug and Ct the concentration of drug after time (t) exposure. Figure 4a shows the comparative degradation (%) of erythrosine, ciprofloxacin and estriol in photolysis and photocatalysis under the visible light exposure (λ>420 nm). In the photolysis, no significant degradation was observed for all the pollutants. CCTO photocatalytic pellet shows maximum degradation efficiency for the erythrosine dye under visible light which is better than previous reported methods34,35. The dye molecules degraded up to 70% in visible light irradiation of 40 min while under dark light no degradation of pollutant was observed. The prepared CCTO ceramic pellets degrade 60% of ciprofloxacin concentration in 60 min while for estriol molecules, CCTO pellet saturates earlier. Upto 50% degradation was performed in 40 min using prepared CCTO pellets which are higher than earlier used catalysts for visible light mediated degradation36,37,38.
The kinetic behavior of CCTO photocatalyst for the degradation of erythrosine, ciprofloxacin and estriol were investigated using Langmuir-Hinshelwood kinetic equation39:
where C0 and Ct are the initial concentration and concentration after time t for pollutants. K is the first order catalytic rate constant which is represented by slope of the ln (At/A0) and degradation time (t) plot. Figure 4b shows the kinetics decay plots for the degradation of erythrosine, ciprofloxacin and estriol. All three of the pollutants show first order decay for the visible light catalysis using CCTO ceramic pellets. The kinetic rate constants for the erythrosine, ciprofloxacin and estriol are calculated as k1 (0.0289 min−1), k2 (0.01682 min−1) and k3 (0.0166 min−1). Figure 4c shows the degradation rate for all the three pollutants in the repeated photocatalytic process using CCTO pellet as catalyst. In all the five cycle, constant degradation rate was observed which attributed as stability and reusability of the catalyst.
Mass spectroscopy was used to probe the generated byproduct after photocatalysis of erythrosine. Figure 5 shows the mass spectra for erythrosine aqueous solution before and after photocatalysis. The intermediates with m/z 467.44 and 657.34 corresponding to the fragments of erythrosine and gradually disappeared after irradiation for 30 minutes in presence of CCTO. Photocatalytic degradation pathway of erythrosine can be analyzed from the transformation of the intermediate species analyzed in mass spectroscopy40. Erythrosine dye molecules reacts with photogenerated holes and 2 or ˙OH radicals which are generated during water splitting. Erythrosine transformed into 2,5-dihydroxybenzoic acid and phthalic acid41,42. The intermediate products further react with ∙OH radicals and converted into CO2 and water by ring opening and mineralization process43.
In the photocatalytic degradation of ciprofloxacin both ˙OH radical and photogenerated holes play role in complete oxidation of molecule and intermediates. The photogenerated holes attack on the N12 position in ciprofloxacin. On the other hand, the addition of ˙OH radical occurs at C10 and C5 position in quinolone ring. The intermediates formed in the process are further oxidized with hydroxyl radicals and perform a complete oxidation in CO244. The conduction band in CCTO which contributed by Ti (3d) state, plays important role to return the quinolone molecule in ground state by transferring electron into conduction band after photo-excitation. The electron in conduction band further transferred to donor quinolone molecules45. In the photocatalytic degradation process of estriol, the active ∙OH radicals formed at photocatalyst surface by water splitting. These ∙OH radicals are more likely to attack the benzene ring at C2 and C4 of estriol followed by reaction with oxygen and elimination of HOO∙ group46,47. 10ε-17β-dihydroxy-1, 4- estradien-3-one (DEO) and testosterone like species are generated as intermediate products in photocatalytic degradation of estriol. These species are further completely mineralized into CO2. The intermediates and final products did not have any estrogenic activity due to the complete dissociation of phenol group which is highly responsible to initiate estrogenic activity48.
To demonstrate the enhanced electron transfer in the CCTO system, some PEC tests were carried out. The photoelectrochemical activity of CCTO under visible light was analyzed by measuring the photocurrent using linear sweep voltammetry (LSV) in the dark and under visible light irradiation as shown in Fig. 6. Cyclic voltammetry observations attributed as high stability of CCTO photo-anode in the electrolyte during electrochemical measurements. The higher photocurrent density was observed under the light illumination for the CCTO pellets which was attributed as light harvesting ability and narrow band gap of CCTO. The photocurrent density (Jsc) was observed as 0.97 mA/cm2 under light irradiation. The interband electron transition due to photon absorption during visible light irradiation results into the generation of photocurrent and four fold increase of current density. LSV and cyclic voltammetry showed that the CCTO can be used effectively as photocatalysts and photoelectrode materials.
In order to understand the origin of photoactivity enhancement in the PEC system, the flat band potential was measured. Here, the flat band potential of electrodes was determined by the Mott–Schottky relation1:
Where C = space charge layers capacitance, e = electron charge, ε = dielectric constant, ε0 = permittivity of vacuum, Nd = electron donor density,Va = applied potential and Vfb = flat band potential.
The flat band potential (Vfb) was determined by taking the x intercept of a linear fit to the Mott–Schottky plot (See supporting information, Fig. S1), 1/C2, as a function of applied potential (Va). The apparent donor density of the CCTO photoanode was calculated as 1.9×1015. Flat band potential of 0.4 V vs SCE was observed for CCTO photoanode. Electrochemical impedance spectroscopy (EIS) was performed to investigate the electrochemical behavior of CCTO photoanode. Figure S2 (See supporting information) shows EIS results presented in the form of Nyquist plot. CCTO electrode exhibits Rct (2.8 kΩ) indicating the more favorable environment for hole transfer to the electrolyte.
Figure 7a,b show the electrocatalytic and photoelectrocatalytic degradation of erythrosine by CCTO. The cyclic voltammogram data (Fig. 7a,b) show a sharp oxidation peak at 0.62 V (vs SCE). This peak intensity decreased on the progression of scans (with the increased number of cycle). The decrease in the anodic peak current can be attributed as oxidative degradation of erythrosine on CCTO electrode as the visible change in the color of the electrolyte was also observed. Careful investigations of the CCTO pellet after electrochemical and photoelectrochemical studies shows no noticeable change(see supporting information), indicating that decline of the peak intensity in CV was due to the degradation of electrolyte materials and not accountable for the structural or chemical degradation of CCTO. The photoelectrochemical performance of CCTO pellets shows significantly higher current density during the visible light assisted electrocatalytic degradation (Fig. 7b). In photoelectrochemical study, higher degradation rate was observed in comparison to the electrochemical degradation of erythrosine. Figure 7c shows the degradation plots for electrocatalysis and photoelectrocatalysis of erythrosine, ciprofloxacin and estriol. The kinetic decay constants for the degradation of all three pollutants was found to be higher under photoelectrocatalytic degradation which is attributed as role of photocurrent in generation of more OH˙ radicals for catalysis and effective separation of charge carriers. The stability of the catalyst has been verified using XRD before and after catalysis. The XRD data shows indifference with the pre-catalysis data collected as shown in Fig S3. (See supporting information).
The photocatalytic activity is controlled by both the ability of light-harvesting and the separation of e−/h+ pair. The e−/h+ pair generated due to light absorption will recombine if they are not separated quickly. A high photocurrent indicates that CCTO has a strong ability to generate and transfer the photo-excited charge carriers and rapidly production of ∙OH radicals during electrochemical water splitting under light illumination. These ∙OH radicals plays major role in the photocatalytic degradation of pollutants. Time-dependent fluorescence experiments had been carried out to identify these ∙OH (See supporting information, Fig. S4). Previous reports and the experimental results indicated that photocatalytic degradation of pharmaceuticals initiated by excitation of electron form the valance band to the conduction band after irradiation of light2,14,49. The photocatalytic performance of catalyst is depends upon its light absorption ability and electron transfer ability. The process starts only when the incident light energy is equal to or larger than band gap. CCTO photocatalyst is a novel material for visible light catalysis due to its high absorbance spectrum, narrow band gap and ability to transfer the photogenerated charge carriers. The process followed by the direct oxidation of pharmaceuticals by photo generated hydroxyl radicals and holes. The indirect oxidation is performed by the ˙OH radials generated by water splitting.
Conclusion
In conclusion, a novel visible light active CaCu3Ti4O12 ceramic was synthesized from the oxalate precursor route. CCTO have broad absorbance spectrum for visible light and narrow band gap which makes it a potential material for visible light induced photocatalysis and photoelectrochemical cell. Under visible light irradiation, CCTO pellet electrodes show high photocurrent density 0.97 mA/cm2. It shows the potential of CCTO photoanode for the high performance PEC solar cells for energy conversion. CCTO ceramic pellets have more efficient photocatalytic ability to degrade erythrosine, ciprofloxacin and estriol than any other catalyst under visible light. The catalysis was performed by using CCTO pellets and does not require any additional filtration process to remove the catalyst which is an added advantage over the catalysis in powder form. This study has demonstrated fabrication of third generation photocatalyst with two distinct transition metals for the visible light mediated photoelectrochemical and photocatalytic degradation for three different classes of pharmaceutical water pollutants which can be applied to develop new class of visible light active catalysts for other pollutants.
Methods
Synthesis of CaCu3Ti4O12
Ceramic samples of CaCu3Ti4O12 (CCTO) were prepared from the oxalate precursor route28. In a typical preparation, initially, the titania gel was prepared from the aqueous TiOCl2 (0.05 M) by adding NH4OH at room temperature till the pH reaches ~8.0 and washed with water to remove NH4Cl. Synthesized titania gel was powdered and dissolved in H2C2O4.2H2O. In the obtained solution, calcium carbonate was added and stirred. The solution remained clear without any precipitate formation. Cupric chloride solution in acetone and water (80:20) was added slowly and stirred continuously at 10 °C. The thick precipitate was separated, washed several times with acetone to make it chloride-free and dried in air. The precipitate thus prepared was isothermally heated above 680 °C to get the ceramic powders of CaCu3Ti4O12. The resultant powder was ground thoroughly, ball milled for 2 h and granulated by adding polyvinyl alcohol (PVA) and poly ethylene glycol (PEG), then pressed into pellets at 150 MPa with a diameter of 12 mm and thickness of 2 mm. The green pressed pellets were slowly heated to 600 °C to get rid of the binder. Finally, the pellets were sintered in air at 1130 °C for 2 h. Pellet densities were measured by the Archimedes principle using xylene as the liquid medium.
Material Characterization
After sintering, X-ray powder diffraction studies were carried with an X’pert diffractometer (Philips, Netherlands) using Cu Kα1 radiation (λ = 0.154056 nm) in a wide range of 2θ (10o–90o) with 0.02 step size to examine the phase constitutes of the specimens. Scanning electron microscope (FEI-Technai SEM-Sirion) was used to observe the microstructure of the sintered pellets. Optical properties of CCTO powder were analyzed by UV-vis absorbance spectroscopy.
Photoelectrochemical Characterization
A scanning potentiostat (Metrohom, Autolab) was used to perform cyclic voltammetry and electrochemical impedance studies in a three-electrode photoelectrochemical cell with CCTO pellet as the working electrode, a calomel electrode as the reference, a platinum wire as the counter electrode and 1M L−1 KOH as electrolyte. To fabricate the working electrode, a copper wire was attached with the silver paste at side of pellet and sealed with epoxy to avoid the copper contact with electrolyte. Cyclic voltammetry and Linear Sweep Voltammetry (LSV) scan were performed between −1 V to 0.5 V vs. SCE at scan rate of 2 mV s−1. For photocurrent measurements, PEC cell was assembled using a CCTO pellet electrode with an area of 1 cm2 as a photoanode, Pt wire as a counter electrode and 1 M L−1 KOH as electrolyte. A halogen lamp with a power of 100 mW/cm2 was used as the incident light source and placed at 10 cm distance from the electrochemical cell.
Visible Light Photocatalysis
Pharmaceutical dye erythrosine, antibiotic ciprofloxacin and estriol were used to test the photocatalytic activity of sintered CCTO pellets. Table 1 shows the chemical structures, applications and toxicological effect of pollutants which are used for photocatalytic degradation in this paper The photocatalytic degradation experiments was carried out by using 10 ml solution of10 mg/L ciprofloxacin, 10 mg/L erythrosine and 1 mg/L of estriol in deionized water. A total of 10 ml solution of pharmaceutical compound was transferred in pyrex glass vessel and the sintered CCTO pellet was placed vertically in vessel. The vessel was kept in dark for 30 min to allow stabilization and pre adsorption of pharmaceutical species on catalyst pellet. The photocatalytic degradation process was initiated by exposing the reaction vessel with visible light 150 W halogen lamp with UV-light cutoff filter (λ>420 nm). During light exposure, cold water was circulated around the vessel to maintain at room temperature. Sample aliquots of pharmaceuticals were collected at various time intervals and analyzed for change in concentration. The concentration of erythrosine and ciprofloxacin were analyzed using Shimadzu-2450 UV-vis spectrophotometer by measuring the peak intensity. The degradation of estriol was investigated by fluorescence spectrophotometer. The analysis was performed using 3 ml of sample aliquots. High resolution mass spectroscopy analysis was performed to analyze the subsequent species produced during photocatalytic degradation of erythrosine.
Photoelectrocatalysis
Photoelectrocatalytic degradation of erythrosine was carried out in a single photoelectrochemical compartment. The CCTO photoanode (12 mm diameter and 1 mm thickness) and a platinum wire cathode were placed in parallel in a cuboid glass reactor (volume of 100 mL) with a SCE reference electrode. All electrodes were connected to a Metrohom, Autolab electrochemical station. A halogen lamp placed outside the glass reactor and paralleled to the CCTO photoanode. A bias potential applied on the CCTO photoanode was varied from 0.5 V to 1.5 V (vs SCE) under visible light intensity of 100 mW cm−2. All the experiments were performed at room temperature (about 25 °C) with a magnetic stirrer at a constant speed.
Additional Information
How to cite this article: Kushwaha, H. S. et al. Efficient Solar Energy Conversion Using CaCu3Ti4O12 Photoanode for Photocatalysis and Photoelectrocatalysis. Sci. Rep. 6, 18557; doi: 10.1038/srep18557 (2016).
References
Klavarioti, M., Mantzavinos, D. & Kassinos, D. Removal of residual pharmaceuticals from aqueous systems by advanced oxidation processes. Environ. Int 35, 402–417 (2009).
Dalrymple, O.K., Yeh, D.H. & Trotz, M.A. Removing pharmaceuticals and endocrine‐disrupting compounds from wastewater by photocatalysis. J. Chem. Technol. Biotechnol. 82, 121–134 (2007).
Lachheb, H. et al. Photocatalytic degradation of various types of dyes (Alizarin S, Crocein Orange G, Methyl Red, Congo Red, Methylene Blue) in water by UV-irradiated titania. Appl. Catal. B 39, 75–90 (2002).
Fujishima, A. & Honda, K. Electrochemical photolysis of water at a semiconductor electrode. Nat. 238, 37–38 (1972).
Daughton, C.G. & Ternes, T.A. Pharmaceuticals and personal care products in the environment: agents of subtle change? Environ. Health Perspect. 107, 907 (1999).
Shore, L.S., Gurevitz, M. & Shemesh, M. Estrogen as an environmental pollutant. Bulletin of Environmental Contamination and Toxicology 51, 361–366 (1993).
Jones, O.A., Lester, J.N. & Voulvoulis, N. Pharmaceuticals: a threat to drinking water? Trend Biotechnol. 23, 163–167 (2005).
Khetan, S.K. & Collins, T.J. Human pharmaceuticals in the aquatic environment: a challenge to green chemistry. Chem. Rev. 107, 2319–2364 (2007).
Rivera-Utrilla, J., Sánchez-Polo, M., Ferro-García, M.Á., Prados-Joya, G. & Ocampo-Pérez, R. Pharmaceuticals as emerging contaminants and their removal from water. A review. Chemosphere 93, 1268–1287 (2013).
Halling-Sørensen, B. et al. Occurrence, fate and effects of pharmaceutical substances in the environment-A review. Chemosphere 36, 357–393 (1998).
Baquero, F., Martínez, J.-L. & Cantón, R. Antibiotics and antibiotic resistance in water environments. Curr. Opin. Biotechnol. 19, 260–265 (2008).
Borzelleca, J. & Hallagan, J. Lifetime toxicity/carcinogenicity study of FD & C Red No. 3 (erythrosine) in mice. Food Chem. Toxicol. 25, 735–737 (1987).
Borzelleca, J., Depukat, K. & Hallagan, J. Lifetime toxicity/carcinogenicity studies of FD & C Blue No. 1 (brilliant blue FCF) in rats and mice. Food Chem. Toxicol. 28, 221–234 (1990).
Mills, A., Davies, R.H. & Worsley, D. Water purification by semiconductor photocatalysis. Chem. Soc. Rev. 22, 417–425 (1993).
Chen, D. & K Ray, A. Removal of toxic metal ions from wastewater by semiconductor photocatalysis. Chem. Eng. Sci. 56, 1561–1570 (2001).
Chen, X., Shen, S., Guo, L. & Mao, S.S. Semiconductor-based photocatalytic hydrogen generation. Chem. Rev. 110, 6503–6570 (2010).
Wang, J., Uma, S. & Klabunde, K. Visible light photocatalysis in transition metal incorporated titania-silica aerogels. Appl. Catal. B 48, 151–154 (2004).
Kato, H. & Kudo, A. Visible-light-response and photocatalytic activities of TiO2 and SrTiO3 photocatalysts codoped with antimony and chromium. J. Phys. Chem. B 106, 5029–5034 (2002).
Asahi, R., Morikawa, T., Ohwaki, T., Aoki, K. & Taga, Y. Visible-light photocatalysis in nitrogen-doped titanium oxides. Science 293, 269–271 (2001).
Youngblood, W.J., Lee, S.-H.A., Maeda, K. & Mallouk, T.E. Visible light water splitting using dye-sensitized oxide semiconductors. Acc. Chem. Res. 42, 1966–1973 (2009).
Zong, X. et al. Enhancement of photocatalytic H2 evolution on CdS by loading MoS2 as cocatalyst under visible light irradiation. J. Am. Chem. Soc. 130, 7176–7177 (2008).
Serpone, N. & Emeline, A. Semiconductor Photocatalysis: Past, Present and Future Outlook. J. Phys. Chem. Lett. 3, 673–677 (2012).
Gionco, C. et al. Cerium-Doped Zirconium Dioxide, a Visible-Light-Sensitive Photoactive Material of Third Generation. J. Phys. Chem. Lett. 5, 447–451 (2014).
Shi, J. & Guo, L. ABO3-based photocatalysts for water splitting. Prog. Nat. Sci.: Mat. Int. 22, 592–615 ( 2012).
Ding, J., Bao, J., Sun, S., Luo, Z. & Gao, C. Combinatorial discovery of visible-light driven photocatalysts based on the ABO3-type (A= Y, La, Nd, Sm, Eu, Gd, Dy, Yb, B= Al and In) binary oxides. J. Comb. Chem. 11, 523–526 (2009).
Ting, V. et al. A structure, conductivity and dielectric properties investigation of A3 CoNb2 O9(A = Ca2+, Sr2+, Ba2+) triple perovskites. J. Solid State Chem. 177, 4428–4442 (2004).
Subramanian, M. & Sleight, A. ACu3 Ti4 O12 and ACu3 Ru4 O12 perovskites: high dielectric constants and valence degeneracy. Solid State Sci. 4, 347–351 (2002).
Thomas, P., Dwarakanath, K., Varma, K. & Kutty, T. Synthesis of nanoparticles of the giant dielectric material, CaCu3Ti4O12 from a precursor route. J. Therm. Anal. Calorim. 95, 267–272 (2009).
Shri Prakash, B. & Varma, K. Ferroelectriclike and pyroelectric behavior of CaCu 3 Ti 4 O 12 ceramics. Appl. Phys. Lett. 90, 082903-082903-082903 (2007).
Prakash, B.S. & Varma, K. Molten Salt Synthesis of Nanocrystalline Phase of High Dielectric Constant Material CaCu3Ti4O12. J. Nanosci. Nanotechnol. 8, 5762–5769 (2008).
Thomas, P., Dwarakanath, K. & Varma, K. Effect of calcium stoichiometry on the dielectric response of CaCu3 Ti4 O12 ceramics. J. Eur. Ceram. Soc. 32, 1681–1690 (2012).
Clark, J.H. et al. Visible light photo-oxidation of model pollutants using CaCu3Ti4O12: an experimental and theoretical study of optical properties, electronic structure and selectivity. J. Am. Chem. Soc. 133, 1016–1032 (2010).
Kubelka, P. & Munk, F. An article on optics of paint layers. Z. Tech. Phys 12 (1931).
Hasnat, M., Uddin, M., Samed, A., Alam, S. & Hossain, S. Adsorption and photocatalytic decolorization of a synthetic dye erythrosine on anatase TiO2 and ZnO surfaces. J. Hazard. Mater. 147, 471–477 (2007)
Feng, F. et al. Highly sensitive and accurate screening of 40 dyes in soft drinks by liquid chromatography–electrospray tandem mass spectrometry. J. Chromatogr. B 879, 1813–1818 (2011).
Nasuhoglu, D., Rodayan, A., Berk, D. & Yargeau, V. Removal of the antibiotic levofloxacin (LEVO) in water by ozonation and TiO2 photocatalysis. Chem. Eng. J. 189, 41–48 (2012).
Wang, L. et al. FeCl3/NaNO2: an efficient photocatalyst for the degradation of aquatic steroid estrogens under natural light irradiation. Environ. Sci. Technol. 41, 3747–3751 (2007).
Liu, X. et al. Selective degradation of ciprofloxacin with modified NaCl/TiO2 photocatalyst by surface molecular imprinted technology. Colloids Surf., A 441, 420–426 (2014).
Roberts, G. & Satterfield, C. Effectiveness factor for porous catalysts. Langmuir-Hinshelwood kinetic expressions. Ind. Eng. Chem. Fund. 4, 288–293 (1965).
Baiocchi, C. et al. Characterization of methyl orange and its photocatalytic degradation products by HPLC/UV–VIS diode array and atmospheric pressure ionization quadrupole ion trap mass spectrometry. Int. J. Mass Spectrom. 214, 247–256 (2002).
Chen, T., Zheng, Y., Lin, J.-M. & Chen, G. Study on the photocatalytic degradation of methyl orange in water using Ag/ZnO as catalyst by liquid chromatography electrospray ionization ion-trap mass spectrometry. J. Am. Soc. Mass Spectrom. 19, 997–1003 (2008).
Houas, A. et al. Photocatalytic degradation pathway of methylene blue in water. Appl. Catal. B31, 145–157 (2001).
Apostol, L.C., Smaranda, C., Diaconu, M. & Gavrilescu, M. Preliminary ecotoxicological evaluation of erythrosin b and its photocatalytic degradation products. Environ. Eng. Manage. J. 14, 465–471 (2015).
An, T. et al. Kinetics and mechanism of advanced oxidation processes (AOPs) in degradation of ciprofloxacin in water. Appl. Catal. B 94, 288–294 (2010).
Paul, T., Miller, P.L. & Strathmann, T.J. Visible-light-mediated TiO2 photocatalysis of fluoroquinolone antibacterial agents. Environ. Sci. Technol. 41, 4720–4727 (2007).
Li Puma, G., Puddu, V., Tsang, H.K., Gora, A. & Toepfer, B. Photocatalytic oxidation of multicomponent mixtures of estrogens (estrone (E1), 17β-estradiol (E2), 17α-ethynylestradiol (EE2) and estriol (E3)) under UVA and UVC radiation: photon absorption, quantum yields and rate constants independent of photon absorption. Appl. Catal. B 99, 388–397 (2010).
Kushwaha, H., Parmesh, G., Vaish, R. & Varma, K. TiO2 microcrystallized glass plate mediated photocatalytic degradation of estrogenic pollutant in water. J. Non-Cryst. Solids 408, 13–17 (2015).
Chen, Y., Zhang, K. & Zuo, Y. Direct and indirect photodegradation of estriol in the presence of humic acid, nitrate and iron complexes in water solutions. Sci. Total Environ. 463, 802–809 (2013).
Gaya, U.I. & Abdullah, A.H. Heterogeneous photocatalytic degradation of organic contaminants over titanium dioxide: a review of fundamentals, progress and problems. J. Photochem. Photobiol., C 9, 1–12 (2008).
Acknowledgements
The authors would like to extend their sincere appreciation to the Deanship of Scientific Research at Kind Saud University for funding this research group no. RG-1436-014.
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H.S.K. and P.T. designed/carried out the experiments, preformed the sample characterization measurements and analyzed all the results. H.S.K. and R.V. wrote the manuscript. A.H. performed electrochemical measurements. R.V., A.H., N.A.M. and B.I. were involved in the design of experiments, editing of the manuscript and discussions throughout the work. All authors reviewed the manuscript.
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Kushwaha, H., Madhar, N., Ilahi, B. et al. Efficient Solar Energy Conversion Using CaCu3Ti4O12 Photoanode for Photocatalysis and Photoelectrocatalysis. Sci Rep 6, 18557 (2016). https://doi.org/10.1038/srep18557
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DOI: https://doi.org/10.1038/srep18557
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